• Title/Summary/Keyword: Configurational analysis

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Study on the improvements for Managerial Efficiency of the Designated Lane Law (지정차로제의 합리적 운영방안에 대한 연구)

  • Lee, Seung-Jun;Lee, Choul-Ki;Lee, Yong-Ju;Kim, Yong-Man
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.15 no.2
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    • pp.85-94
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    • 2016
  • Lane Designation is defined as reasonable road management to ensure the road safety and enhance road efficiency. While the lane designation system was abolished in 1999, it was redefined because of the increasing number of large vehicles in the passing lane, violent on driving and traffic accidents in 2000. The needs of improvement on operating the lane designation has been increasing more in recent due to the low ratio of compliance with the system and difficulties to keep the right lane due to need of turning and demand of widening of designates lane for two-wheeled vehicles and truck. In this study, we presented the improvement plan through the question survey, simulation analysis, safety evaluation. It found a problem that the low-speed vehicle is to use the upper level roadway, difficulties of supervision, the imbalance in the lane use, imbalance traffic and does not match the international standards. This study suggested five different alternatives through the survey. micro simulation has used in order to examine each alternative by management effectiveness and feasibility. It analyzed the traffic speed, efficiency, traffic balance of alternatives. Also, safety evaluation conducted in terms of the range of field-of-view to ensure the easiness of field of view by various configurational difference between the vehicles. By the analysis results of such indicators, This study presents proposals for improvement in operating designated lane that low-speed-big-sized vehicles keep to the right lane, and high-speed-small sized vehicles keep to the left lane.

Identification of Petroselinic Acid (Cis-6-octadecenoic Acid) in the Seed Oils of Some of the Family Umbelliferae (Panax schinseng, Aralia continentalis and Acanthopanax sessiliflorus) by GC-MS, IR, $^1H-and$ $^13C-NMR$ Spectroscopic Techniques

  • Kim, Seong-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.4
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    • pp.323-331
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    • 2005
  • Fatty acid compositions of the seed oils of P. schinseng, A. continentalis and A. sessiliflorus, were analyzed by gas chromatography (GC) equipped with a capillary column. A large unusual peak was observed just before the peak corresponding to oleic acid $(cis-9-C_{18:1})$. This unknown fatty acid was isolated by silver ion chromatography and then derivatized into the picolinyl ester. The mass spectrum of the picolinyl ester showed molecular ion at m/z=373 with other diagnostic ions such as m/z=178, 218, 232, 246, 274, 288, 302 and 344. Characteristic absorption peaks at $720\;cm^{-1}$, $1640\;cm^{-1}$ and $3010\;cm^{-1}$ in IR spectrum indicated the presence of cis-configurational double bond in the molecule. The $^1H-NMR$ spectrum of this acid gave two quintets centered at ${\delta}1.638$ (2H, C-3) and ${\delta}1.377$ (2H, C-4), and two multiplets centered at ${\delta}2.022{\sim}2.047$ (2H, C-5) and ${\delta}2.000{\sim}2.022$ (2H, C-8), and multiplet signals of olefinic protons centered at ${\delta}5.3015{\sim}5.3426$ (C-6, J=9.5 Hz) and ${\delta}\;5.3465{\sim}5.3877$ (C-7, J=9.5 Hz). The $^13C-NMR$ spectrum showed 18 carbon resonance signals including an overlapped signal at ${\delta}29.7002$ for C-12 and ${\delta}29.6520$ for C-13 (or they can be reversed), and other highly resolved signals at ${\delta}33.950$, ${\delta}24.558$, ${\delta}26.773$ and ${\delta}27.205$ due to C-2, C-3, C-5 and C-8 of a ${\Delta}^6-octadecenoic$ acid, respectively. From analysis results this unknown fatty acid could be identified as cis-6-octadecenoic acid. The seed oils of P. schinseng and A. sessiliflorus contained petroselinic acid (59.7%, 56.0%), oleic acid (18.3%, 6.1%) and linoleic acid (16.2%, 30.4%) with small amount of palmitic acid (3.0%, 3.1%) while the seed oil of A. continentalis comprised mainly oleic acid (30.2%), petroselinic acid (29.0%), linoleic acid (24.1%) and palmitic acid (13.1%).