• 제목/요약/키워드: Concentration variation

검색결과 2,461건 처리시간 0.025초

都市大氣의 水銀動態와 影響因子에 關한 硏究 (Study on the Behavior of Gaseous Mercury and its Influencing Factors in Urban AMbient Air)

  • 김민영;박상현;박성배
    • 한국대기환경학회지
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    • 제5권1호
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    • pp.11-21
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    • 1989
  • Atmospheric gaseous mercury was automatically measured by a mercury air monitor (Mercury monitor AM-1). The sample air was led to a scrubber and washed with buffer solution, and mercury was trapped with gold coated chromosorb P(AW) was successively eluted by heating the chromosorb and then detected by the cold vapor atomic absorption spectrophotometry. $SO_2, TSP, NO_x, CO, THC$. and some of meteorological factors were also measured simultaneously with mercury. A significant correlation between the concentration of mercury and those of 2,513 measurements, gaseous mercury concentration ranged from 4.73 to 112.8 $ng/m^3$ with an annual mean of 14.7$ng/m^3$ in urban area. At this place there was a clear seasonal variation with a maximuminDecember-January and aminimum in March-June. A secondary maximum existed in August to September. THe seasonal variation was found that the gaseous mercury in ambient air has a tendency to become low in spring and high in winter. Namely, the average of concentration in winter was about two times, 19.2 $ng/m^3$, higher than that in spring. In Seoul mercury levels on some months mainly Septermber-October increase with increasing relative humidity of the atmosphere. In Olympic park air levels were 8.2 (range 4.4-23.7)$ng/m^3$ with an coefficients of variation of 0.34 and in Seoul sports complex those were 7.7 (rnage 4.4-25.5) $ng/m^3$ with an coefficients of variation of 0.38 within the Seoul olympiad holding period of time. A significant diurnal mercury variation occurs both at the measuring sites and in the period of observation.

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실내 체적과 라돈 농도와의 상관관계 연구 (A Study on the Correlation between the Volume of Indoor Space and the Measured Concentration of Indoor Radon)

  • 강성아;한동현;김종일
    • Journal of Radiation Protection and Research
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    • 제32권3호
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    • pp.97-104
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    • 2007
  • 전주시에 소재한 아파트의 큰 방과 작은 방을 대상으로 실내 체적과 측정되는 라돈 농도와의 상관 관계를 분석하였다. 또한 실내의 라돈 농도를 측정하여 실내의 시간별 라돈 농도의 변화를 파악하고 이를 토대로 실내 라돈의 년간 피폭선량을 계산하였다. 본 연구를 위하여 각각 8개의 아파트 큰 방과 작은 방을 대상으로 라돈 농도를 측정하였으며, 큰 방의 평균 체적은 $31.59\;m^3$ 그리고 작은 방의 평균 체적은 $16.82\;m^3$이었다. 큰 방의 평균 라돈 농도는 $71.73\;Bq/m^3$, 작은 방의 평균 라돈 농도는 $108.51\;Bq/m^3$로 측정되어 실내 체적과 실내 라돈 농도는 반비례 관계로 나타났다. 밀폐된 실내 라돈 농도의 주 발생원이 건축자재임을 감안하여 건물 벽의 표면적을 체적으로 나누어 계측해 본 결과 표면적/체적의 비가 클수록 측정되는 실내 라돈 농도가 크게 나타났다. 실내 라돈 농도의 하루 중 시간에 따른 변화를 조사한 결과 오전 $8{\sim}10$시에 일 최고 농도($114.5\;Bq/m^3$)를 보였고, 오후 $2{\sim}4$시에 일 최저농도($67.7\;Bq/m^3$)를 나타냈으며, 하루 중 라돈 농도의 변화는 약 $46.8\;Bq/m^3$이었다. 8개 지점의 실내 라돈의 연간 피폭선량을 계산해 본 결과 0.3에서 2.16 mSv/yr사이로 나타나, 일부 아파트의 피폭선량이 국제방사선영향과학위원회(UNSCEAR)가 제시한 수치인 1.3 mSv/yr를 초과했다.

유동층 연소로에서 유$cdot$무연탄 혼합 연소시 대기오염물질 배출에 관한 연구 (A Study on Contaminant Emission and Combustion of Anthracite-Bituminous Coal Blend in a Fluidized Bed Coal Combustor)

  • 조상원;정종현;손병현;김영식;오광중
    • 한국환경보건학회지
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    • 제22권3호
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    • pp.28-36
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    • 1996
  • The objects of this study were to investigate emissions of air pollutant the particles as well as the combustibility of the low grade domestic anthracite coal and imported high-calorific bituminous coal in the fluidized bed coal combustor. The production of air pollution from anthracite-bituminous coal blend combustion in a fluidized bed coal combustor was evaluated. The effects of air velocity and anthracite fraction on the reaching time of steady state condition was also evaluated. We used coal samples the domestic low grade anthracite coal with heating value of 2,010 kcal/kg and the imported high grade bituminous coal with heating value of 6,520 kcal/kg. The experimental results are presented as follows. The time of reaching to steady state was affected by the temperature variation. The steady state time was about 120 minute at 0.3 m/s which was the fastest. It has been found that $O_2$ and $CO_2$ concentration were reached steady state at about 100 minute. As the height of fluidized bed becomes higher, the concentration s of $SO_2$ and $NO_x$ mainly increased. The concentration of freeboard was the highest and emission concentration was diminished. Also, as anthracite fraction increased, the emission of $SO_x$ concentration was increased. But, it has been found that the variation of $NO_x$ concentration with anthracite fraction was negligible and the difference of emission concentration according to air flow rates was negligible, too. It has been found that $O_2$ concentration decreased and $CO_2$ concentration increased as the height of fluidized bed increased. As anthracite fraction increased, the mass of elutriation particles increased, and $CO_2$ concentration decreased. Also, as air velocity increased, $O_2$ concentration decreased and $CO_2$ concentration increased. Regardless-of anthracite fraction and flow rate, the combustible weight percentage in elutriation particles were high in the case of fine particles.

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청정지역과 도시지역의 오존농도 특성 연구 (A Study on the Characteristics of Rural and Urban Surface Ozone Conentrations)

  • 서명석;박경윤;이호근;장광미;강창희;허철구;김영준
    • 한국대기환경학회지
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    • 제11권3호
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    • pp.253-262
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    • 1995
  • A study has been performed on the characteristics of rural and urban surface ozone concentration for the period of March 1992 to February 1993. The monitoring station of rural ozone is located at Kosan, Cheju and other urban monitoring stations are located at Seoul, Pusan and Kwangju. Rural's and urban's ozone data exhibit a distinct features in many ways. First, annual mean of rural ozone concentration os very high(42 ppbv) but urban's are very low(10 .sim.15 ppbv). Second, rural ozone data shows a seasonal variation with it's maximum in spring, and minimum in summer, but urban's show a seasonal variation with it's maximum in spring, and minimum in winter. Third, diurnal variation of rural data is very small but that of urban's are very large. Fourth, urban's data are extremely low(< 3 ppbv) and have no seasonal variations.

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인체 호흡 영역에서의 대구시 대기질에 관한 연구 (Breathing Zone Air Quality in Taegu)

  • 조완근;손상호
    • 한국환경과학회지
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    • 제5권1호
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    • pp.7-14
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    • 1996
  • Two experiments were conducted to evaluate breathing zone air quality in Taegu, using automatic analyzers for four air quality standards($SO_2$, $NO_2$, CO, and $O_3$). First, air target compounds were measured for 8 to 12 hours in each of two commercial areas and five residential areas. Second, air target compounds were hourly measured for 24 hours in each of two commercial areas, two residential areas, and an industrial complex area. Based on the first experiment the breathing zone air was more polluted in the commercial area as compared to the residential area, while the second experiment showed that the breathing zone air was polluted rather in the residential are3 as compared to the commercial area. The second experiment also indicated that there was some variation of breathing zone air concentration with time and measuring sites. Diurnal variation of breathing zone air concentrations was consistent with previous studies which measured at building height. The highest breathing zone air concentration was shown in Seongseo industrial complex area. An unusual finding of this study was that $SO_2$ concentration in the breathing zone air of Bisandong, a typical residential area of Taegu, was higher than that of other residential areas, even higher than that of Seongseo industrial complex area.

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ELISA를 이용한 cortisol 측정법의 정립 및 임상적 응용 (Development of ELISA for cortisol and it's application to clinical use)

  • 나기정;이창우
    • 대한수의학회지
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    • 제36권3호
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    • pp.731-741
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    • 1996
  • ELISA kit for cortisol was developed and then evaluated. Polyclonal antihydrocortisone-3-(o-carboxymethyl)oxime BSA rabbit serum was used to coat the 96-well microplates. The minimum detection limit of the kit was 250pg of cortisol per milliliter. The within-run variation and the day to day variation of the ELISA system were 2.0 and 5.9 at maximum, respectively. The kit was used to determine whether salivary cortisol concentration could replace blood cortisol concentration in dexamathasone suppression test of dogs. Changes of cortisol concentration were measured in serum or saliva after intravenous administration of 0.01mg of dexamethasone per kilogram of body weight. Blood alone, saliva alone or both were collected at 0, 30, 60, 120, 240, and 360 minutes after injection of dexamethasone. The change in blood cortisol concentration was found to be suitable in dexamathasone suppression test of dogs, but the change in salivary cortisol concentration was not. The kit was also used to determine whether salivary cortisol concentration could be a stress index as well as blood cortisol concentration in dogs. Two types of trial were performed to estimate the stress either by blood or salivary cortisol concentration. The first trial was stress experiment by intravenous injection of 0.2IU of PZI-insulin per kilogram body weight. Either blood alone or saliva alone was collected at 0, 30, 60, and 90 minutes after insulin administration. Both blood and salivary cortisol concentration were found to be suitable index in estimating stress from hypoglycemia by injection of insulin. The second trial was stress experiment by electrical irritation. The dogs were irritated with anti-bark device for 10 seconds. Blood was collected before and at 2 and 5 minutes after electrical irritation. Saliva was collected before and at 3 and 6 minutes after electrical irritation. The blood cortisol concentration, but not the salivary cortisol concentration was found to be suitable index in estimating stress from electrical irritation. Cushing syndrome in a dog was also successfully diagnosed with this kit.

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대구상공에서의 대기 오염 물질 확산에 관한 연구 (A Study on the Diffusion of Atmospheric Pollutants over Taegu)

  • 윤일희;민경덕;박동재
    • 한국환경과학회지
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    • 제3권3호
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    • pp.241-252
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    • 1994
  • Meteorological parameters In the atmospheric boundary layer and the vertical and horizontal dispersion parameters were determined by analyzing the data obtained by the special upper-air observations of one clear day for each season from October 1991 to August 1992. The concentration of the aklospheric pollutants over Taegu was analyzed by using the application of the Gaussian diffusion model. In the diurnal variation of diffusion of atmospheric pollutants, vertical diffusion due to turbulence is active in daytime while horizontal diffusion due to wind is active in nighttime. The mean concentration of pollutants in the side of downwind is higher during the daytime than the nighttime. Thus, the height of the mixed-layer at the nighttime considered as the most important parameter of the mean concentration of pollutants. In the seasonal variation of diffusion of atmospheric pollutants, vertical diffusion due to strong solar radiation is active in summer case day, and horizontal diffusion due to strong wind is active in winter case day. In winter case day, the mean concentration of pollutants in the side of downwind is maximum in the daytime. However, in summer case day, that is maximum in the nighttime.

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확산측정기를 이용한 대전시 도로변에서의 이산화질소 측정 (Nitrogen Dioxide Measurement with Diffusive Passive Samplers at the Curbside Points in Daejeon)

  • 임봉빈;김선태;양흥모
    • 한국대기환경학회지
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    • 제24권2호
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    • pp.143-152
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    • 2008
  • This study investigates the variation and spatial distribution of nitrogen dioxide($NO_2$) concentrations measured with passive diffusive samplers at 40 curbside points in Daejeon. Average $NO_2$ concentration was $39.8{\pm}18.0\;ppb$ (n=1,127) and the significant difference in concentrations by regional groups (Dong-gu, Jung-gu, Seo-gu, Daedeok-gu, Yuseong-gu) was not observed. The frequency distribution of $NO_2$ concentration was found to be a normal distribution with the high frequency in the concentration range of 30 to 40 ppb (20 to 25%). Average $NO_2$ concentration measured during the rainy periods was lower than that measured during the non-rainy periods and the decrease of concentration by rainfall was about 16% (7 ppb). The variation of $NO_2$ concentrations measured by passive diffusive samplers during the sampling period was similar to that continuously measured at the air quality monitoring station.

AERONET 선포토미터 데이터를 이용한 동북아시아 지역 대기 에어로졸 종류별 광학적 농도 변화 특성 연구 (A Study on the Variation of Aerosol Optical Depth according to Aerosol Types in Northeast Asia using Aeronet Sun/Sky Radiometer Data)

  • 노영민
    • 한국대기환경학회지
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    • 제34권5호
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    • pp.668-676
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    • 2018
  • This study has developed a technique to divide the aerosol optical depth of the entire aerosol (${\tau}_{total}$) into the dust optical depth (${\tau}_D$) and the pollution particle optical depth (${\tau}_P$) using the AERONET sun/sky radiometer data provided in Version 3. This method was applied to the analysis of AERONET data observed from 2006 to 2016 in Beijing, China, Seoul and Gosan, Korea and Osaka, Japan and the aerosol optical depth trends of different types of atmospheric aerosols in Northeast Asia were analyzed. The annual variation of ${\tau}_{total}$ showed a tendency to decrease except for Seoul where observation data were limited. However, ${\tau}_D$ tended to decrease when ${\tau}_{total}$ were separated as ${\tau}_D$ and ${\tau}_P$, but ${\tau}_P$ tended to increase except for Osaka. This is because the concentration of airborne aerosols, represented by Asian dust in Northeast Asia, is decreased in both mass concentration and optical concentration. However, even though the mass concentration of pollution particles generated by human activity tends to decrease, Which means that the optical concentration represented as aerosol optical depth is increasing in Northeast Asia.

소규모 오수처리를 위한 $A_{2}O$ SBR과 $A_{2}O$ SBBR에서 유입 유기물 농도변화에 따른 염양염류 제거 특성 비교 (A Comparison of Nutrients Removal Characteristics by the Variation of Organics in $A_{2}O$ SBR and $A_{2}O$ SBBR for the Small Sewerage System)

  • 박영식;정노성;김동석
    • 한국환경보건학회지
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    • 제32권5호
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    • pp.451-461
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    • 2006
  • Laboratory scale experiments were conducted to study the conversion of sludge from conventional activated sludge to nitrogen-phosphorus removal sludge using two types of sequencing batch reactor (SBR) systems, a conventional SBR and sequencing batch biofilm reactor (SBBR). The nitrogen and phosphorus removal characteristics were similar between SBR and SBBR and the removal efficiencies were very low when the influent TOC concentrations were low. The nitrogen and phosphorus removal efficiencies in SBR were 96% and 77.5%, respectively, which were higher than those in SBBR (88% and 42.5%) at the high influent TOC concentration. In SBBR, the simultaneous nitrification-denitrification was occurred because of the biofilm process. The variations of pH, DO concentration and ORP were changed as the variation of influent TOC concentration both in SBR and SBBR and their periodical characteristics were cleary shown at the high influent TOC concentration. Especially, the pH, DO concentration and ORP inflections, were cleary occurred in SBR compared with SBBR.