• Title/Summary/Keyword: Conformationally rigid polymer

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Synthesis and Conformational Analysis of Novel Polymeric Ligands based on myo-Inositol (마이오 이노시톨을 이용한 고분자 리간드의 합성 및 형태 분석)

  • Kim, Tae-Hyeon;Holmes, Andrew B.
    • Journal of the Korean Chemical Society
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    • v.50 no.2
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    • pp.129-136
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    • 2006
  • Synthesis of novel polymeric ligands based on myo-inositol was performed. Cyclopolymerization, whose mechanism and the cyclic structure were proved, was first attempted to build a conformationally rigid inositol polymer. Comparative spectroscopic methods were introduced to verify the conformation of the prepared cyclohexane polymers. A conformationally rigid polymeric ligand was successfully prepared using myo-inositol carbonate.