• Title/Summary/Keyword: Constant potential

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Electrical Imaging of Thin Film Surface by Scanning Maxwell-stress Microscopy (주사형 맥스웰응력 현미경에 의한 표면의 전기적 이미지)

  • Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1508-1510
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    • 1998
  • Recent development of scanning probe microscope techniques has made it possible to investigate, not only microscopic surface topography, but also physical and chemical properties on the nanometer-scale. The scanning Maxwell-stress microscopy (SMM) is surface characterization tool capable of mapping both the surface topography and electrical properties, such as surface potential, surface charge dielectric constant of thin films with a nanometer-scale resolution by means of the AC voltage driven oscillation of metal coated cantilever. In this study, we observed the surface potential distribution and molecular ordering in thin films. We have demonstrated that the SMM can be used for imaging surface potential distribution over the film surface and also be used for detecting surface changes in thin films. This is first step towards the understanding of electrical phenomena in organic and inorganic materials, biological system with SMM.

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Growing High-Quality Ir-Sb Nanostructures by Controlled Electrochemical Deposition

  • Nisanci, Fatma Bayrakceken
    • Journal of Electrochemical Science and Technology
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    • v.11 no.2
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    • pp.165-171
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    • 2020
  • The electrochemical preparation and spectroscopic characterisation of iridium-antimony (Ir-Sb) species is important owing to their potential applications as nanostructure materials. Nanostructures, i.e. nanoflower and nanodisk, of Ir-Sb were electrodeposited on conductive substrates using a practical electrochemical method based on the simultaneous underpotential deposition (UPD) of Ir and Sb from the IrCl3 and Sb2O3 at a constant potential. Electrochemical UPD mechanism of Ir-Sb was studied using cyclic voltammetry and potential-controlled electrochemical deposition techniques. Herein, X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, X-ray photoelectron and Raman spectroscopy were used to determine the morphological and structural properties of the electrochemically-synthesised Ir-Sb nanostructures.

A Study on the IR Drop in Crevice of AISI 304 Stainless Steel by Temperature Variation (온도변화에 따른 AISI 304SS의 틈내 전위강하에 관한 연구)

  • 나은영
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.7
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    • pp.872-878
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    • 2003
  • As the results of recent industrial development, many industrial plants and marine structures are exposed to severe corrosion environment than before. Especially, under the wet environment, crevice corrosion damage problems necessarily occur and encourage many interests to prevent them. In this study, the electrochemical polarization test was carried out to study characteristics of crevice corrosion for AISI 304 stainless steel in various solution temperatures. The results are as follows ; 1) as the solution temperature increased in IN $\textrm{H}_2\textrm{SO}_4$, the passive current density and critical current density were increased, whereas corrosion potential and break down potential were nearly constant, 2) as the solution temperature increased. the induced time for initiation of crevice corrosion was shortened. 3) The potential range in the crevice was -220mV/SCE to -380mV/SCE according to the distance from the crevice opening, which is lower than that of external surface of -200mV/SCE.

The Response Characteristic of Hydrogen-responsive Glass Electrode in Methanol, N, N-dimethylformamide and Acetonitrile (Methanol, N,N-dimethylformamide 및 Acetonitrile 속에서 유리전극의 pH 응답성)

  • Su Chan Moon
    • Journal of the Korean Chemical Society
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    • v.16 no.3
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    • pp.149-156
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    • 1972
  • The responsive characteristics of hydrogen-responsive glass electrode in various buffer solutions of methanol, N,N-dimethylformamide and acetonitrile were examined. The potentials were attained more rapidly with an electrode stored in the same solvent medium than that stored in water before use. However, the time to be required for a stable potential increased with the basicity of buffer solution, and it was not provide a constant potential in the strong basic solution of these solvent. Even in acidic solution, the potential was varied according to the past usage of the electrode.

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Molecular Dynamics Study on the Behavior of a Carbon Nanotube (분자동역학을 이용한 탄소나노튜브의 거동 연구)

  • Huh, J.;Huh, H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.10a
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    • pp.348-351
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    • 2007
  • Simulations of the buckling behavior of a single wall carbon nanotube(SWCNT) was carried out using molecular dynamics simulation. Molecular dynamics simulations were done with 1fs of time step. Tersoff's potential function was used as the interatomic potential function since it has been proved to be reliable to describe the C-C bonds in carbon nanotubes. Compressive force was applied by moving the top end of the nanotube at a constant velocity. Buckling behavior under compressive load was observed for (15,15) armchair SWCNTs with 2nm of diameter and 24.9nm of length. Buckling load and critical strain is obtained from the MD simulation. Deformation occurred on the top region of the CNT because of fast downward velocity.

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Sulfur Redox Equilibrium in Mixed Alkali Silicate Glass Melts

  • Kim, Ki-Dong;Hwang, Jong-Hee
    • Journal of the Korean Ceramic Society
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    • v.48 no.3
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    • pp.205-210
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    • 2011
  • The dependence of sulfur redox behavior and its diffusivity on temperature and composition was studied in mixed alkali silicate melts by means of square wave voltammetry (SWV) at different frequencies in a temperature range of $1000^{\circ}C$ to $1400^{\circ}C$. The voltammograms showed two reduction peaks at high frequency but only one peak at low frequency. Irrespective of $K_2O/(Na_2O+K_2O)$, each peak potential due to reduction of $S^{6+}$ to $S^{4+}$ and $S^{4+}$ to $S^0$ moved toward a negative direction with temperature decrease, and the peak current showed a strong dependence on frequency at a constant temperature. However, the compositional dependence of the peak potential showed an inconsistent behavior with an increase of $K_2O$. The mixed alkali effect was not observed in sulfur diffusion. This inconsistency of both peak potential and diffusion for compositional dependence may be derived from the strong volatilization of sulfur in melts.

MONTE-CARLO SIMULATION OF NEUTRON STAR ORBITS IN THE GALAXY

  • TAANI, ALI
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.583-584
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    • 2015
  • In this paper, the numerical results concerning different orbits of a 3D axisymmetric non-rotating galactic potential are presented. We use $Paczy{\acute{n}}ski^{\prime}s$ gravitational potential with different birth velocity distributions for the isolated old Neutron Star (NS) population. We note some smooth non-constant segments corresponding to regular orbits as well as the characterization of their chaoticity. This is strongly related to the effect of different kick velocities due to supernovae mass-loss and natal kicks to the newly-formed NS. We further confirm that the dynamical motion of the isolated old NSs in the gravitational field becomes obvious, with some significant diffraction in the symmetry of their orbital characteristics.

Microbial BOD Sensor Using Hansenula anomala

  • Ihn Gwon-Shik;Park Kyung-Ho;Pek Un-Hua;Sohn Moo-Jeong
    • Bulletin of the Korean Chemical Society
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    • v.13 no.2
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    • pp.145-148
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    • 1992
  • A microbial sensor for BOD (Biochemical Oxygen Demand) measurement has been developed by immobilizing Hansenula anomala in a polyacrylamide gel. The optimum pH and temperature for BOD measurement using this sensor were pH 7.0 and $30^{\circ}C$, respectively. The response time was 30 min. A linear relationship was observed between the potential and the concentration below 44 ppm BOD. The potential was reproducible within ${\pm}9%$ of the relative error when a sample solution containing 20 mg/l of glucose and 20 mg/l of glutamic acid was employed. The effect of various compounds on BOD estimation was also examined. The potential output of the sensor was almost constant for 30 days. The relative error in BOD estimation was within ${\pm}10%$.

3-D Magnetostatic Field Analysis Using Boundary Element Method (경계요소법을 이용한 3차원 정자장해석)

  • Jeon, K.E.;Koh, C.S.;Jung, H.K.;Hahn, S.Y.
    • Proceedings of the KIEE Conference
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    • 1991.07a
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    • pp.97-101
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    • 1991
  • A three-dimensional magnetostatic problem is analyzed using the boundary element method and the magnetic scalar potential are employed in order to reduce the size of system matrix. Although the total magnetic scalar potential gives very accurate solutions in inner and outer regions of magnetic material, it has limitation on application because the magnetic scalar potential due to applied magnetic field sources is hard to be obtained. The reduced magnetic scalar potential gives more or less inaccurate solutions inside the magnetic material but very accurate solutions outside. Hence it can be concluded that the reduced magnetic scalar potential is very useful when the magnetic fields of outside magnetic material only are interested. It is also shown, from the numerical results, that the linear shape function gives more efficient solutions than the constant shape functions because the former gives more accurate solutions in spite of relatively fewer unknowns than the latter.

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Transport Properties of Lennard-Jones Mixtures: A Molecular Dynamics Simulation Study

  • Lee, Song-Hi
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.641-646
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    • 2008
  • Equilibrium molecular dynamics simulations in a canonical ensemble are performed to evaluate the transport coefficients of several Lennard-Jones (LJ) mixtures at a liquid argon states of 94.4 K and 1 atm via modified Green-Kubo formulas. Two component mixture of A and B is built by considering the interaction between A and A as the attractive (A) potential, that between A and B as the attractive potential (A), and that between B and B as the repulsive potential (R), labelled as AAR mixture. Three more mixtures - ARA, ARR, and RAR are created in the same way. The behavior of the LJ energy and the transport properties for all the mixtures is easily understood in terms of the portion of attractive potential (A %). The behavior of the thermal conductivities by the translational energy transport due to molecular motion exactly coincides with that of diffusion constant while that of the thermal conductivities by the potential energy transport due to molecular motion is easily understood from the fact that the LJ energy of AAR, ARR, and RAR mixtures increases negatively with the increase of A % from that of the pure repulsive system while that of ARA changes rarely.