• Title/Summary/Keyword: Concentration of Solution

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Co-deposition of Si Particles During Electrodeposition of Fe in Sulfate Solution (황산철 도금액 중 Si 입자의 공석 특성)

  • Moon Sung-Mo;Lee Sang-Yeal;Lee Kyu-Hwan;Chang Do-Yon
    • Journal of Surface Science and Engineering
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    • v.37 no.6
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    • pp.319-325
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    • 2004
  • Fe thin films containing Si particles were prepared on metallic substrates by electrodeposition method in sulfate solutions and the content of codeposited Si particles in the films was investigated as a function of applied current density, the content of Si particels in the solution, solution pH, solution temperature and concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film was not dependent on the applied current density, solution pH and solution temperature, while it was dependent on the content of Si particles in the solution and the concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film increased with increasing content of Si particles in the solution but reached a maximum value of about 6 wt% when the content of Si particles in the solution exceeds 100 g/l. On the other hand, the content of Si codeposited in the film increased up to about 17 wt% with decreasing concentration of $FeSO_4$$7H_2$O in the solution. These results would be applied to the fabrication of very thin Fe-6.5 wt% Si sheets for electrical applications.

Experiments on a Regenerator with Thermosyphon for Absorption Heat Pumps (기포 펌프를 적용한 흡수식 열펌프용 고온 재생기의 작동 특성 실험)

  • Park, C.W.;Jurng, J.;Nam, P.W.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.463-472
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    • 1996
  • Experiments were carried out to study the operation characteristics of a regenerator with a thermo-syphon pump and a surface-flame burner for a lithium bromide (LiBr)-water absorption heat pump. A cylindrical-shape metal-fiber burner and commercial grade propane were used. The emission of carbon monoxide and nitric oxide was measured by a combustion gas analyzer. Ther regeneration rate of water vapor as a refrigerant was measured. It could be as a reference value showing the performance of the regenerator. The circulation rate of the LiBr-water solution was also measured from both the tanks for the weak-and the strong-solution. Using a refractometer, the LiBr concetration in the solution was calculated from the measured refractory index of the solution. Temperature of the solution and the condensed water was recorded at several points in the experimental apparatus with thermocouples, using a personal computer. This data collecting system for measuring temperature was calibrated with a set of standard thermometers. The generating rate of water vapor as refrigerant increased linearly with heat supplied. It was about 4.0g/s with the heat supplied at a rate of 16,500kcal/h. The circulation rate of LiBr solution also increases with the heat supplied. The difference in LiBr concentrations between the weak and the strong solution was in the range of 1 to 5% when the concentration of the strong solution was about 60%. It was dependent upon both the heat supplied and the circulation rate of the solution. The initial concentration and the level of the LiBr solution in the regenerator were measured and recorded before experiments. The effect of them on the generating rate of water vapor and the circulation rate of the solution was also studied. The generating rate of water vapor was not strongly dependent upon both the level of the LiBr solution and the initial LiBr concentration. However, the concentration difference of the solution increases with the initial level of the LiBr solution.

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Antibacterial Activity and the Stability of an Ag+ Solution made using metallic Silver (금속 은으로 제조한 Ag+ 용액의 항균효과와 안정성)

  • 강환열;정명주;정영기
    • KSBB Journal
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    • v.15 no.5
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    • pp.521-524
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    • 2000
  • An Ag+ solution was made by supplying pure metal silver in filtrated distilled at constant voltage. the solution at an Ag+ concentration of 10 ppm showed specific activity against Gram positive and negative bacteria, and more than 90% activity against Candida albicans ATCC 102321 at the same concentration. The ionic solution produced was stable with regard to antibacterial activity and an Ag+ Concentration in the temperature range of 4$^{\circ}C$∼37$^{\circ}C$ for more than 4 weeks. In addition, the no pH change was observed under there conditions and the solution was confirmed stable by adjusting pH from 5.5 to 6.5.

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The Dispersion Stability of $\alpha-Fe_2O_3$ Particulate Soil in the Anionic/Nonionic Mixed Surfactant Solution (음/비이온계 혼합계면활성제 용액에서 $\alpha-Fe_2O_3$ 입자의 분산안정성)

  • 정선영;강인숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.6
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    • pp.854-861
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    • 2004
  • To estimate dispersion stability of particles in anionic and nonionic surfactant mixed solution, suspending power was examined as functions of duration time of suspension, ionic and nonionic surfactant mixed ratio, surfactant concentration, kinds of electrolyte, ionic strength and mole numbers of oxyethylene additions to nonionic surfactant using $\alpha$-Fe$_2$O$_3$ particle as the model of particulate soil. The suspending power of anionic and nonionic surfactant mixed solution was relatively higher than that of anionic and nonionic surfactant single solution regardless of solution concentration. The suspending power was gradually decreased with increasing duration time of suspension. In the absence of electrolyte, the effect of surfactant concentration on suspending power was small but in solution with electrolyte, suspending power was lowest at 1 % surfactant concentration. With 1${\times}$10$^{-3}$ ionic strength and polyanionic electrolyte in solution, the suspending power was high but effects of oxyethylene mole number to nonionic surfactant on suspending power was small. Generally the suspending power was gradually increased with decreasing the particle size. Hence the suspending power was inversely related to the particle size.

Experimental study of Heat Transfer and Pressure Drop Characteristics for the Welded Plate Heat Exchanger (용접형 판형 열교환기의 열전달 및 압력강하 특성에 관한 실험적 연구)

  • Jeong, Jong-Yun;Kim, Sung-Soo;Kang, Yong-Tae
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.419-424
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    • 2008
  • Heat transfer and pressure drop characteristics of welded plate heat exchanger are studied to apply it for the solution heat exchanger of 210RT absorption system. This study quantifies the effect of mass flow rate and strong solution concentration on the heat transfer coefficient and pressure drop in the plate heat exchanger. The concentration of weak solution is fixed at 55% and the strong solution varies 55%, 57%, and 59% in mass. The results show that the overall heat transfer coefficient and pressure drop increase linearly with increasing Reynolds number. It is also found that the heat transfer coefficient of hot side increases with increasing the concentration of strong solution while the strong solution concentration has no effect on heat transfer coefficient of cold side.

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An Experimental Study on Beat and Mass Transfer Characteristics of Helical Absorber (헬리컬 흡수기의 열ㆍ물질전달 특성에 관한 실험적 연구)

  • Kwon, Oh-Kyung;Yun, Jae-Ho;Yoon, Jung-In
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.1
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    • pp.81-88
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    • 2004
  • In this study, heat and mass transfer characteristics of five components solution (LiBr+Lil+LiNO$_3$+LiCl+$H_2O$) which could be substituted for commonly used LiBr solution are tested using a helical absorber. The arrangement of helical-typed heat exchangers allows to make the system more compact as compared to conventional one. The effects of experimental parameters, such as the solution flow rate, cooling water, solution temperature, solution concentration and surfactant have been investigated in view of the heat and mass transfer. The results of the experiment of heat and mass transfer performance show that five components solution should have 2% higher concentration fur equal absorption capacity of LiBr solution. But considering that five components solution have higher solubility than LiBr solution about 4% high concentration, five components solution could be applied to a small sized water cooled or air cooled absorption chiller/heater. The increase of heat and mass transfer coefficient by surfactant addition is about 25∼30% and 23∼40% respectively.

Effect of the Concentration of Cobalt Chloride Solution for the Preparation of Nano-Sized Cobalt Oxide Powder by Spray Pyrolysis Process

  • Yu, Jae Keun;Cha, Kwang Yong;Seo, Dong Jun;Han, Joung Su;Jang, Jae Bum;Lee, Yong Hwa;Kim, Dong Hee
    • Korean Journal of Materials Research
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    • v.24 no.6
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    • pp.277-284
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    • 2014
  • Using the spray pyrolysis process, nano-sized cobalt oxide powder with average particle size below 50 nm was prepared from cobalt chloride solution. The influences of the raw material solution on the properties of the powder formed examined. When the concentration of Co was low(20 g/L), the average particle size of the powder formed was roughly 20 nm, and the cohesion between these particles was significantly strong. When the concentration of Co increased to 100 g/L, the droplets nearly failed to exist in circular form and reflected a severely divided form. Furthermore, the average size of the particles formed was roughly 40 nm, and the particles reflected a polygonal form. When the solution was increased to nearly saturation level (Co at 200 g/L), the particle size distribution reflected significant unevenness due to severe droplet division while the surface also reflected significant unevenness. Furthermore, the average size of the particles formed increased significantly to 70 nm. The results of XRD analysis showed that the strength of the peaks reflected very little change when the concentration of Co was increased from 20 g/L to 50 g/L. Alternatively, when the concentration was increased to 100 g/L, the strength of the peaks increased compared to when the concentration was 50 g/L. However, when the concentration was increased to 200 g/L, the strength of the peaks failed to reflect significant change compared to when the concentration was 100 g/L. The specific surface area dramatically decreased by 30 % when the concentration of Co was increased from 20 g/L to 50 g/L. Alternatively, when the concentration of Co the solution increased to 100 g/L, the specific surface area decreased by roughly 15 %. Furthermore, when the concentration of Co was increased to nearly saturation level(200 g/L), the specific surface area decreased by roughly 35%.

Adsorption Characteristics of Alkaline Copper Quat Preservative Components in Wood (구리⋅알킬암모늄화합물계 목재방부제 (ACQ) 유효성분의 목재 흡착 특성)

  • Lee, Jong-Shin;Choi, Gwang-Sik
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.491-498
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    • 2014
  • In order to obtain basic data for concentration control of alkaline copper quat (ACQ) solution in wood preservative treatment, this study investigates the change of concentration and adsorption of treating solution and active ingredient, copper oxide (CuO) and didecyldimethyl ammonium chloride (DDAC), in the process of recycling of ACQ solution. Japanese larch (Larix leptolepis), Douglas-fir (Psedotsuga menziesii) and Radiata pine (Pinus radiata) were treated with ACQ solution. The active ingredient concentration of ACQ solution was decreased continuously with increase of recycling. There are differences between extent of concentration decrease of Cu (as CuO) and DDAC. DDAC was decreased more quickly and to a higher degree than Cu for all recycling. The extent of DDAC concentration decrease was remarkable than that of Cu for wood species. The amount of DDAC adsorbed into wood decreased with the increase of ACQ solution recycling, but adsorption of Cu was little difference regardless of recycling. The adsorption of Cu into wood increased as DDAC concentration decrease by recycling of ACQ solution. This is likely due to decrease of DDAC competition with Cu for the same reaction site in wood.

Preparation of Optically Anisotropic Film by Sunset Yellow Chromonic Liquid Crystal (Sunset Yellow 액정 색소를 이용한 광학적 이방성 필름 제조)

  • Kim, Byungchul;Chang, Eugene;Shin, Seunghan
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.81-86
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    • 2011
  • The aqueous solution of Sunset Yellow-FCF (SY-FCF) began to show schlieren texture at room temperature when its concentration reaches 25 wt%. A further increase of the concentration of SY-FCF to 28 wt% resulted in a perfect nematic liquid crystal phase. However, more than 30 wt% of SY-FCF in aqueous solution was required to make an optically anisotropic film simply by shear coating. In our study, concentration of SY-FCF solution, coating speed, drying temperature, and relative humidity were considered as coating parameters affecting the preparation of optically anisotropic thin films. From analysis of variance analysis (ANOVA), the solution concentration was revealed as a main factor affecting the film thickness. The drying temperature and solution concentration were main factors affecting the transmittance of parallel direction ($T_o$). Especially, SY-FCF aqueous solution with high concentration induced a better alignment of LC columns and produced highly oriented anisotropic films. In this study, optically anisotropic films prepared by 33 wt% of SY-FCF in aqueous solution showed 89.7~98.7% of degree of polarization.

Effect of Sodium Chloride on Stress-Deformation of Sand Bentonite Mixture (염분이 모래와 벤토나이트 혼합토의 응력 변형에 미치는 영향)

  • 안태봉
    • Geotechnical Engineering
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    • v.13 no.2
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    • pp.17-28
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    • 1997
  • In this study sodium chloride solution is employed for chemicals, and several cylindrical triaxial tests are performed on the sand-bentonite mixtures saturated with sodium chloride solution. Deformation(elastic modulus, E) and strength(cohesion, c', and angle of friction, f') parameters are obtained from the triaxial tests as functions of confining pressure and sodium chloride solution concentrations. The results here indicate an increase in the value of effective cohesion with increase in the concentration of NaCl solution, which can be explained by using the Gouy-Chapman model. The value of the effective angle of shearing resistance does not show significant change with the increase in concentration of NaCl solution. The Young's modulus also increases with the increase in concentration of NaCl solution.

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