• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.213-213
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• 2012

It has been known that quantum confinement effect of CdSe nanocrystal was observed by increasing the number of deposition cycle using successive ionic layer adsorption and reaction (SILAR) method. Here, we report on thermally-induced quantum confinement effect of CdSe at the given cycle number using spin-coating technology. A cation precursor solution containing $0.3\;M\;Cd(NO_3)_2{\cdot}4H_2O$ is spun onto a $TiO_2$ nanoparticulate film, which is followed by spinning an anion precursor solution containing $0.3\;M\;Na_2\;SeSO_3$ to complete one cycle. The cycle is repeated up to 10 cycles, where the spin-coated $TiO_2$ film at each cycle is heated at temperature ranging from $100^{\circ}C$ to $250^{\circ}C$. The CdSe-sensitized $TiO_2$ nanostructured film is contacted with polysulfide redox electrolyte to construct photoelectrochemical solar cell. Photovoltaic performance is significantly dependent on the heat-treatment temperature. Incident photon-to-current conversion efficiency (IPCE) increases with increasing temperature, where the onset of the absorption increases from 600 nm for the $100^{\circ}C$- to 700 nm for the $150^{\circ}C$- and to 800 nm for the $200^{\circ}C$- and the $250^{\circ}C$-heat treatment. This is an indicative of quantum size effect. According to Tauc plot, the band gap energy decreases from 2.09 eV to 1.93 eV and to 1.76 eV as the temperature increases from $100^{\circ}C$ to $150^{\circ}C$ and to $200^{\circ}C$ (also $250^{\circ}C$), respectively. In addition, the size of CdSe increases gradually from 4.4 nm to 12.8 nm as the temperature increases from $100^{\circ}C$ to $250^{\circ}C$. From the differential thermogravimetric analysis, the increased size in CdSe by increasing the temperature at the same deposition condition is found to be attributed to the increase in energy for crystallization with $dH=240cal/^{\circ}C$. Due to the thermally induced quantum confinement effect, the conversion efficiency is substantially improved from 0.48% to 1.8% with increasing the heat-treatment temperature from $100^{\circ}C$ to $200^{\circ}C$.

• Journal of the Korea Concrete Institute
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• v.21 no.2
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• pp.159-168
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• 2009

In this study, strength, stiffness and confinement effect with stress-strain and stress-volumetric strain curves for improved uniaxial compressive behavior of RC circular columns laterally confined with prestressing aramid fiber strap were experimentally investigated. The test variables were the specimens with or without axial reinforcing bar and the number and spacing of strap, prestressing level, the types of reinforcing fiber (CFS, GFS). As a result, the failure type of the columns was very stable and strength increase rate was about 73% comparison with the general RC columns. Moreover, the strain increase rate is very small and the axial displacement confinement effect was very effective compared with existry methods (CFS, GFS), the initial and final lateral confinement effect was excellent.

• Structural Engineering and Mechanics
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• v.74 no.3
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• pp.351-363
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• 2020

Based on the dynamic tests of recycled aggregate concrete (RAC) short columns confined by the hoop reinforcement, the dynamic failure mechanism and the mechanical parameters related to the constitutive relation of confined recycled aggregate concrete (CRAC) were investigated thoroughly. The fracturing sections were relatively flat and smooth at higher strain rates rather than those at a quasi-static strain rate. With the increasing stirrup volume ratio, the crack mode is transited from splitting crack to slipping crack constrained with large transverse confinement. The compressive peak stress, peak strain, and ultimate strain increase with the increase of stirrup volume ratio, as well as the increasing strain rate. The dynamic confining increase factors of the compressive peak stress, peak strain, and ultimate strain increase by about 33%, 39%, and 103% when the volume ratio of hoop reinforcement is increased from 0 to 2%, but decrease by about 3.7%, 4.2%, and 9.1% when the stirrup spacing is increased from 20mm to 60mm, respectively. This sentence is rephrased as follows: When the stirrup volume ratios are up to 0.675%, and 2%, the contributions of the hoop confinement effect to the dynamic confining increase factors of the compressive peak strain and the compressive peak stress are greater than those of the strain rate effect, respectively. The dynamic confining increase factor (DCIF) models of the compressive peak stress, peak strain, and ultimate strain of CRAC are proposed in the paper. Through the confinement of the hoop reinforcement, the ductility of RAC, which is generally slightly lower than that of NAC, is significantly improved.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.6
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• pp.153-160
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• 2020

Columns are one of the most critical parts of a structural system subjected to earthquake excitations. In this regard, extensive experimental studies have been conducted to evaluate the effect of fiber reinforced polymer (FRP) wrapping on the seismic performance of reinforced concrete (RC) columns. Among them, many studies focused on the behavior of circular or square RC columns strengthened with CFRP or GFRP sheets. Since the cross-sectional shape affects confinement by FRP wrapping, its strengthening effect and final damage pattern may differ with shapes. In this study, a series of cyclic tests was conducted to investigate the seismic behavior of rectangular reinforced concrete columns strengthened with basalt-based fiber reinforced polymer (BFRP) sheets and composite fiber panels. The result shows that the effect of strengthening is not significant, and it implies a little increase of confinement by BFRP sheets and composite fiber panels, which is considered partly due to the cross-sectional shape of the columns.

• Steel and Composite Structures
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• v.18 no.4
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• pp.1023-1044
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• 2015

Concrete-filled tubes (CFT), formed by an outer steel tube filled with plain or reinforced concrete inside, have been increasingly used these recent decades as columns or beam-columns, especially for tall buildings in seismic areas due to their excellent structural response. This improved behavior is derived from the effect of confinement provided by the tube, since the compressive strength of concrete increases when being subjected to hydrostatic pressure. In circular CFTs under compression, the whole tube is uniformly tensioned due to the radial expansion of concrete. Contrarily, in rectangular and square-shaped CFTs, the lateral flanges become subjected to in-plane bending derived from this volumetric expansion, and this fact implies a reduction of the confinement effect of the core. This study presents a numerical analysis of different configurations of CFT stub columns with inner stiffening plates, limited to the study of the influence of these plates on the compressive behavior without eccentricity. The final purpose is to evaluate the efficiency in terms of strength and ductility of introducing stiffeners into circular and square CFT sections under large deformation axial loading.

• Bulletin of the Korean Chemical Society
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• v.27 no.10
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• pp.1562-1566
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• 2006

Mesoporous silica films with three different pore sizes were prepared by using cationic surfactant, non-ionic surfactant, or triblock copolymer as structure directing agents with tetramethylorthosilicate as silica source in order to control the pore size and wall thickness. They were synthesized by an evaporation-induced self-assembly process and spin-coated on Si wafer. Mesoporous silica films with three different pore sizes of 2.9, 4.6, and 6.6 nm and wall thickness ranging from $\sim$1 to $\sim$3 nm were prepared by using three different surfactants. These materials were optically transparent mesoporous silica films and crack free when thickness was less than 1 m m. The photoluminescence spectra found in the visible range were peaked at higher energy for smaller pore and thinner wall sized materials, consistent with the quantum confinement effect within the nano-sized walls of the silica pores.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.132-132
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• 2009

A 2D-simulation using a quantum model of silicon nanowire (SiNW) field-effect transistors (FETs) have been performed by the effective mass theory. We have investigated very close for real device analysis, so we used to the non-equilibrium Green's function (NEGF) and the density gradient of quantum model. We investigated I-V characteristics curve and C-V characteristics curve of the channel thickness from 5nm to 200nm. As a result of simulation, even higher drain current in SiNW using a quantum model was observed than in SiNW using a non-quantum model. The reason of higher drain current can be explained by the quantum confinement effect.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.15-16
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• 2009

The purpose of this research is to examine the confinement effect of high-strength transverse reinforcement for concrete cylinders. In this study the behavior of concrete cylinders reinforced with high-strength steel spirals was investigated.

• KIEAE Journal
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• v.7 no.4
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• pp.105-111
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• 2007

As this study investigates the influence about type of transverse reinforcement, spacing of transverse reinforcement(s), volumetric ratios of transverse reinforcement(${\rho}s$) of ultra-high strength concrete columns. It try to offer to resonable basic data of the confined model for the ultra-high concrete of in reinforced concrete columns. Experimental tests with large scaled columns were conducted under concentric axial loads. The ultra-high strength concrete (100MPa) was used. From this test result, it evaluate influence of the strength enhancement and ductility enhancement, important variables about behavior of the confined concrete by confinement of ultra-high strength reinforced concrete.There are two ways to improve the confinement effect of high strength concrete columns through the increase of amounts and/or strength of transverse reinforcement.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.51-51
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• 2010

We have proposed a new configuration for the improvement of neutron yield without the application of external ion sources in an inertial electrostatic confinement (IEC) device. The application of a double grid cathode to the IEC device is expected to generate a higher ion current than a single grid cathode. This paper verifies the effect of the double grid cathode by both fluid and particle simulation. Through the fluid simulation the optimal shape and applied voltage of the double grid cathode is determined, and through the particle simulation the usefulness of that is confirmed.