• Title/Summary/Keyword: Constant potential

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Applying methane and carbon flow balances for determination of first-order landfill gas model parameters

  • Park, Jin-Kyu;Chong, Yong-Gil;Tameda, Kazuo;Lee, Nam-Hoon
    • Environmental Engineering Research
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    • v.25 no.3
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    • pp.374-383
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    • 2020
  • Landfill gas (LFG) emissions from a given amount of landfill waste depend on the carbon flows in the waste. The objective of this study was to more accurately estimate the first-order decay parameters through methane (CH4) and carbon flow balances based on the analysis of a full-scale landfill with long-term data and detailed field records on LFG and leachate. The carbon storage factor for the case-study landfill was 0.055 g-degradable organic carbon (DOC) stored per g-wet waste and the amounts of DOC lost with the leachate were less than 1.3%. The appropriate CH4 generation rate constant (k) for bulk waste was 0.24 y-1. The the CH4 generation potential (L0) values ranged 33.7-46.7 m3-CH4 Mg-1, based on the fraction of DOC that can decompose (DOCf) value of 0.40. Results show that CH4 and carbon flow balance methods can be used to estimate model parameters appropriately and to predict long-term carbon emissions from landfills.

Effects of Salinity on Demographic Traits of the Rotifer (Brachionus rotundiformis)

  • Viayeh Reza Malekzadeh;Song Choon Bok
    • Fisheries and Aquatic Sciences
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    • v.7 no.1
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    • pp.39-45
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    • 2004
  • Six demographic parameters including life span (LS), maturation time (MT), net reproduction rate (Ro), mean generation length (G), innate capacity for increase $(r_m)$ and finite rate of increase $(\gamma)$ were estimated in the rotifer (Brachionus rotundiformis) cultured at three salinities of 5, 20 and 34 PSU and under a constant temperature of $28^{\circ}C$. The maximum life spans at salinities of 5, 20 and 34 PSU were 17, 12 and 13 days, respectively. The shortest maturation time (24 hr) was recorded at 5 PSU, and the rotifer at 20 PSU showed a most delayed maturation (192 hr). The maximum reproduction rate was 42 offspring per female in rotifer cultured at 5 PSU, while the longest generation length (8 days) was observed at 20 PSU. Maximum and minimum values of $r_m$ (1.56 and 0.46 individual per day) and $(\gamma)$ (6.67 and 1.70 individuals per day) were calculated at 5 and 34 PSU, respectively. Salinity also showed strong effect on correlation of the demographic traits examined. ANOVA revealed significant differences (P<0.05) between demographic parameters of the rotifer at the three salinity condition. Considering the higher values of life span, innate capacity and finite rate of increase, and shortest maturation time at 5 PSU, the rotifer we examined had a higher reproductive potential and longer life span at 5 PSU rather than at 20 or 34 PSU.

Effective Admission Policy for Multimedia Traffic Connections over Satellite DVB-RCS Network

  • Pace, Pasquale;Aloi, Gianluca
    • ETRI Journal
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    • v.28 no.5
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    • pp.593-606
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    • 2006
  • Thanks to the great possibilities of providing different types of telecommunication traffic to a large geographical area, satellite networks are expected to be an essential component of the next-generation internet. As a result, issues concerning the designing and testing of efficient connection-admission-control (CAC) strategies in order to increase the quality of service (QoS) for multimedia traffic sources, are attractive and at the cutting edge of research. This paper investigates the potential strengths of a generic digital-video-broadcasting return-channel-via-satellite (DVB-RCS) system architecture, proposing a new CAC algorithm with the aim of efficiently managing real-time multimedia video sources, both with constant and high variable data rate transmission; moreover, the proposed admission strategy is compared with a well-known iterative CAC mainly designed for the managing of real-time bursty traffic sources in order to demonstrate that the new algorithm is also well suited for those traffic sources. Performance analysis shows that, both algorithms guarantee the agreed QoS to real-time bursty connections that are more sensitive to delay jitter; however, our proposed algorithm can also manage interactive real-time multimedia traffic sources in high load and mixed traffic conditions.

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Elucidation of Electrode Reaction of EuCl3 in LiCl-KCl Eutectic Melts through CV Curve Analysis

  • Kim, Tack-Jin;Jung, Yong-Ju;Kim, Si-Hyung;Paek, Seung-Woo;Ahn, Do-Hee
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.863-866
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    • 2011
  • The electrode reaction of $Eu^{3+}$ in a LiCl-KCl eutectic melt has been re-examined using cyclic voltammetry (CV). In this work, for the first time, the kinetic details of a $Eu^{3+}/Eu^{2+}$ redox system have been completely elucidated, along with the thermodynamic property, through a curve fitting applied to experimental CV data, which were obtained in a wide scan rate range of 0.5 to 10 V/s. The simulated results showed an excellent fit to all experimental CV data simultaneously, even though the curve fittings were performed within a large dynamic range of initial transfer coefficient values, formal potentials, and standard rate constants. As a result, a proper formal potential, transfer coefficient, and standard rate constant for the $Eu^{3+}/Eu^{2+}$ redox system were successfully extracted using the CV curve fitting.

Manganese(II) Ion-Selective Membrane Electrode Based on N-(2-picolinamido ethyl)-Picolinamide as Neutral Carrier

  • Aghaie, M.;Giahi, M.;Zawari, M.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2980-2984
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    • 2010
  • A new poly (vinyl chloride) (PVC) membrane electrode that is highly selective to $Mn^{+2}$ ions was prepared using N,N'-bis(2'-pyridinecarboxamide)-1,2-ethane ($bpenH_2$) as a suitable neutral carrier. This concentration range ($1.0{\times}10^{-5}$ to $1.0{\times}10^{-1}\;M$) with Nernstian slope of $29.3{\pm}0.5\;mV$ per decade. The detection limit and the response time of electrode were $8.0{\times}10^{-6}\;M$ and (${\leq}15\;s$) respectively. The membrane can be used for more than two months without observing any divergence. The electrodes exhibited excellent selectivity for $Mn^{+2}$ ion over other mono-, di- and trivalent cations. Selectivity coefficients were determined by the matched potential method (MPM). The electrode can be used in the pH range from 4.0 - 9.0. The isothermal coefficient of this electrode amounted to 0.00023 V/$^{\circ}C$. The stability constant (log $K_s$) of the $Mn^{+2}$ - $bpenH_2$ complex was determined at $25^{\circ}C$ by potentiometric titration in mixed aqueous solution. The proposed electrode was applied to the determination of $Mn^{+2}$ ions in real samples.

Analysis of Flow Rate Inducing Voltage Loss in a 100 cm2 Class Molten Carbonate Fuel Cell

  • Lee, Choong-Gon
    • Journal of Electrochemical Science and Technology
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    • v.2 no.1
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    • pp.20-25
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    • 2011
  • This work focuses on the behavior of the overpotential increase due to a utilization rise in a molten carbonate fuel cell. The behavior is generally explained by Nernst loss, which is a kind of voltage loss due to the thermodynamic potential gradients in a polarization state due to the concentration distribution of reactant species through the gas flow direction. The evaluation of Nernst loss is carried out with a traditional experimental method of constant gas utilization (CU). On the other hand, overpotential due to the gas-phase mass-transport resistance at the anode and cathode shows dependence on the utilization, which can be measured using the inert gas step addition (ISA) method. Since the Nernst loss is assumed to be due to the thermodynamic reasons, the voltage loss can be calculated by the Nernst equation, referred to as a simple calculation (SC) in this work. The three values of voltage loss due to CU, ISA, and SC are compared, showing that these values rise with increases in the utilization within acceptable deviations. When we consider that the anode and cathode reactions are significantly affected by the gas-phase mass transfer, the behavior strongly implies that the voltage loss is attributable not to thermodynamic reasons, namely Nernst loss, but to the kinetic reason of mass-transfer resistance in the gas phase.

Reduction of biofouling using vanillin as a quorum sensing inhibitory agent in membrane bioreactors for wastewater treatment

  • Nam, AnNa;Kweon, JiHyang;Ryu, JunHee;Lade, Harshad;Lee, ChungHak
    • Membrane and Water Treatment
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    • v.6 no.3
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    • pp.189-203
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    • 2015
  • Membrane biofouling impedes wide application of membrane bioreactor (MBR) for wastewater treatment. Recently, quorum sensing (QS) mechanisms are accounted for one of major mechanisms in biofouling of MBRs. In this study, vanillin was applied to investigate reduction of biofouling in MBRs. MBR sludge was analyzed to contain QS signal molecules by cross-feeding biosensor assay and HPLC. In addition, the inhibitory activity of vanillin against bacterial quorum sensing was verified using an indicator strain CV026. The vanillin doses greater than 125 mg/L to 100 mL of MBR sludge showed 25% reduction of biofilm formed on the membrane surfaces. Two MBRs, i.e., a typical MBR as a control and an MBR with vanillin, were operated. The TMP increases of the control MBR were more rapid compared to those of the MBR with the vanillin dose of 250 mg/L. The treatment efficiencies of the two MBRs on organic removal and MLSS were maintained relatively constant. Extracellular polymeric substance concentrations measured at the end of the MBR operation were 173 mg/g biocake for the control MBR and 119 mg/g biocake for the MBR with vanillin. Vanillin shows great potential as an anti-biofouling agent for MBRs without any interference on microbial activity for wastewater treatment.

Reducing Peak Cooling Demand Using Building Precooling and Modified Linear Rise of Indoor Space Temperature (건물예냉과 실내온도의 선형상승에 의한 피크냉방수요 저감)

  • Lee, Kyoung-Ho;Yang, Seung-Kwon;Han, Seung-Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.2
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    • pp.86-96
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    • 2010
  • The paper describes development and evaluation of a simple method for determining gradient of modified linear setpoint variation to reduce peak electrical cooling demand in buildings using building precooling and setpoint adjustment. The method is an approximated approach for minimizing electrical cooling demand during occupied period in buildings and involves modified linear adjustment of cooling setpoint temperature between $26^{\circ}C$ and $28^{\circ}C$. The gradient of linear variation or final time of linear increase is determined based on the cooling load shape in conventional cooling control having a constant setpoint temperature. The potential to reduce peak cooling demand using the simple method was evaluated through building simulation for a calibrated office building model considering four different weather conditions. The simple method showed about 30% and 20% in terms of reducing peak cooling demand and chiller power consumption, respectively, compared to the conventional control.

Temporal changes in mitochondrial activities of rat heart after a single injection of iron, including increased complex II activity

  • Kim, Mi-Sun;Song, Eun-Sook
    • Animal cells and systems
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    • v.14 no.2
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    • pp.91-98
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    • 2010
  • Male rats were given a single injection of iron, and temporal changes in iron content and iron-induced effects were examined in heart cellular fractions. Over a period of 72 h, the contents of total and labile iron, reactive oxygen species, and NO in tissue homogenate, nuclear debris, and postmitochondrial fractions were mostly constant, but in mitochondria they continuously increased. An abrupt decrease in membrane potential and NAD(P)H at 12 h was also found in mitochondria. The respiratory control ratio was reduced slowly with a slight recovery at 72 h, suggesting uncoupling by iron.While the ATP content of tissue homogenate decreased steadily until 72 h, it showed a prominent increase in mitochondria at 12 h. Total iron and calcium concentration also progressively increased in mitochondria over 72 h. Enzyme activity of the oxidative phosphorylation system was significantly altered by iron injection: activities of complexes I, III, and IV were reduced considerably, but complex II activity and the ATPase activity of complex V were enhanced. A reversal of activity in complexes I and II at 12 h suggested reverse electron transfer due to iron overload. These results support the argument that mitochondrial activities including oxidative phosphorylation are modulated by excessive iron.

Utilization of Heat from Waste-Incineration Facility for Heating Large-Scale Horticultural Facilities (소각시설 여열을 이용한 대규모 시설원예 단지의 난방 시스템 적용 가능성 평가)

  • Lee, Jaeho;Hyun, Intak;Lee, Kwang Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.27 no.8
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    • pp.418-425
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    • 2015
  • The Korean government plans to establish large-scale horticultural facilities using reclaimed land to improve the competitiveness of the national agricultural sector at the government level. One of the most significant corresponding problems is the ongoing dependence of these facilities on fossil fuel, whereby constant heating is necessary during the winter season to provide the necessary breeding conditions for greenhouse crops. In particular, high-level energy consumption is incurred from the use of heating-related coverings with large heat-transmission coefficients such as those composed of vinyl and glass. This study investigated the potential applicability of waste-incineration heat for use in large-scale horticultural facilities by evaluating the hot-water temperature, heat loss, and available greenhouse area as functions of the distance between the incineration facility and the greenhouse. In conclusion, waste-incineration heat from a HDPE pipe can heat a horticultural facility of 10 ha if the distance is less than 8 km.