• Title/Summary/Keyword: Conductive Polymer Coating

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Yttrium-doped and Conductive Polymer-Coated High Nickel Layered Cathode Material with Enhanced Structural Stability

  • Shin, Ji-Woong;Lee, Seon-Jin;Nam, Yun-Chae;Son, Jong-Tae
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.272-278
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    • 2021
  • In this study, high nickel layered LiNi0.8Co0.1Mn0.1O2 cathode materials for lithium-ion batteries were modified by yttrium doping and poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) coating. The effects of yttrium doping and PEDOT:PSS coating on the structural and electrochemical properties of the LiNi0.8Co0.1Mn0.1O2 cathode material were investigated and compared. The substitution of nickel with an electrochemically inert yttrium was confirmed to be successful in stabilizing the layered structure framework. Moreover, coating the surfaces of the LiNi0.8Co0.1Mn0.1O2 particles with a conductive polymer, PEDOT:PSS, improved the capacity retention, thermal stability, and impedance of the cathode material by increasing its ionic and electric conductivities.

Characterization of Transparent Electrodes using Carbon Nanotubes Coated by Conductive Polymers (전도성 고분자가 코팅된 탄소 나노튜브 투명전극의 특성 분석)

  • Kim, Bu-Jong;Han, Sang-Hoon;Park, Jin-Seok
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.1
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    • pp.19-25
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    • 2014
  • This study demonstrates transparent electrodes with characteristics desirable for touch screen panels using carbon nanotubes (CNTs). This has been accomplished by depositing CNTs on glass substrates via spray coating and then depositing thin conductive polymer films on the CNTs via spin coating. For all of the samples, such as CNTs, conductive polymers, and polymer-coated CNTs, the surface morphologies, sheet resistances, visible transmittances, chromatic properties are characterized as functions of their preparation conditions, such as the spray times for CNTs and the spin speeds for conductive polymers. The experimental results confirm that only the polymer-coated CNTs can satisfy all of the requirements that are required for electrodes of touch screen panels, such as the sheet resistance lower than $100{\Omega}/sq$, the visible transmittance higher than 80 %, and the yellowness smaller than 1.

Transparent Electrode Forming Technology using ESD Coating Methode (ESD 기법을 이용한 투명전도막 형성 기술)

  • Kim, Jung-Su;Kim, Dong-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.348-348
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    • 2009
  • The conductive coating method is used for various industrial fields. For example, Sputtering process is used to coat ITO layer in LCD or OLED panel manufacture process and fabricate a base layer of substrate of an electric printing device. However, conventional coating processes (beam sputtering, spin coating etc.) has a problems in the industrial manufacturing process. These processes have a very high cost and critical manufacturing environment as a vacuum process. Recently, many researchers have proposed various printing process instead of conventional coating processes. In this paper, we propose an ESD printing process in ITO coating layer and apply to fabricate a conductive coating film. Furthermore, the effect of the nozzle and also the applied voltage on different configuration of the nozzle head was also studied for better understanding of the Electro Static deposition process.

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Commercialization & Process Optimization of Protective Film on Nano Silver Transparent Conductive Substrate by Means of Large Scale Roll-to-Roll Coating and Experimental Design (나노실버 투명전도소재 보호필름의 개발 및 공정 최적화와 실험 계획법을 이용한 검증)

  • Park, Kwang-Min;Lee, Ji-Hoon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.813-820
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    • 2015
  • We have studied commercialization and process optimization of protective film on transparent conductive coated substrate, nano silver on flexible PET (poly ethylene terephthalate), by means of roll-to-roll micro-gravure coater. Nanosilver on flexible PET substrate is potential materials to replace ITO (indium tin oxide). Protective film is most important to maintain unique silver pattern on top of transparent PET. PSA pressure sensitive adhesives) was developed solely for nano silver on PET and protective film was successfully laminated. We have optimized all process conditions such as coating thickness, line speed and aging time & temperature via experimental design. Transparent conductive film and its protective film developed in this research are commercially available at this moment.

Study and Fabrication of Transparent Electrode Film by using Thermal-Roll Imprinted Ag Mesh Pattern and Coated Conductive Polymer (열형-롤 각인으로 형성한 Ag 격자 패턴과 전도성 고분자 코팅을 이용한 투명전극 필름 제작에 관한 연구)

  • Yu, Jong-Su;Jo, Jeong-Dai;Yoon, Seong-Man;Kim, Do-Jin
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.9
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    • pp.11-15
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    • 2010
  • In this study, to fabricate a low-resistance and high optical transparency electrode film, the following steps were performed: the design and manufacture of electroforming stamp, the fabrication of a thermal roll-imprinted polycarbonate (PC) patterned films, the filled low-resistance Ag paste using doctor blade process on patterned PC films and spin coating by conductive polymers. As a result of PC films imprinted line width of $26.69{\pm}2\;{\mu}m$, channel length of $247.57{\pm}2\;{\mu}m$, and pattern depth of $7.54{\pm}0.2\;{\mu}m$. Ag paste to fill part of the patterned film with conductive polymer coating and then the following parameters were obtained: a sheet resistance of $11.1\;{\Omega}/sq$ optical transparency values at a wavelength of 550 nm was 80.31 %.

Enhanced adhesion properties of conductive super-hydrophobic surfaces by using zirco-aluminate coupling agent

  • Park, Myung-Hyun;Ha, Ji-Hwan;Song, Hyeonjun;Bae, Joonwon;Park, Sung-Hoon
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.387-392
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    • 2018
  • Various technical approaches and concepts have been proposed to develop conductive super-hydrophobic (SH) surfaces. However, most of these approaches are not usable in practical applications because of insufficient adhesion and cost issues. Additionally, durability and uniformity issues are still in need of improvement. The goal of this research is to produce a large-area conductive SH surface with improved adhesion performance and uniformity. To this end, carbon nanotubes (CNT) with a high aspect ratio and elastomeric polymer were utilized as a conductive filler and matrix, respectively, to form a coating layer. Additionally, nanoscale silica particles were utilized for stable implementation of the conductive SH surface. To improve the adhesion properties between the SH coating layer and substrate, pretreatment of the substrate was conducted by utilizing both wet and dry etching processes to create specific organic functional groups on the substrate. Following pretreatment of the surface, a zirco-aluminate coupling agent was utilized to enhance adhesion properties between the substrate and the SH coating layer. Raman spectroscopy revealed that adhesion was greatly improved by the formation of a chemical bond between the substrate and the SH coating layer at an optimal coupling agent concentration. The developed conductive SH coating attained a high electromagnetic interference (EMI) shielding effectiveness, which is advantageous in self-cleaning EMI shielding applications.

Novel Conductive Paste based on Cellulose Acetate Butyrate (셀룰로오스를 이용한 전도성 체이스트의 개발)

  • Kim, Tae-Hyun
    • Journal of the Korean Chemical Society
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    • v.51 no.2
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    • pp.171-177
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    • 2007
  • Polymer-based electrically conductive pastes have been used to make the conductive paths between voltage sources and devices. The pastes used for these applications consist of two main components: a polymer binder and a conductive filler. Having both low viscosity and good metal-encapsulating properties, cellulose acetate butyrate (CAB) was regarded to be a good candidate as a binder for the conductive paste. We have prepared a formulation for a novel conductive paste based on CAB. Preliminary studies showed that this conductive paste revealed stable conductivity, together with uniform coating and flexibility.

Conductive Polymer Coated Electro-active Paper(EAPap) (전도성 고분자를 결합한 EAPap작동기에 관한 연구)

  • Yun, Sungryul;Ounaies Zoubeida;Bae, Seung-Hun;Kim, Jaehwan
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.15 no.9 s.102
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    • pp.1077-1083
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    • 2005
  • Electro-Active Paper (EAPap) is one of attractive electro-active polymer (EAP) materials for artificial muscles due to its many advantages such as light weight, biologically degradable, low cost, large displacement output, low actuation voltage and low power consumption. However, drawbacks of EAPap actuators include low force output and humidity dependence. To enhance the performance of EAPap, conductive polymer (PPy) and SWNT/conductive polymer (PANI) are coated on EAPap PPy as conductive polymer is coated on cellulose EAPap by means of electrochemical deposition. Two different dopants are used in PPy through conducting polymer processing. SWNTS are mixed with PANI in emeraldine base along with different dopants. The compound materials are coated on cellulose EAPap using spin coating system. The performance of PPy/EAPap and SWNT/PANI/EAPap are evaluated in terms of bending displacement, blocked force, and the effects of dopants, humidity, coaling time, voltage and frequency are investigated. Comparing with EAPap actuators, SWNT/PANI/EAPap actuators show $200\%$ improvement of bending displacement and $300\%$ increment of blocked force.

Development of Roll Printing Process System for The Next Generation Flexible Solar Cell (차세대 플렉서블 태양전지 생산용 롤프린팅 공정장비 기술 개발)

  • Kim, Dong-Soo;Kim, Jung-Su;Kim, Myoung-Sub;Kim, Kang-Dae
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.57-60
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    • 2009
  • The conductive coating method was used for a various industrial fields. For example, Sputtering process is using to a coat of ITO layer in LCD or OLED panel manufacture process and fabricate a base layer of substrate of an electric printing device. However, conventional coating process (beam sputtering, spin coating etc.) has a problems in the industrial manufacturing process. These processes have a very high cost and critical manufacturing environment as a vacuum process. Recently, many researchers were proposed a various printing process instead of conventional coating process. In this paper, we propose an ESD printing process in ITO coating layer and apply to fabricate a conductive coating film. Ours transparent electrode had a surface resistance of about $66{\Omega}/{\square}$ and transparent of 74% in the wavelength of 500nm. This transparent electrode manufacturing process will be applied to Roll-to-Roll process. In addition, we developed roll printing process system for the next generation flexible solar cell.

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Antistatic Behavior of UV-curable Multilayer Coating Containing Organic and Inorganic Conducting Materials (유·무기 전도성 물질을 함유한 UV 경화형 다층 코팅의 대전방지 특성)

  • Kim, Hwa-Suk;Kim, Hyun-Kyoung;Kim, Yang-Bae;Hong, Jin-Who
    • Journal of Adhesion and Interface
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    • v.3 no.3
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    • pp.22-29
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    • 2002
  • UV curable coating system described here consists of double layers, namely under layer and top laser coatings. The former consists of organic-inorganic conductive materials and the latter consists of multifunctional acrylates. Transparent double layer coatings were prepared on the transparent substrates i.e. PMMA, PC, PET etc. by the wet and wet coating procedure. Their surface resistances and film properties were measured as a function of the top layer thickness and relative humidity. As the thickness of the top layer was less than $10{\mu}m$, the surface resistance in the range of $10^8{\sim}10^{10}{\Omega}/cm^2$ was obtained. The surface properties of the two-layer coating were remarkably improved compared with the single layer coating. The effects of migration of conducting materials on the film properties of multilayer coating were investigated by using contact angle and Fourier transform infrared/attenuated total reflection(FT-IR/ATR). It was found that the migration of dopant(dodecyl benzenesulfonic acid, DBSA) molecules were occurred from film-substrate interface to film-air interface in the organic conductive coating system but not in the inorganic one.

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