• Journal of Environmental Health Sciences
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• v.45 no.5
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• pp.443-456
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• 2019

Objectives: Children are exposed to various environmental pollutants through contact with children's products. We investigated the KC mark, certification number, and contained substances labeled on children's products through market research and collected the toxicological data on these substances. Methods: The environmentally hazardous substances labeled on children's products (n=6576), including toys (n=2812), personal care products (n=2212), stationary/books (n=1333), and playground equipment (n=219) were examined. For the components that could be identified by CAS number, toxicological data on oral, inhalation, and dermal routes, cancer slope factor, and reference dose were collected. Results: Among the investigated products, KC marks or certification numbers were found for 4557 products (69.3%). Except for cosmetics and cleansers, the material information was labeled on most of the products. The frequency of labeling substance information in toys and stationary/books was low since this information could be omitted if KC certification was obtained. In the target products, 617 substances were identified by CAS number, and polypropylene, acrylonitrile butadiene styrene, and polyester were the most frequently displayed. Chronic toxicity data was found for only 32.4% of individual components, and information on toxicity through the dermal route was also highly limited. Conclusion: Our study suggested that labeling guidelines should be required to identify the environmentally hazardous substances contained in children's products. In addition, the toxicological data on many ingredients in children's products were insufficient. The data gap for toxicity data should be filled for future risk assessment.

• Journal of Korean Society on Water Environment
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• v.27 no.1
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• pp.104-109
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• 2011

The removal efficiencies of 2-methylisoborneol (MIB) and geosmin were investigated to reveal removal characteristics of typical organic compounds causing disagreeable taste and odor at the conventional water treatment plant installed with pulsator clarifier patented by the French company $Degr{\acute{e}}mont$. The injection rate of Powdered Activated Carbon (PAC) into water was changed step wisely as we conducted jar tests in the laboratory and water treatment in the actual plant. 2-MIB concentration decreased linearly while geosmin did exponentially along with the injection rate of PAC at our jar tests. The removal efficiency of geosmin by PAC injection was considerably higher than that of 2-MIB. In the real pulsator clarifier, 2-MIB concentration started decreasing as the injection rate reached up to 10 mg/L of PAC. On the other hand, the concentration of geosmin in water decreased proportional to the injection rate of PAC. In the sand filtration, removal efficiencies of 2-MIB and geosmin on July were much higher than those on March. It was carefully suggested beforehand and found afterwards that general microorganisms notably existed in the sand filter with no chlorine in filter influent and backwash water and the sand filter biologically activated removed much more odor compounds. It was considered as the reason why the removal efficiency of 2-MIB and geosmin was increased. The microbial activity maybe increased in summer with water temperature rising and low filtration rate possibly increased contact time between odor compounds and general microorganisms.

• Korean Journal of Metals and Materials
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• v.47 no.7
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• pp.416-422
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• 2009

Approaches for analyzing indentation hardness are still controversial, although the instrumented indentation technique has been generalized as one powerful method that can record surface deformation behaviors. Material pile-ups around the indenter/surface contact region make the conventional Oliver and Pharr's analysis on the instrumented indentation curve inaccurate. Thus, in order to prove the validity of the hardness analyses, five approaches were applied to the experimental data obtained from fused quartz and (100) monocrystalline tungsten specimens; an elastic recovery analysis on instrumented indentation curves, three indentation work analyses on the unit plastic volume, and a differentiation analysis on remnant indentation morphologies were tried. Five kinds of indentation hardness overlapped on one result plot showed the validity of each analysis. The modified indentation work approach based on a new definition of plastic volume showed consistent results with those from the Oliver-Pharr's and image differentiation methods. In the case of pile-up accompanying deformation, the Oliver-Pharr's and image differentiation methods showed the upper and lower limits of indentation hardness, respectively.

• Korean Journal of Chemical Engineering
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• v.35 no.11
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• pp.2241-2255
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• 2018

RSM methodology was applied to present mathematical models for the fabrication of polyvinylidene fluoride (PVDF) dual-layer hollow fibers in membrane distillation process. The design of experiments was used to investigate three main parameters in terms of polymer concentration in both outer and inner layers and the flow rate of dope solutions by the Box-Behnken method. According to obtained results, the optimization was done to present the proper membrane with desirable properties. The characteristics of the optimized membrane (named HF-O) suggested by the Box-Behnken (at the predicted point) showed that the proposed models are strongly valid. Then, a morphology study was done to modify the fiber by a combination of three types of a structure such as macro-void, sponge-like and sharp finger-like. It also improved the hydrophobicity of outer surface from 87 to $113^{\circ}$ and the mean pore size of the inner surface from 108.12 to 560.14 nm. The DCMD flux of modified fiber (named HF-M) enhanced 62% more than HF-O when it was fabricated by considering both of RSM and morphology study results. Finally, HF-M was conducted for long-term desalination process up to 100 hr and showed stable flux and wetting resistance during the test. These stepwise approaches are proposed to easily predict the main properties of PVDF dual-layer hollow fibers by valid models and to effectively modify its structure.

• Transactions of Materials Processing
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• v.30 no.3
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• pp.142-148
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• 2021

In hot forging analysis, the interfacial heat transfer coefficient (IHTC) is a very important factor defining the heat flow between the die and the material. In particular, in the hot forging analysis of aluminum 6xxx series alloy, which are used in automobile parts, differences in load and microstructure occur due to changes in surface temperature according to the IHTC. This IHTC is not a constant value but changes depends on pressure. This study derived the IHTC under low load using aluminum 6082 alloy. An experiment was performed by fabricating a compression die, and a heat transfer analysis was performed based on the experimental data. The heat transfer analysis used DEFORM-2D, a commercial finite element analysis program. To derive the IHTC, heat transfer analysis was performed for the IHTC in the range of 10 to 50 kW/m²℃ at intervals of 10kW/m²℃. The heat transfer analysis results according to the IHTC and the actual experimental values were compared to derive the IHTC of the aluminum 6082 alloy under low load.

• Korean Journal of Materials Research
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• v.31 no.7
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• pp.420-426
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• 2021

Graphene, a new material with various advantageous properties, has been actively used in various fields in recent years. Applications of graphene oxide are increasing in combination with other materials due to the different properties of graphene oxide, depending on the number of single and multiple layers of graphene. In this study, single-layer graphene oxide and multi-layer graphene oxide are spray coated on polystyrene, and the physicochemical properties of the coated surfaces are characterized using SEM, Raman spectroscopy, AFM, UV-Vis spectrophotometry, and contact angle measurements. In single-layer graphene oxide, particles of 20 ㎛ are observed, whereas a 2D peak is less often observed, and the difference in surface height increases according to the amount of graphene oxide. Adhesion increases with an increase in graphene oxide up to 0.375 mg, but decreases at 0.75 mg. In multi-layer graphene oxide, particles of 5 ㎛ are observed, as well as a 2D peak. According to the amount of graphene oxide, the height difference of the surface increases and the adhesive strength decreases. Both materials are hydrophilic, but single-layer graphene oxide has a hydrophilicity higher than that of multi-layer graphene oxide. We believe that multi-layer graphene oxide and single-layer graphene oxide can be implemented based on the characteristics that make them suitable for application.

• Steel and Composite Structures
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• v.37 no.6
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• pp.711-731
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• 2020

This paper deals with free vibration of FG sandwich annular sector plates on Pasternak elastic foundation with different boundary conditions, based on the three-dimensional theory of elasticity. The plates with simply supported radial edges and arbitrary boundary conditions on their circular edges are considered. The influence of carbon nanotubes (CNTs) waviness, aspect ratio, internal pores and graphene platelets (GPLs) on the vibrational behavior of functionally graded nanocomposite sandwich plates is investigated in this research work. The distributions of CNTs are considered functionally graded (FG) or uniform along the thickness of upper and bottom layers of the sandwich sectorial plates and their mechanical properties are estimated by an extended rule of mixture. In this study, the classical theory concerning the mechanical efficiency of a matrix embedding finite length fibers has been modified by introducing the tube-to-tube random contact, which explicitly accounts for the progressive reduction of the tubes' effective aspect ratio as the filler content increases. The core of structure is porous and the internal pores and graphene platelets (GPLs) are distributed in the matrix of core either uniformly or non-uniformly according to three different patterns. The elastic properties of the nanocomposite are obtained by employing Halpin-Tsai micromechanics model. A semi-analytic approach composed of 2D-Generalized Differential Quadrature Method (2D-GDQM) and series solution is adopted to solve the equations of motion. The fast rate of convergence and accuracy of the method are investigated through the different solved examples. Some new results for the natural frequencies of the plate are prepared, which include the effects of elastic coefficients of foundation, boundary conditions, material and geometrical parameters. The new results can be used as benchmark solutions for future researches.

• Steel and Composite Structures
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• v.38 no.2
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• pp.223-239
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• 2021

This paper presents the analytical modeling and finite element (FE) analysis, using ABAQUS software, of the new types of steel reinforced lightweight aggregate concrete (SRLAC) columns with cross-shaped (+shaped and X-shaped) steel section, using proposed three analytical and two FE models in total. The stress-strain material models for different components in the columns, including the confined zones of the lightweight aggregate concrete (LWAC) using three and four concrete zones divisions approaches and with and without taking into account the stirrups reaction effect, are established first. The analytical models for determining the axial load-deformation behavior of the SRLAC columns are drawn based on the materials models. The analytical and FE models' results are compared with previously reported test results of the axially loaded SRLAC columns. The proposed analytical and FE models accurately predict the axial behavior and capacities of the new types of SRLAC columns with acceptable agreements for the load-displacement curves. The LWAC strength, steel section ratio, and steel section configuration affect the contact stress between the concrete and steel sections. The average ratios of the ultimate test load to the three analytical models and FEA model loads, Put /Pa1, Put /Pa2, Put /Pa3, and Put /PFE1, for the tested specimens are 0.96, 1.004, 1.016, and 1.019, respectively. Finally, the analytical parametric studies are also studied, in terms of the effects of confinement, LWAC strength, steel section ratio, and the reinforcement ratio on the axial capacity of the SRLAC column. When concrete strength, confinements, area of steel sections, or reinforcement bars ratio increased, the axial capacities increased.

• Advances in nano research
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• v.10 no.3
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• pp.253-261
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• 2021

Polydimethylsiloxane (PDMS) is one of the most widely adopted silicon-based organic polymeric elastomers. Elastomeric nanostructures are normally required to accomplish an explicit mechanical role and correspondingly their mechanical properties are crucial to affect device and material performance. Despite its wide application, the mechanical properties of PDMS are yet fully understood. In particular, the time dependent mechanical response of PDMS has not been fully elucidated. Here, utilizing state-of-the-art PeakForce Quantitative Nanomechanical Mapping (PFQNM) together with Force Volume (FV) and Fast Force Volume (FFV), the elastic moduli of PDMS samples were assessed in a time-dependent fashion. Specifically, the acquisition frequency was discretely changed four orders of magnitude from 0.1 Hz up to 2 kHz. Careful calibrations were done. Force data were fitted with a linearized DMT contact mechanics model considering surface adhesion force. Increased Young's modulus was discovered with increasing acquisition frequency. It was measured 878 ± 274 kPa at 0.1 Hz and increased to 4586 ± 758 kPa at 2 kHz. The robust local probing of mechanical measurement as well as unprecedented high-resolution topography imaging open new avenues for quantitative nanomechanical mapping of soft polymers, and can be extended to soft biological systems.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.21 no.3
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• pp.56-62
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• 2022

The tank engine clutch flange constitutes a tank on which the engine and transmission of the tank are mounted. The engine clutch flange is fabricated using a difficult-to-cut material that exhibits high strength and hardness. It is difficult to process and requires considerable processing expertise. In addition, the engine clutch flange for the tank requires high machining precision because it is a system in which the connection is detachable. Because it requires high processing precision, the measurement of products equally important as processing. However, productivity is low owing to the significant amount of time required to measure each product using a three-dimensional coordinate measuring machine. Hence, this study is conducted to improve the productivity of the female tank engine clutch flange. Dedicated hobs and jigs are designed and manufactured to convert the existing end-mill cutting processing into hobbing cutting processing. An engine clutch for the tanks is manufactured using the manufactured dedicated hob and jig, and the shortening time is verified by measuring the processing time. In addition, a jig for inspection is designed and manufactured to measure the precision of the product. To verify the inspected product, the product precision is measured using a contact-type three-dimensional coordinate measuring machine and a surface roughness measuring instrument. The study confirmed that the productivity of the engine clutch flange product for tanks can be improved by simplifying the process, reducing the processing time, and simplifying product inspection.