• Journal of Korean Society for Atmospheric Environment
• /
• v.33 no.6
• /
• pp.605-615
• /
• 2017

Efficient simultaneous reduction conditions for $NO_x$ and $NH_3$-slip was investigated in SCR (Selective Catalytic Reduction) process with load variation by applying dual catalysts (SCR catalyst, $NH_3$ decomposition catalyst) system. $N_2O$ formation characteristics were analyzed to look into possible undesirable reaction pathways. In the experiments of catalyst characteristics, various operational variables were tested for the combined catalytic system, such as $NH_3/NO_x$ ratio, temperature, oxygen concentration and $H_2O$. The reaction characteristics of $NO_x$, $NH_3$ and $N_2O$ were analyzed and optimal conditions could be evaluated for the combustion facility with varied load. In terms of $NO_x/NH_3$ simultaneous reduction and $N_2O$ formation suppression, optimal condition was considered NSR 1.2 and temperature $300^{\circ}C$. At this operational condition, $NO_x$ conversion was 98%, $NH_3$ reduction efficiency was 95%, generated $N_2O$ concentration 9.5 ppm with inlet $NO_x$ concentration of 100 ppm. In $NH_3-SCR$ process with $NH_3$ decomposition catalyst, $NO_x$ and $NH_3$ can be considered to be reduced simultaneously at limited conditions. The results of this study may be utilized as basic data at facilities requiring simultaneous $NO_x$ and $NH_3$ reduction for facilities with load variation.

• Journal of Environmental Health Sciences
• /
• v.26 no.2
• /
• pp.34-40
• /
• 2000

The purpose of this study was to investigate the seasonal variation of PAHs and to estimate their source characteristics in Taegu area. To do this, four sampling sites were selected to represent an industrial, a traffic, a traffic & residential, and a residential area in Taegu. Total of 72 samples had been collected from January, 1999 to September, 1999 on glass micro fiber filters by high volume air sampler. The PAHs in the total suspended particulate were extracted by a soxhlet process with dichloromethane and analyzed by GC/MSD, GC/FID. A statistical analysis was performed for the PAHs data set using a principal component analysis to derive important factor inherent in the interactions among the variables. The specific conclusions of this research are: 1) There was a significant seasonal and local variation in the atmospheric concentration of PAHs. The seasonal variation is winter>spring>Fall>summer, and the local variation is industrial>traffic>graffic & residential>residential area. 2) To evaluate the correlation between a measured PAHs and other affecting factors such as air pollutant concentration and meterological data, statistical analysis was performed. PAHs and other affecting factors such as air pollutant concentration and meterological data, statistical analysis was performed. PAHs have negative correlation with temperature (r=-0.593, p<0.05), radiation(r=-0.535, p<0.05), and O3(r=-0.719, p<0.05), but have positive correlation with NO(r=0.615, p<0.05) 3)Finally, multivariate analysis was performed for the PAHs dat set to identify and to estimate the source contributions of PAHs. According to results of statistical analysis, it could be identifies as three factors such as vehicular/gasoline, vehicular/diesel, and combustion in Taegu area.

• Journal of dental hygiene science
• /
• v.23 no.1
• /
• pp.51-59
• /
• 2023

Background: Tea tree oil has antiviral, antimicrobial and antifungal effects and Mastic oil has antifungal and anticancer effects. For synergistic effects of oils, blending oil containing a mixture of two to three oils is recommended. This study aimed to determine the antibacterial effects of Tea tree oil, Mastic oil, and Blending oil containing the two oils in a mixture, to verify and suggest the potential use of these oils as a substance to prevent dental caries. Methods: Tea tree oil, Mastic oil, and Blending oil with a 1:1 blend of the two oils were diluted in liquid medium to 0% (negative control), 0.5%, 1.0%, and 2.0%. Streptococcus mutans was applied to each experimental group of the three diluted oils and after 8 h culture, the optical density (OD) was measured and the growth inhibition rate for S. mutans was estimated. Results: Tea tree oil had significantly low OD values across all concentrations (p<0.05) without significant variation among different concentrations (p>0.05). Mastic oil did not significantly vary in OD compared to the negative control across all concentrations (p>0.05) without significant variation among different concentrations (p>0.05). Blending oil, compared to the negative control, did not significantly vary in OD at 0.5% (p>0.05) but significant variation was found as the concentration increased (p<0.05). Additionally, for Tea tree oil and Mastic oil, the growth inhibition rate showed no significant variation according to concentration (p>0.05), whereas for Blending oil, the growth inhibition rate for S. mutans showed a significant difference at 1.0% (p<0.05) and at higher concentrations. Conclusion: Blending oil containing a Tea tree oil and Mastic oil demonstrated a significant growth inhibition effect on S. mutans from the concentration of 1.0%, which suggested its potential use as an effective antibacterial agent for dental caries.

• Journal of Environmental Science International
• /
• v.23 no.3
• /
• pp.399-407
• /
• 2014

In this study, before and after sunset carbon dioxide concentration and air temperature were observed in two points of atmosphere (lower observation point of the GL + 0.1 m, the upper observation point of GL + 1.0 m) on the foreshore at located in Suncheon Bay and their variations were analyzed. Observation was performed on the foreshore on 2~4 August 2010. Instrument (VAISALA, GMP343) was set two hours before sunset and then observation was made continuously for six hours. In three days, observed carbon dioxide concentration was 375~419 ppm, and the air temperature was in the range of $28.7{\sim}32.5^{\circ}C$. The average concentration of carbon dioxide was 388~399 ppm in the upper observation point and 386~396 ppm in the lower observation point. It was higher in the upper observation point and its fluctuations were similar in two observation points. Correlation coefficients between carbon dioxide concentration and air temperature in the upper observation point were in the range of -0.64~-0.88, and were calculated -0.65 to -0.90 in the lower observation point. For the carbon dioxide concentration, correlation coefficients between the upper part and the lower part were very high as 0.98 in three times. For the air temperature, correlation coefficients between the upper part and the lower part were very high as 0.97 and 0.99. In the same observation time, the slope of the linear regression function as carbon dioxide concentration in the lower observation point for the upper observation point was in the range of 0.97~1.01. Carbon dioxide concentration was slightly higher in the upper observation point. Because carbon dioxide in the lower observation point was closer on the surface of the foreshore and absorbed from atmosphere to the foreshore. In this study, it was showed that the vertical variation of carbon dioxide concentration was insignificant in the several meter scale of atmosphere on the surface of the foreshore.

• Journal of Korean Society for Atmospheric Environment
• /
• v.10 no.1
• /
• pp.24-31
• /
• 1994

Hourly variation of gaseous nitrous acid( HNO$_2$) concentration in Seoul air was monitored from Jan. 11 to SeP. 12, Nitrous acid concentration was determined by DS/IC over nine months of observation, HNO$_2$ range from 0.04 ppb to 5.5 ppb. Gor-tex tube as gaseous HNO$_2$generator in this study is thought to be more convenient and reproducible device than previous generator. As a result of NaOH instead of Na$_2$ CO$_3$/NaHCO$_3$ solution as the IC eluent, we could obtain more stable baseline. The concentration of the NaOH eluent was 15 mM . The limit of detection(3$\sigma$) of the liquid- Phase and gas phase nitrous acid of this method are 1.1ng/$m\ell$ , 0.04 n $\ell$ / $\ell$, respectively. The precisions evaluated by 10 replicate analysis of standard solution and standard gas generated are $\pm$1.59, $\pm$2. 89% RSD, respectively. Due to the lack of standard material for air, direct assessment of the accuracy was not possible. This study was applied to the analysis of Seoul ambient air and their results are reported herein.

• Journal of Korean Society for Atmospheric Environment
• /
• v.1 no.1
• /
• pp.93-98
• /
• 1985

Mass size distribution of atmospheric particulates were measured using an Andersen using an Andersen sampler in urban air. The atmospheric particulates were fractionated in eight stages of an Andersen sampler operating at 28.4$\ell/min$ and collected on polyester sheets. A quartz filter was placed behind the last stage collect permeated partculates. The size distribution of atmospheric particulates were divided around 1-2 $\mu$m into two groups, coarse and fine particulates regardless of sampling times. The variation of course particulates concentration was higher than fine particulates among sampling times. Different meterorological conditions and natural phenomena brought high variation of course particulates' concentration. The rain caused removal of coarse particulates seriously and the yellow and may take part in a increase of the course particulates in spring. The average concentration of atmospheric particulates to be collected by Andersen sampler was 170.8 $\mug/m^3$ during 3 times of sampling. Among them the average concentration of atmospheric particulates which could penetrated under a bronchi and alveoli were 70.4$\mug/m^3$ and 36.6$\mug/m^3$ respectively.

• Journal of Korean Society for Atmospheric Environment
• /
• v.2 no.2
• /
• pp.41-50
• /
• 1986

Urban aerosol concentrations in the size range of $0.01 \sim 1.0 \mum$ have been measured by using an electrical aerosol analyzer from May through October, 1984. The total diurnal variation of the number concentration indicates that a minimum value is observed at 3 hr and a sharp increase is noticed early in the morning with a subsequent slow and continuous increase from around 7 hr until 20 hr. After that it is decreased to reach its minimum by dawn. However, both surface and volume concentrations have shown that their first maxima at 8 hr and their second at about 20 hr simultaneously. It is found that the aerosol number is mainly governed by the particles in the size range of $0.01 \sim 0.1 \mum$, while most volume is in $0.1 \sim 1.0 \mum$ size range. It is known fact that particles of $0.1 \sim 1.0 \mum$ size range affect the visibility reduction in the atmosphere. The monthly variation of aerosol concentration remarks its minimum in summer. The main factors influencing the aerosol concentration are emission of autoexhausts, various processes of production and removal, and meteorological parameters.

• Journal of the Korean Applied Science and Technology
• /
• v.19 no.1
• /
• pp.68-72
• /
• 2002

We have seen the effects of buffer layer in organic light-emitting diodes(OLEDs) using poly(N-vinylcarbazole)(PVK) depending on a concentration of PVK. Polymer PVK buffer layer was made using spin casting technique. Two device structures were fabricated; one is ITO/TPD/$Alq_{3}$/Al as a reference, and the other is ITO/PVK/TPD/$Alq_{3}$/Al to see the effects of buffer layer in organic light-emitting diodes. Current-voltage-luminance characteristics and an external quantum efficiency were measured with a variation of spin-casting rpm speeds and PVK concentration. We have obtained an improvement of external quantum efficiency by a factor of four when the PVK concentration is 0.1wt% is used. The improvement of efficiency is expected due to a function of hole-blocking of PVK in OLEDs.

• Journal of Environmental Science International
• /
• v.13 no.1
• /
• pp.27-36
• /
• 2004

Present study analyzed the temporal and spatial characteristics of PM10 pollution in Metropolitan Daegu area based on air pollution monitoring station data and measurements of PM10 concentrations in background area in order to provide essential data for efficient PM10 pollution management. The significant variation of spatial and temporal PM10 concentrations in Daegu area was observed during the study years. The highest maximum PM10 concentration(332 $\mu\textrm{g}$/㎥), average concentration(88 $\mu\textrm{g}$/㎥) and frequency exceeding PM10 daily standard(150 $\mu\textrm{g}$/㎥) were all observed in Namsandong located near a major roadway. The hourly and weekly variations of PM10 concentrations had different pattern for the measurement sites. The monthly and seasonal concentrations exhibited a notable characteristic： the maximum concentration was obtained in spring season, most likely due to Yellow sand effects. Furthermore, this temporal variation of PM10 pollution varied with study site. Meanwhile, the PM10 values measured at the monitoring site, Manchondong, were comparable with those of a control site. The average PM10 concentration ranged from 23 $\mu\textrm{g}$/㎥ to 115 $\mu\textrm{g}$/㎥ with a mean value of 53 $\mu\textrm{g}$/㎥ in the former site and from 22 $\mu\textrm{g}$/㎥ to 91 $\mu\textrm{g}$/㎥ with a mean value of 45 $\mu\textrm{g}$/㎥ in the latter site.

• Asian-Australasian Journal of Animal Sciences
• /
• v.19 no.8
• /
• pp.1134-1138
• /
• 2006

Forest tree leaves (12 different species) of semi hilly arid region of Punjab State were collected at 30-day interval throughout the year to assess the seasonal variations in tannin profile. Tannins were extracted and fractionated from fat free samples and data were analyzed statistically by $12{\times}12$ factorial design. The leaves of Anogeissus latifolia had the highest (p<0.05) concentration of total phenols (17.4%), net (15.9%) and hydrolysable (16.9%) tannins, followed by leaves of Acacia nilotica. Majority of the tree leaves selected had moderate levels (2-5%) of net tannins. Leaves of Carrisa had the highest (p<0.05) concentration of condensed tannins (CT), whereas the leaves of Anogeissus had the lowest (p<0.05) concentration of condensed tannins. The protein precipitable phenols (PPP) corresponded well with the net tannin content present in different tree leaves. Seasonal variation data revealed that in summer, net tannins and PPP decline in leaves of Bauhinia and Zizyphus whereas the net tannin content of Anogeissus and that of Carrisa increased during summer. The CT and PPP content in the leaves of Pheonix, Leucaena, Zizyphus and Ougenia increased in winter till spring season. Tree leaves generally had higher concentration of HT during summer months. It was concluded that leaves of leaves of A. nilotica, A. latifolia and L. leucocephala could serve as an excellent alternate feed stuffs for ruminants. However, leaves of Phoenix, Carrisa, Bauhinia and Dodonea should be avoided.