• Journal of the Korean Society of Groundwater Environment
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• v.5 no.3
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• pp.155-161
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• 1998

Retardation effect of heavy metals in soils caused by adsorption onto the surfaces of solids particles is well known phenomenon. In this study, we investigated the retardation effect on the mobility of a Zn in a sandy soil by conducting batch and column tests. The column test consisted of monitoring the concentrations of effluent versus time known as a breakthrough curve (BTC). We used NaCl and ZnCl$_2$ solutions with the concentration of 10 g/L as a tracer, and injected them respectively into the inlet boundary of the soil sample as a square pulse type, and monitored the effluent concentrations at the exit boundary under a steady state condition using an EC-meter and ICP-AES. The batch test was conducted based on the standard procedure of equilibrating fine fractions collected from the soil with various initial ZnCl$_2$ concentrations, and analysis of Zn ions in the equilibrated solutions using ICP-AES. The results of column test showed that i) the peak concentration of ZnCl$_2$analyzed by ICP was far less than that of either NaCl or bulk electrical conductivity and ⅱ) travel times of peak concentrations for two tracers were more less identical. The relatively low concentration of Zn can be explained by ion exchange between Zn and other cations, and possible precipitation of Zn in the form of Zn(OH)$_2$due to high pH range (7.0∼7.9) of the effluent. The identical result of travel times of peak concentrations indicates that the retardation effect is not present in the soil. The only way to describe the prominent decrease of Zn ion was to introduce decay or sink coefficient in the CDE model to account for irreversible decrease of Zn ions in the aqueous phase.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.9
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• pp.49-56
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• 2020

High temperature heat generated during rifle firing not only degrades the performance of the weapon, but also limits the user's operation. In this study, temperature change of handguard according to firing was measured with reference to Human Engineering criteria and the operability according to material was examined. Accordingly, for the firing test, three types of Korean rifle and one overseas model were selected for each material of handguard, and firing test was conducted using a contact type temperature meter. The test result shows that using a plastic handguard with low thermal conductivity and aluminum handguard with high thermal conductivity enabled the rifles to be operated with bare hands even when firing at more than 100 rounds at low atmospheric temperature. However, when firing more than 60 rounds at over 20℃ atmospheric temperature, aluminum handguard use is limited. When firing quickly over 100 rounds, handguard use is restricted regardless of its fabrication material. To eliminate operational limitations by overheating, it is necessary to eliminate direct contact with skin using gloves, vertical grips, etc. This study examined the operability of rifles in terms of thermal risk, and the resulting study results are expected to be used as basic data for Human Engineering of other rifles and munitions.

• Journal of the Korean Chemical Society
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• v.53 no.2
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• pp.125-132
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• 2009

The magnetized water is known to have a unique pattern of hydrogen bond between water molecules, thereby producing different physicochemical properties from the ordinary water. We have examined the effect of magnetized water on the change of critical micelle concentrations (CMC) of some surfactants. The CMC changes of SDS (sodium dodecyl sulfate) and CTAB (cetyltrimethylammonium bromide) dissolved in the magnetized water have been determined by the conductivity measurement at $25\;{^{\circ}C}$ and that of SDS, CTAB and Pluronic F-68 have also been examined by the surface tension method at $25\;{^{\circ}C}$. The CMC variation of SDS was examined by ITC (Isothermal Titration Calorimeter) at $25\;{^{\circ}C}$. The CMC of SDS, CTAB, and Pluronic F-68 are more decreased in the magnetized water, SDS is about $2.7{\sim}6.5$25 %, CTAB is about $2.3{\sim}3.0$%, and Pluronic F-68 is about 24.2 %, than in the control water.

• Journal of Ocean Engineering and Technology
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• v.31 no.6
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• pp.413-418
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• 2017

In the present study, silica-aerogel-polyurethane foams were synthesized to improve the mechanical characteristics and insulation performance of the polyurethane foam applied to a liquefied natural gas carrier at a cryogenic temperature of $-163^{\circ}C$. A silica-aerogel-polyurethane foam bulk was prepared using a homogenizer by varying the weight ratio of the silica aerogel (0, 1, 3, and 5 wt%), while maintaining the contents of the polyol, isocyanate, and blowing agent constant. Compression tests were performed at room and cryogenic temperatures to compare the mechanical properties of the silica-aerogel polyurethane foams. The internal temperature of the universal testing machine was maintained through the cryogenic chamber. The thermal conductivity of the silica-aerogel-polyurethane foam was measured using a heat flow meter to confirm the insulation performance. In addition, the effect of the silica aerogels on the cells of the polyurethane foam was investigated using FE-SEM and FTIR. From the experimental results, the 1 wt% silica aerogel polyurethane foam showed outstanding mechanical and thermal performances.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.25 no.3
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• pp.111-116
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• 2019

Thermal insulation performance of new insulation packaging made of recycled PET nonwoven (thickness : 10 mm) was verified by conducting comparative experiment with an EPS box (thickness : 25 mm) and a double wall corrugated box (thickness : 7 mm). Three ice packs (300 g) were positioned 200 mm above the bottom inside each box, all of which are placed side by side and temperature change of 2 points (5mm under middle icepack and 130 mm under middle icepack) was recorded by data logger (GL-840, Graphtec) for 16 hours under the environment of 29℃. The new packaging box showed 75% higher insulation performance than the EPS box and 180% higher than the corrugated box. In order to figure out the reason for insulation performance difference among boxes, thermal conductivities of each box material were measured using heat flow meter (HFM436 lamda, Netzsch). U-value (thermal conductivity divided by thickness) of EPS was lower than recycled pet nonwoven by 57%, which seemed to be opposite to the result of insulation test of boxes. This was explained by high water vapor transmission rate of EPS (6 times higher than PET insulation) and air pocket effect of PET insulation.

• Water for future
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• v.22 no.1
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• pp.81-90
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• 1989

A numerical simulation technique of three-dimensional finite difference model is developed to study the groundwater flow system in Dejima, an upland area which faces Kasumigaura Lake. For general perspectives of the groundwater flow system, a steady state three-dimensinal model is simulated. For the sedimentary mud formations which are found in the representative formation, three situations where the horizontal permeability is equal to 10 times and 100 times of the vertical one. The finite difference grid used in the simulation has 60$\times$50$\times$30=90,000 nodes. A converged solution with a tolerance of 0.001 meter of hydraulic head is set. Having determined the flow net by using a steady state three-dimensional model, the results for the three cases of hydraulic conductivity are compared with the results of the tracer methods (Bae and Kayane, 1987). With the aid of four representative vertical cross-sections, groundwater flow systems in the study area are assumed. The results of these are reasonally good comparable with the results of the basin yield and thd recharge-discharge distribution 8.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.883-888
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• 2007

일반적인 하천의 흐름방향으로 발생하는 주흐름(primary flow)에 중첩하여 주흐름 방향의 수직단면에 이차류(secondary flow)가 발생하게 되며 이러한 이차류의 발달은 투입된 오염물질의 횡혼합을 증대시킨다. 오염물질의 혼합은 이송(advection)과 확산(diffusion) 또는 분산(dispersion)의 과정으로 설명되며 본 연구에서는 수로전체의 혼합과정을 설명하기 위해서 이송 확산 방정식을 적용하였다. 본 연구에서는 실험수조를 $150^{\circ}$의 중심각을 갖는 S자 형태의 만곡수로를 제작하여 유량조건은 15, 30, $60\;{\ell}l/sec$의 세 가지 경우로, 수심은 15, 20, 30, 40 cm의 경우로 총 12 케이스의 실험을 수행하였다. 유속장의 측정은 Sontek사의 3차원 micro-ADV(Acoustic Doppler Velocimeter)를 이용하였다. 오염물질 확산실험은 소금물 용액에 주변수와의 밀도차를 없애기 위해서 메탄올 용액을 첨가하여 추적자로 이용하여 농도장의 분석을 일본 KENEK사의 전기전도도계(conductivity meter)와 Gartner사의 DAS(data acquisition system)를 이용하여 횡방향 유속장의 분포와 오염운의 거동을 비교하여 다음과 같은 결론을 얻게 되었다. 주 흐름은 직선구간에서는 중앙에서 최대 유속을 나타내며, 좌우대칭적인 유속분포의 모습을 보이고, 만곡부에서는 수로안쪽을 따라 최대유속이 발생하였다. 수로의 직선구간에서는 최대유속이 발생하는 즉, 중앙에서의 오염물질의 분산이 가장 활발하게 이뤄졌으며 농도의 퍼짐형상인 오염운 역시 만곡부에서는 수로만곡부의 안쪽을 따라 확산 이동함을 알 수 있었다. 만곡부 외측에서는 오염물질의 정체현상이 일시적으로 발생하며, 유속구조의 횡방향 비대칭구조로 인한 종 횡방향의 분리현상이 발생하고, 오염운의 중첩현상이 종방향으로 연속되게 나타난다. 향후 수심방향 거동을 포함한 3차원적 분석이 요구되며 이 연구결과는 2차원적 수치해석의 적용 및 분석 자료로써 이용이 가능하다.

• Composites Research
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• v.25 no.3
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• pp.70-75
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• 2012

Interfacial durability and electrical properties of CNT, ITO or xGnP coated PVDF nanocomposites were investigated for acoustic actuator applications. The xGnP coated PVDF nanocomposite exhibited better electrical conductivity than CNT and ITO case due to the unique electrical property of xGnP, and this nanocomposite also showed good sound characteristics. Interfacial adhesion durability between either neat CNT or plasma treated CNT and plasma treated PVDF were measured by static contact angle, surface energy, work of adhesion, and spreading coefficient tests. The optimum acoustic actuation performance of xGnP coated PVDF nanocomposite was measured using sound level meter with changing radius of curvature and coating conditions. As compared to CNT and ITO, the xGnP was known as more appropriate acoustic actuator due to the characteristic electrical property. It is the most appropriate condition when the radius of curvature is 15 degree. Although sound characteristics were different with various coating thicknesses, it is possible to manufacture transparent actuator with good sound quality.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.52 no.2
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• pp.159-172
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• 2019

This study investigated the effects of dietary monobasic potassium phosphate (MKP) on the growth of the far eastern catfish Silurus asotus and four leafy vegetables in a hybrid biofloc technology aquaponic system. To an experimental diet containing 45% protein and 7% lipid, 1, 2, 3 or 4% MKP was added and was designated as MKP1, MKP2, MKP3, and MKP4, respectively. The optimum MKP levels were determined for the growth of fish and four leafy vegetables over 10 weeks. After the 10-week feeding trial, weight gain, feed efficiency, specific growth rate and protein efficiency ratio were higher in the fish groups fed MKP2 and MKP3 than in the other groups (P<0.05). The growth of the four leafy vegetables was also higher in the fish groups fed MKP2 and MKP3. Water quality [dissolved oxygen, pH, water temperature, electrical conductivity, turbidity, total ammonia nitrogen (TAN), $NO_2-N$, $NO_3-N$ and $PO_4-P$] was measured six times a week using a portable water quality meter and reagent measurements. The TAN (4.58-20.40 mg/L), $NO_3-N$ (24.12-52.40 mg/L) and $PO_4-P$ (20.38-48.48 mg/L) levels increased with time, while the $NO_2-N$ level remained below 0.1 mg/L throughout the study.

• Journal of the Korean Chemical Society
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• v.63 no.6
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• pp.453-458
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• 2019

Synthesis of ZnCo₂O₃ oxide is performed by sol-gel method via nitrate-citrate route. Powder X-ray diffraction (XRD) study shows monoclinic unit cell having lattice parameters: a = 5.721(1) Å, b = 8.073(2) Å, c = 5.670(1) Å, β = 93.221(8)°, space group P_2/m and Z = 4. Average crystallite sizes determined by Scherrer equation are the range ~14-32 nm, whereas SEM micrographs show nano-micro meter size particles formed in ZnCo₂O₃. Endothermic peak at ~798 K in the Differential scanning calorimetric (DSC) trace without weight loss could be due to structural transformation and the endothermic peak ~1143 K with weight loss is due to reversible loss of O₂ in air atmosphere. Energy Dispersive X-ray (EDX) analysis profile shows the presence of elements Zn, Co and O which indicates the purity of the sample. Magnetic measurements in the range of +12 kOe to -12 kOe at 10 K, 77 K, 120 K and at 300 K by PPMS-II Physical Property Measurement System (PPMS) shows hysteresis loops having very low values of the coercivity and retentivity which indicates the weakly ferromagnetic nature of the oxide. Observed X-band EPR isotropic lineshapes at 300 K and 77 K show positive g-shift at g_iso ~2.230 and g_iso ~2.217, respectively which is in agreement with the presence of paramagnetic site Co²⁺(3d⁷) in the oxide. DC conductivity value of 2.875 ×10^-8 S/cm indicates very weakly semiconducting nature of ZnCo₂O₃ at 300 K. DRS absorption bands ~357 nm, ~572 nm, ~619 nm and ~654 nm are due to the d-d transitions ⁴T_1g(⁴F)→²E_g(²G), ⁴T_1g(⁴F)→⁴T_1g(⁴P), ⁴T_1g(⁴F)→⁴A_2g(⁴F), ⁴T_1g(⁴F)→⁴T_2g(⁴F), respectively in octahedral ligand field around Co²⁺ ions. Direct band gap energy, E_g~ 1.5 eV in the oxide is obtained by extrapolating the linear part of the Tauc plot to the energy axis indicates fairly strong semiconducting nature of ZnCo₂O₃.