• Bulletin of the Korean Chemical Society
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• 제34권1호
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• pp.243-245
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• 2013

Rate equations are exactly solved for the reversible consecutive reaction of the first-order and the time-dependence of concentrations is analytically determined for species in the reaction. With the assumption of pseudo first-order reaction, the calculation applies and determines the concentration of product accurately and explicitly as a function of time in the unimolecular decomposition of Lindemann and in the enzyme catalysis of Michaelis-Menten whose rate laws have been approximated in terms of reactant concentrations by the steady-state approximation.

• Bulletin of the Korean Chemical Society
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• 제16권4호
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• pp.310-315
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• 1995

The heterobimetallic anion, (OC)5CrMn(CO)5-M+ (M+=Na+, PPN+), which has a donor-acceptor metal-metal bond1, was reacted with allyl bromide to yield BrCr(CO)5- and Mn(CO)5(CH2CHCH2). The reaction mechanism has been proposed in terms of the consecutive reaction pathway in which Cr(CO)5(THF) is an important intermediate leading to the corresponding product. Counterion effect on this reaction was also evaluated and the results were compared with those of the corresponding reaction of the mononuclear carbonyl anion, Mn(CO)5-.

• 대한토목학회논문집
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• 제31권1D호
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• pp.65-72
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• 2011

고속도로 분기부 연결로상에서는 연속되는 유출형태가 나타나게 되어, 주행상의 안전성을 고려한 1차, 2차 분류지점 간 적정 이격거리(L)를 확보하는 것은 매우 중요한 사항이다. 본 연구에서는 현행 도로설계 지침에서 제시한 240m라는 동일한 설계기준을 적용하는 대신에, 동 구간에서 운전자에게 필요한 인지반응시간과 차로변경시간을 고려한 적정 이격거리를 산정하는 방식을 제안하였다. 특히 인지반응시간과 관련하여 정지시거 계산에 활용되는 기존의 2.5초와 더불어 기하구조 상의 특성을 고려한 판단시거 계산에 활용되는 보다 긴 인지반응시간을 추가적으로 고려하였다. 더불어 적정 이격거리 산정의 타당성을 확인하기 위해 고속도로 분기점 중 사고가 잦은 네 개의 분기점을 대상으로 교통사고 발생현황을 조사하여, 본 연구에서 검토한 적정 이격거리 산정방법을 적용하여 최소 이격거리를 도출하여 보았다. 연구 결과, 현재의 기준치가 정지시거를 중심으로 할 때는 충분한 최소 이격거리를 제시하고 있지만 판단시거를 중심으로 할 때는 충분하지 못하다는 점을 확인할 수 있었다. 사고가 잦은 현장에서 조사한 차량들의 실제 주행속도가 설계속도와 비교해 월등히 높은 점을 감안한다면, 지침에서 제시하는 것과 같은 획일적인 이격거리의 적용보다는 예상되지 못한 상황을 가정하여 적정 이격거리를 구하게 되는 판단시거를 중심으로 한 이격거리 계산과 설계가 오히려 더 설득력 있을 것으로 사료된다.

• 한국세라믹학회지
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• 제15권1호
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• pp.21-27
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• 1978

Hadong Kaolin (Halloysite) was granulated cylindrically and treated with 1N aqueous sodium hydroxide solution for 6-48 hrs at 60-10$0^{\circ}C$. The crystalling structure of surface of the products was studied by X-ray powder diffraction method. The reaction rate of halloysite to sodium A zeolite showed a gradual decrease from surface to inner layer. At the surface layer, the reaction mechanism was observed as first order consecutive reaction as follows: halloysitelongrightarrowamorphous aluminosilicatelongrightarrowsodium A zeolitelongrightarrowhydroxysodalite By applying the above reaction mechanism, the rate constants and activation energies was measured.

• Bulletin of the Korean Chemical Society
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• 제32권4호
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• pp.1387-1390
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• 2011

• Journal of Applied Biological Chemistry
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• 제48권2호
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• pp.97-100
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• 2005

Chiral dienophile 5 was synthesized from D-glucose by consecutive diisopropylidenation, partial deprotection, diol cleavage, and Wittig reactions. Under thermal conditions, asymmetric Diels-Alder reaction between chiral dienophile and cyclopentadiene gave four possible chiral norbornenes stereoisomers whose absolute configurations were determined through CADD and NMR.

• Bulletin of the Korean Chemical Society
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• 제15권6호
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• pp.448-452
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• 1994

2-Hydroxymethyl-2,5-dihydrothiophene 1,1-dioxide (1) was prepared from thiophene-2-carboxylic acid by consecutive reactions involving the Birch reduction, esterification, reduction with lithium aluminum hydride, and oxidation with Oxone$^{\circledR}$. The esterification of alcohol 1 with various unsaturated carboxylic acids provided the precursors 8 for the intramolecular Diels-Alder reaction. The cheletropic expulsion of sulfur dioxide from the esters 8 followed by intramolecular Diels-Alder reaction furnished bicyclic ${\gamma}$-and ${\delta}$-lactones.

• Clinics in Shoulder and Elbow
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• 제27권1호
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• pp.45-51
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• 2024

Background: It is essential to distinguish between symptomatic- and asymptomatic radiographic acromioclavicular (AC) osteoarthritis (OA) because AC-targeted physical examinations are dubious. This study aimed to determine the diagnostic value of a preoperative AC injection in discriminating between symptomatic- and asymptomatic radiographic AC OA based on patient arthroscopic distal clavicle resection (aDCR) outcomes. Methods: Forty-eight patients who underwent aDCR for AC OA were included. Their satisfaction was objectified using a 5-point Likert scale and patient willingness to repeat the surgery. The Oxford Shoulder Score (OSS), the Subjective Shoulder Value (SSV), and the Numerical Rating Scale (NRS) were used to assess postoperative shoulder function and pain. Patients were subdivided into groups based on their good or minimal reaction to an AC injection (good reaction: ≥7 consecutive days of pain reduction, Minimal reaction: <7 consecutive days of pain reduction). Results: Twenty-seven patients had a good reaction and 21 patients had a minimal reaction to the AC injection (median follow-up, 45.0 months; range, 31.0-52.8 months). No significant differences were found in level of satisfaction (P=0.234) or willingness to repeat the surgery (P=0.861). No significant differences were found in OSS (P=0.612), SSV (P=0.641), NRS at rest (P=0.684) or during activity (P=0.422). Conclusions: This study found no significant differences between patients with a good reaction or a minimal reaction to an AC injection after aDCR surgery. The outcomes of this study seem to suggest that a distinction between symptomatic and asymptomatic radiographic AC OA is unnecessary, as all patients were equally satisfied with the outcome.

• Bulletin of the Korean Chemical Society
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• 제34권5호
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• pp.1477-1480
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• 2013

The Suzuki cross-coupling reactions proceeded in excellent yields when it was catalyzed by magnetically recyclable nanocatalyst. This nanocatalyst provided very high catalytic activity with low loading level (1 mol %), because the palladium nanoparticles were so small in size (~2 nm) and located on the surface of the nanocomposite. It was also easily recovered from the reaction mixture using a magnet and reused for six consecutive cycles.

• Bulletin of the Korean Chemical Society
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• 제15권7호
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• pp.537-541
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• 1994

The reaction of the heterobimetallic anion, ${(OC)_5CrMn(CO)_5^-M^+ (M^+=Na^+, PPN^+)\;with\;CH_3I$ was proven to be overall 1st order with respect to $[(OC)_5CrMn(CO)_5^-]$ This reaction mechanism may be described in terms of the consecutive reaction pathway in which Cr$(CO)_5$(THF) may be an important intermediate, leading to the corresponding products such as MeMn$(CO)_5\;and\;ICr(CO)_5^-$, accordingly. The counterion effect on this reaction was also elucidated.