• Title/Summary/Keyword: Constant potential

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A Study of Over Voltage Ground Relay Operation Status at Opening of No-load Charged Cable (무부하 충전케이블 개방시 잔류전압에의한 과전압계전기 동작현상 연구)

  • Kim, Yeong-Han;Choi, Jong-Hyuck;Yoon, Ki-Seob
    • Proceedings of the KIEE Conference
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    • 2000.07a
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    • pp.185-187
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    • 2000
  • Fault current is flowed into 154/23kV M. Tr when line-to-ground fault occurs in power system. NGR(Neutral Grounded Reactor) is set up in order to prevent M.Tr fault by limiting magnitude of fault currents. Here, disconnection of NGR causes voltage increase by L-C resonance and line-to-ground fault in an unearthed system results in voltage increase at healthy phases. So Over Voltage Ground Relay(OVGR) is used for tripping M.Tr. Also, buses at second phases of M.Trs are all connected with section circuit breakers closed for the purpose of parallel operation and load shedding. In case of speciality buses are comprised of power cable in part for GIS connection. When no-load charged cable or bus is open by a section CB, unbalanced voltage charged on the bus is induced. Also discrepant opening time for circuit breakers on different phases gives rise to unbalanced zero sequence voltage. It was observed that this zero sequence voltage detected in the 22.9kV P.T (Potential Transformer for bus) mal-operated 59GT and tripped M.Tr. The zero sequence voltage of which vanishing time is longer than relay operating time came out by EMTDC simulation. Also, it was shown that the voltage waves of actual test are similar to those of simulation. On the basis of above results, R-C circuit complement on the relay without any effect on a power system made operating time of the relay longer than vanishing time of distorted waves. Consequently, operating time of the relay was delayed and magnitude of distorted waves was decreased by increasing time constant of the relay.

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Electrochemical Characteristics at Copolymeric film Electrodes of [Ru(v-bpy)$_3$]$^{2+}$ and Vinylbenzoic Acid Modified with Dopamine (Dopamine으로 수식된 [Ru(v-bpy)$_3$$^{2+}$와 Vinylbenzoic Acid의 공중합 피막 전극의 전기화학 특성)

  • 차성극;박유철;임태곤
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.782-788
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    • 2001
  • The $[Ru(v-bpy)_3]^{2+}$ and vinylbenzoic acid (vba) were electrochemically copolymerized to afford electrodes modified with dopamine to study their properties such as electropolymerization rate, redox process, and electron transfer. The optimum mole ratio of the monomers was 5:2, which gave $1.84{ imes}10^{-2}s^{-1}$ of rate constant for first order reaction, while the ratio of the substances on the copolymeric film produced was 5:1.68. The formal potential produced from the hydroquinone=quinone+$2H^+2e^-$reaction at the electrode of GC/p- $[Ru(v-bpy)_3]^{2+}$/vba-dopamine was 0.17 V in phosphate buffer (pH=7.10). The electrocatalytic rate was $2.58{ imes}10^5cms^{-1}$;2.41 times faster than that of non-modified one. The mass change measured by EQCM was $3.28{ imes}10^3$$gmol^{-1}$ which is larger than that of non-modified one.

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Synthesis of Chiral Poly(norbornene carboxylic acid ester)s and Their Characteristic Properties in The Thin Film

  • Byun, Gwang-Su;Lee, Taek-Joon;Jin, Kyeong-Sik;Ree, Moon-Hor;Kim, Sang-Youl;Cho, I-Whan
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.333-333
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    • 2006
  • We synthesized two novel polynorbornene derivatives, chiral poly(norbornene acid methyl ester) (C-PNME) and racemic poly(norbornene acid n-butyl ester) (R-PNME), which are potential low dielectric constant materials for applications in advanced microelectronic and display devices. Thin films of these polymers deposited on substrates were investigated by structural analyses using synchrotron grazing incidence X-ray scattering, specular reflectivity and ellipsometry. These analyses provided important information on the structure, electron density gradient across film thickness, chain orientation, refractive index and thermal expansion of the polymers in substrate-supported thin films. The structural characteristics and properties of the thin films were first dependent on the polymer chain' tacticity and further influenced by film thickness and thermal annealing.

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A Cost-effective Light Emitting Diode-acoustic System for Preclinical Ocular Applications

  • Choi, Hojong;Ryu, Jaemyung;Yeom, Jung-Yeol
    • Current Optics and Photonics
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    • v.2 no.1
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    • pp.59-68
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    • 2018
  • Opto-acoustic systems provide structural and functional information regarding biological tissues. Conventional opto-acoustic systems typically employ continuous or pulsed lasers as transmission sources. Compared to lasers, light emitting diodes (LEDs) are cost-effective and relatively portable excitation sources but are non, coherent. Therefore, in this study, a relatively low cost lens - a type of Ramsden eyepiece - was specially designed to theoretically calculate the illumination and achieve a constant brightness across the pupil of an eye. In order to verify the capability of the developed light-emitting diode-acoustic (LEDA) systems, we carried out experiments on bovine and bigeye tuna eyeball samples, which are of similar size to the human eye, using low frequency (10 MHz) and high frequency (25 MHz) ultrasound transducers. High frequency ultrasound transducers are able to provide higher spatial resolution compared to low frequency ultrasound transducers at the expense of penetration depth. Using the 10 MHz and 25 MHz ultrasound transducers, acceptable echo signals (3.82, 3.94, and 5.84 mV at 10 MHz and 282, 1557, 2356 mV at 25 MHz) from depth greater than 3 cm and 6 cm from the anterior surface of the eye were obtained. We thereby confirmed that the LEDA system using a pulsed LED with the designed Ramsden eyepiece lens, used in conjunction with low and high frequency ultrasound transducers, has the potential to be a cost-effective alternative method, while providing adequate acoustic signals from bovine and bigeye tuna ocular areas.

Electrical Properties of $(Ba,Sr)_{1-x}Y_xTiO_3$ with Variation of Yttrium Content (이트륨 혼입량 변화에 따른 $(Ba,Sr)_{1-x}Y_xTiO_3$의 전기적 특성)

  • Noh, Taeyong;Sung, Hyun Je;Kim, Seungwon;Lee, Chul
    • Journal of the Korean Chemical Society
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    • v.39 no.10
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    • pp.806-811
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    • 1995
  • The electrical properties for $(Ba,Sr)_{1-x}Y_xTiO_3$(x=0.001∼0.009, BSYT) with a positive temperature coefficient of resistivity(PTCR) effect were investigated. The BSYT powder was prepared by oxalate coprecipitation method. It was found that the large PTCR effect was appeared up to 0.3 mol% and decreased above 0.5 mol% of the yttrium concentration. The plot of temperature vs. $1{\varepsilon}$m(T) above Curie temperature($T_c$) was agreed with Curie-Weiss law. The potential barrier calculated from measured resistivity and dielectric constant of specimens was high up to 0.3 mol% and reduced above 0.5 mol% of yttrium concentration as the curve of PTCR effect.

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Effectiveness of Feather Waste for Orange II Removal from Aqueous Solutions (수용액 중 Orange II 흡착 제거를 위한 우모폐기물의 이용가능성)

  • Park, Soo-Yeun;Yoo, Ji-Yeon;Son, Hong-Joo
    • Journal of Environmental Science International
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    • v.27 no.9
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    • pp.743-751
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    • 2018
  • The objective of this study was to investigate the adsorption potential of chicken feathers for the removal of OrangeII (AO7) from aqueous solutions. Batch experiments were performed as a function of different experimental parameters such as initial pH, reaction time, feather dose, initial OrangeII concentration and temperature. The highest OrangeII uptake was observed at pH 1.0. Most of the OrangeII was adsorbed at 2 h and an adsorption equilibrium was reached at 6 h. As the amount of chicken feather was increased, the removal efficiency of OrangeII increased up to 99%, but its uptake decreased. By increasing the initial concentration and temperature, OrangeII uptake was increased. The experimental adsorption isotherm exhibited a better fit with the Langmuir isotherm than with the Freundlich isotherm, and maximum adsorption capacity from the Langmuir constant was determined to be 0.179244 mmol/g at $30^{\circ}C$. The adsorption energy obtained from the Dubinin-Radushkevich model was 7.9 kJ/mol at $20^{\circ}C$ and $30^{\circ}C$ which indicates the predominance of physical adsorption. Thermodynamic parameters such as ${\Delta}G^0$, ${\Delta}H^0$, and ${\Delta}S^0$ were -12.28 kJ/mol, 20.64 kJ/mol and 112.32 J/mol K at $30^{\circ}C$, respectively. This indicates that the process of OrangeII adsorption by chicken feathers was spontaneous and endothermic. Our results suggest that as a low-cost biomaterials, chicken feather is an attractive candidate for OrangeII removal from aqueous solutions.

Experimental and Numerical Study on Slamming Impact

  • Kwon, Sun Hong;Yang, Young Jun;Lee, Hee Sung
    • Journal of Ocean Engineering and Technology
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    • v.27 no.1
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    • pp.1-8
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    • 2013
  • This paper presents the results of experimental and numerical research on the slamming phenomenon. Two experimental techniques were proposed in this study. The traditional free drop tests were carried out. However, the free drop tests done in this study using an LM guide showed excellent repeatability, unlike those of other researchers. The coefficients of variation for the drop test done in this experiment were less than 0.1. The other experimental technique proposed in this study was a novel concept that used a pneumatic cylinder. The pneumatic cylinder could accelerate the specimen over a very short distance from the free surface. As a result, high rates of repeatability were achieved. In the numerical study, the development of in-house code and utilization of commercial code were carried out. The in-house code developed was based on the boundary element method. It is a potential code. This was mostly applied to the computation of the wedge entry problem. The commercial code utilized was FLUENT. Most of the previous slamming research was done under the assumption of a constant body velocity all through the impact process, which is not realistic at all. However, the interaction of a fluid and body were taken into account by employing a user-defined function in this study. The experimental and numerical results were compared. The in-house code based on BEM showed better agreement than that of the FLUENT computation when it cames to the wedge computation. However, the FLUENT proved that it could deal with a very complex geometry while BEM could not. The proposed experimental and numerical procedures were shown to be very promising tools for dealing with slamming problems.

Review on the Determination of Frumkin, Langmuir, and Temkin Adsorption Isotherms at Electrode/Solution Interfaces Using the Phase-Shift Method and Correlation Constants

  • Chun, Jinyoung;Chun, Jang H.
    • Korean Chemical Engineering Research
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    • v.54 no.6
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    • pp.734-745
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    • 2016
  • This review article described the electrochemical Frumkin, Langmuir, and Temkin adsorption isotherms of over-potentially deposited hydrogen (OPD H) and deuterium (OPD D) for the cathodic $H_2$ and $D_2$ evolution reactions (HER, DER) at Pt, Ir, Pt-Ir alloy, Pd, Au, and Re/normal ($H_2O$) and heavy water ($D_2O$) solution interfaces. The Frumkin, Langmuir, and Temkin adsorption isotherms of intermediates (OPD H, OPD D, etc.) for sequential reactions (HER, DER, etc.) at electrode/solution interfaces are determined using the phase-shift method and correlation constants, which have been suggested and developed by Chun et al. The basic procedure of the phase-shift method, the Frumkin, Langmuir, and Temkin adsorption isotherms of OPD H and OPD D and related electrode kinetic and thermodynamic parameters, i.e., the fractional surface coverage ($0{\leq}{\theta}{\leq}1$) vs. potential (E) behavior (${\theta}$ vs. E), equilibrium constant (K), interaction parameter (g), standard Gibbs energy (${\Delta}G_{\theta}{^{\circ}}$) of adsorption, and rate (r) of change of ${\Delta}G_{\theta}{^{\circ}}$ with ${\theta}$ ($0{\leq}{\theta}{\leq}1$), at the interfaces are briefly interpreted and summarized. The phase-shift method and correlation constants are useful and effective techniques to determine the Frumkin, Langmuir, and Temkin adsorption isotherms and related electrode kinetic and thermodynamic parameters (${\theta}$ vs. E, K, g, ${\Delta}G_{\theta}{^{\circ}}$, r) at electrode/solution interfaces.

A study on measurement of physical parameters using electromagnetic wave of the compacted saturated soil (고주파수 전자기파를 이용한 압밀 포화토 물성치 측정을 위한 연구)

  • Kim, Man-Il;Kim, Hyoung-Soo;Suk, Hee-Jun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.354-361
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    • 2005
  • Physical parameters such as porosity and effective porosity are important physical parameters that determine the transfer and movement of water and solutes in porous media. Various methods of determining these parameters have been developed, with varying degrees of accuracy and applicability. Most of the existing methods produce static results. They do not produce instantaneous and real time of porosity and effective porosity in a porous media. In this study, a new permittivity method called Frequency Domain Reflectometry with Vector analyzer (FDR-V) is proposed to determine the porosity and effective porosity of some sand samples in the laboratory. The advantage of the FDR-V method is that it instantaneously determines the temporal variation of dielectric constants of porous media. Then, the porosity and the effective porosity of porous media are computed using well established empirical equations. Results obtained from the FDR-V method compared favorably with results from other permittivity methods such as gravimetric, injection and replacement tests. The ratio of effective porosity to porosity was $85{\sim}92%$, when FDR-V was used. This value compared favourably with 90%, which has been usually quoted in previous studies. Considering the convenience and its applicability, the measurement system of FDR-V permittivity holds a great potential in porous media and contaminant transport studies.

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Protein Binding of [S]-Perillyl Alcohol in HSA using High-Performance Frontal Analysis (HPFA를 이용한 HSA와 [S]-Perillyl Acohol의 단백질 결합력)

  • 송명석;왕덕선;구윤모;노경호
    • KSBB Journal
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    • v.18 no.2
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    • pp.100-106
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    • 2003
  • An on-line frontal analysis HPLC system was developed to determine the unbound concentration of (S)-perillyl alcohol, an potential anti-cancer agent, in human serum albumin (HSA) solution, The analysis was performed on a Develosil 100 Diol 5 (10 cm x 4.6 mm I.D.) high-performance frontal analysis (HPFA) column. Sodium phosphate solution was used as the mobile phase (pH 7.4, ionic strength 0.17) at a flow rate of 1 $m\ell$/min. UV wavelength was set at 205 nm. A injection volume of 600${mu}ell$ was chosen to ensure the compound eluted formed a zonal peak with a plateau. By Scatchard analysis, it was found that the binding constant(K) and binding number(n) of (S)-perillyl alcohol to molecular HSA were 2.05 x $10^6$ [$M{-1}$], 0.00428, respectively.