• 제목/요약/키워드: Concentration Transition

검색결과 626건 처리시간 0.033초

InSb 결정 성장과 Zn 확산에 관한 연구 (A study on the InSb crystal growth and the Zn diffusion)

  • 김백년;송복식;문동찬;김선태
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1992년도 하계학술대회 논문집 B
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    • pp.816-819
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    • 1992
  • Binary compound semiconductor InSb crystal which has direct-transition energy gap (0.17 ev) grown by vertical Bridgman method, then the electric-magnetic and optical properties of InSb crystal were surveyed. The growth rate of the crystals was 1mm/hr and the lattice constant $a_\circ$ of the grown crystal was 6.4863$\AA$. The electrical properties were examined by the Hall effect measurement with the van der Pauw method in the temperature range of 70$\sim$300K, magnetic field range of 500$\sim$10000 gauss. The undoped InSb crystal was n-type, the concentration and the electron mobility were 2$\sim$6 ${\times}$ $10^{16}$$\textrm{cm}^{-3}$ and carrier mobility was 6$\sim$2${\times}$$10^{4}$$cm^{2}$/v.sec at 300K, respectively. The carrier mobility was decreased with $T^{-1/2}$ due to the lattice scattering above 100K, and decreased by impurity scattering below100K. The magnetoresistance was increased 190% at 9000 gauss as compared with non-appliced magnetic field and the magnetoresistance was increased with increasing the magnetic field. Also, the Hall voltage was increased with increasing the magnetic field and decreasing the thickness of sample. The optical energy band gap of InSb at room temperature determined using the IR spectrometer was 0.167eV. The diffusion depth of Zn into InSb proportionally increased with the square root of diffusion time and the activation energy for Zn diffusion was 0.67eV. The temperature dependence of diffusion coefficient was $D=4.25{\times}10^{-3}$exp (-0.67/$K_BT$).

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Effects of Simultaneous Bending and Heating on Characteristics of Flexible Organic Thin Film Transistors

  • Cho, S.W.;Kim, D.I.;Lee, N.E.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.470-470
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    • 2013
  • Recently, active materials such as amorphous silicon (a-Si), poly crystalline silicon (poly-Si), transition metal oxide semiconductors (TMO), and organic semiconductors have been demonstrated for flexible electronics. In order to apply flexible devices on the polymer substrates, all layers should require the characteristic of flexibility as well as the low temperature process. Especially, pentacene thin film transistors (TFTs) have been investigated for probable use in low-cost, large-area, flexible electronic applications such as radio frequency identification (RFID) tags, smart cards, display backplane driver circuits, and sensors. Since pentacene TFTs were studied, their electrical characteristics with varying single variable such as strain, humidity, and temperature have been reported by various groups, which must preferentially be performed in the flexible electronics. For example, the channel mobility of pentacene organic TFTs mainly led to change in device performance under mechanical deformation. While some electrical characteristics like carrier mobility and concentration of organic TFTs were significantly changed at the different temperature. However, there is no study concerning multivariable. Devices actually worked in many different kinds of the environment such as thermal, light, mechanical bending, humidity and various gases. For commercialization, not fewer than two variables of mechanism analysis have to be investigated. Analyzing the phenomenon of shifted characteristics under the change of multivariable may be able to be the importance with developing improved dielectric and encapsulation layer materials. In this study, we have fabricated flexible pentacene TFTs on polymer substrates and observed electrical characteristics of pentacene TFTs exposed to tensile and compressive strains at the different values of temperature like room temperature (RT), 40, 50, $60^{\circ}C$. Effects of bending and heating on the device performance of pentacene TFT will be discussed in detail.

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수학 문장제 해결에 영향을 주는 언어적.인지적 요인 -혼합물 문제를 중심으로- (Linguistic and Cognitive Factors that Affect Word Problem Solving)

  • 김선희
    • 대한수학교육학회지:수학교육학연구
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    • 제14권3호
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    • pp.267-281
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    • 2004
  • 방정식의 활용 문제로 다루어지는 문장제는 학생들의 흥미를 유도하고 수학의 유용성을 보여줄 수 있는 것이지만, 학생들이 해결하기에는 여러 어려움이 있다. 본 연구는 학생들이 수학 문장제를 해결하는데 영향을 줄 수 있는 요인들을 언어적 측면과 인지적 측면에서 조사하였다. 언어적 요인에는 텍스트 기반, 실세계, 상황 모델이 있었는데, 학생들은 문장의 텍스트 기반에서 방정식의 상황 모델로 해석하는 것을 어렵게 생각하고 있었으며, 상황 모델에서 학생들은 많은 오류를 보였다. 인지적 측면에서는 방정식을 세우는 스키마와 해결 전략, 식의 복잡성 수준을 조사하였는데, 방정식을 세울 때 학생들은 복잡성 수준을 고려하기보다는 교사의 지도 내용에 따라 전략을 선택하는 경향이 있었다. 그리고 설탕의 양이나 농도, 설탕물의 양을 혼동하는 경향이 강했다. 본 연구의 결과를 통해 문장제에서 학생들에게 제시되는 문제가 해결하기에 얼마나 복잡한지, 학생들이 주로 어떤 전략을 선택하는지, 방정식의 문제 유형별로 발생하는 오류에 대해 알 수 있었다.

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Effects of Prepartum Dietary Carbohydrate Source on Metabolism and Performance of Primiparous Holstein Cows during the Periparturient Period

  • Mirzaei Alamouti, H.R.;Amanlou, H.;Rezayazdi, K.;Towhidi, A.
    • Asian-Australasian Journal of Animal Sciences
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    • 제22권11호
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    • pp.1513-1520
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    • 2009
  • Forty-six Holstein heifers were used in a completely randomized design and assigned to 1 of 2 treatments to evaluate the effects of 2 diets varying in ruminal fermentable carbohydrate sources, namely ground corn (GC) and rolled wheat (RW), on metabolism and performance of primiparous cows in the periparturient period. The heifers were fed diets as a total mixed ration (TMR) with similar energy and crude protein content including i) 18.57% GC, or ii) 18.57% RW from -24.13${\pm}$7.73 d relative to expected calving until calving. After calving, all animals received the same lactation diet until 28 d. Animals were group fed from the beginning of the study to -7 d relative to expected calving, fed individually from d -7 to 7 days in milk (DIM), and again group fed to 28 DIM. The pre-partum diets affected (p<0.05) dry matter intake (DMI), energy intake, energy balance (EB) and urinary pH during the last week pre-partum. There was no effect of pre-partum carbohydrate source on overall plasma concentration of glucose, nonesterified fatty acid (NEFA), $\beta$-hydroxybutyrate (BHBA), albumin, triglyceride (TG), cholesterol, aspartate aminotransferase (AST), insulin, and cortisol during the periparturient period. Cows fed the RW diet during the pre-partum period had greater calcium for the first week (p<0.05) and during 28 d (p = 0.08) of lactation compared with heifers fed the GC diet. Primiparous cows fed the RW diet produced greater milk protein content and yield (p<0.05). Primiparous cows fed the RW diet had lower milk urea nitrogen (MUN) and somatic cell count (SCC) than cows fed the GC diet (p<0.05). The results of this study show that feeding pre-partum diets with a rapidly fermentable source of starch but low energy content can improve animal metabolism and performance and smooth the transition of primiparous Holstein cows from gestation to lactation.

계사용 온풍기를 이용한 유해가스처리 복합촉매시스템 개발 (Development of composite catalyst for hazardrous gas treatment using the heat of aviary heating equipment)

  • 장현태;차왕석
    • 한국산학기술학회논문지
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    • 제10권10호
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    • pp.2779-2785
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    • 2009
  • 육류 중에 닭은 가장 저렴한 생산비용으로 단백질을 섭취할 수 있는 장점으로 인하여 많은 양이 사육되며 우리나라 식생활의 육류 소비를 늘리는 중요한 가축이다. 생육조건에 악영향을 미치는 여러 요인 중에 축산업에서 가장 대표적인 것은 악취이다. 악취물질은 축분에서 발생되는 암모니아, 아민류, 황화수소 및 머캡탄을 들 수 있으며 악취는 없으나 악영향을 미치는 물질로는 메탄, 질소산화물 등이 있다. 이러한 악취물질에 의하여 가축은 생육에 저해를 받으며, 심한 경우 폐사까지 이르게 된다. 계사의 경우 겨울철에는 난방을 하고 있는 실정임에도 불구하고 나머지 계절과 같이 환기를 통하여 악취를 제어하고 있다. 겨울철의 경우 대부분의 계사가 등유를 사용하는 온풍기를 이용하여 난방을 하고 있으나 계사내의 유해한 암모니아의 농도가 높아지므로 인하여 환기를 시키고 있는 실정이다. 따라서 본 연구과제에서는 기존에 사용되고 있는 온풍기에 복합촉매시스템을 접합하여 계사 및 축사의 암모니아 등의 유해 가스를 제어할 수 있는 시스템에 사용될 촉매를 개발하였으며, Mn과 Pt-Rh을 최적의 조성으로 도출하였다.

Sildenafil Ameliorates Advanced Glycation End Products-Induced Mitochondrial Dysfunction in HT-22 Hippocampal Neuronal Cells

  • Sung, Soon Ki;Woo, Jae Suk;Kim, Young Ha;Son, Dong Wuk;Lee, Sang Weon;Song, Geun Sung
    • Journal of Korean Neurosurgical Society
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    • 제59권3호
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    • pp.259-268
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    • 2016
  • Objective : Accumulation of advanced glycation end-products (AGE) and mitochondrial glycation is importantly implicated in the pathological changes of the brain associated with diabetic complications, Alzheimer disease, and aging. The present study was undertaken to determine whether sildenafil, a type 5 phosphodiesterase type (PDE-5) inhibitor, has beneficial effect on neuronal cells challenged with AGE-induced oxidative stress to preserve their mitochondrial functional integrity. Methods : HT-22 hippocampal neuronal cells were exposed to AGE and changes in the mitochondrial functional parameters were determined. Pretreatment of cells with sildenafil effectively ameliorated these AGE-induced deterioration of mitochondrial functional integrity. Results : AGE-treated cells lost their mitochondrial functional integrity which was estimated by their MTT reduction ability and intracellular ATP concentration. These cells exhibited stimulated generation of reactive oxygen species (ROS), disruption of mitochondrial membrane potential, induction of mitochondrial permeability transition, and release of the cytochrome C, activation of the caspase-3 accompanied by apoptosis. Western blot analyses and qRT-PCR demonstrated that sildenafil increased the expression level of the heme oxygenase-1 (HO-1). CoPP and bilirubin, an inducer of HO-1 and a metabolic product of HO-1, respectively, provided a similar protective effects. On the contrary, the HO-1 inhibitor ZnPP IX blocked the effect of sildenafil. Transfection with HO-1 siRNA significantly reduced the protective effect of sildenafil on the loss of MTT reduction ability and MPT induction in AGE-treated cells. Conclusion : Taken together, our results suggested that sildenafil provides beneficial effect to protect the HT-22 hippocampal neuronal cells against AGE-induced deterioration of mitochondrial integrity, and upregulation of HO-1 is involved in the underlying mechanism.

비이온계 계면활성제의 독성 평가 및 Polycyclic Aromatic Hydrocarbons(PAHs) 생분해에 미치는 영향 (Toxicity Estimation of Nonionic Surfactants and Their Effect on the Biodegradation of Polycyclic Aromatic Hydrocarbons (PAHs))

  • 박종섭;김인수;최희철
    • 대한환경공학회지
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    • 제22권12호
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    • pp.2107-2113
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    • 2000
  • 세 가지 비이온계 계면활성제(Brij 30, Tween 80, Triton X-l00)의 독성 평가와 polycyclic aromatic hydrocarbons(PAHs)의 생분해에 미치는 영향을 조사하였다. 사용된 세 가지 계면활성제 중에서 Brij 30이 가장 생분해가 잘 되는 것으로 나타났으며, 1.5 g/L까지 아무런 기질 저해 효과가 나타나지 않았다. 이는 사용된 계면활성제가 미생물에 탄소원으로 이용된다는 것을 나타낸다. 수용액상에서 naphthalene과 phenanthrene은 60시간 안에 완전히 분해되었지만 naphthalene의 경우 상당량이 휘발에 의해 손실됨을 알 수 있었다. 슬러리상에서 제어단계는 모래 슬러리의 경우 미생물에 의한 생분해였고, 점토 슬러리의 경우는 흡착표면에서 수용액으로의 물질 전달이었다. TOC분석을 통해 계면활성제를 포함한 거의 모든 기질이 분해됨을 알 수 있었다. pH 변화는 phenanthrene이 산 작용기를 가지는 중간산물로 분해됨을 나타내었다.

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온도 변화에 의한 상전이를 이용한 다공성 동정맥 누관의 개발 (Development of Porous polyurethane Arterial-Venous Shunt by Thermal Phase Transition)

  • 유규하;정재승;정희교;이해광;이규백;김종원;민병구;이해룡
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1997년도 춘계학술대회
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    • pp.447-450
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    • 1997
  • A new technique for the preparation of porous vascular prostheses was investigated. Polyurethane solution (10 to 14wt%) was injected into a mold. After freezing at low temperature $(0^{\circ}C\sim-40^{\circ}C)$, solvent was dissolved out with water at $0^{\circ}C$ to form porous tubes. The average pore size $(<10{\mu}m)$and pore occupation (10% to 51%) were easily changed by changing polyurethane concentration, freezing temperature, and freezing methods. This technique can give a proper pore size $(30\sim60{\mu}m)$ for tissue ingrowth, and suitable compliances for matching with arteries and veins. This method might give a desired compliant graft for artificial implantation with the presently valid medical polymers.

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Dispersion polymerization of styrene and Methylmethacrylate using macromonomers as a reactive stabilizer

  • Jung, Hye-Jun;Lee, Kang-Seok;Choe, Soon-Ja
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.86-88
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    • 2006
  • The novel linear- (V-LUM) and cross-type macromonomers (C-VUM) of vinyl-terminated bifunctional polyurethane were synthesized and applied to the dispersion polymerization of styrene and MMA in ethanol. The existence of the vinyl terminal groups and the grafted macromonomer with styrene and PMMA was verified using 1H NMR and 13C NMR. Monodisperse polystyrene (PS) microspheres were successfully obtained above 15 wt % of macromonomer relative to styrene. The macromonomer can efficiently stabilize higher surface area of the particles compared to a conventional stabilizer, PVP. The grafting ratio of the PS calculated from 1H NMR linearly increased up to 0.048 with 20 wt % of the macromonomer and the high molecular weights (501,300 g/mol) of PS with increased glass transition and enhanced thermal stability were obtained. Furthermore, the stable and monodisperse PMMA microspheres having a weight-average diameter of $5.09{\mu}m$ and a good uniformity of 1.01 were obtained with 20 wt% L-VUM. The molecular weight increased, but the size of the PMMA particles decreased with the macromonomer concentration due to the increased stabilizing effect. The molecular weight of the PMMA was approximately two fold higher than that by a conventional PVP. The L-VUM acts as a reactive stabilizer, which gives polyurethane-grafted PS or PMMA with a high molecular weight. In addition, the XPS result showed that the C-PS (PS using the C-VUM) was anchored with a larger amount of PEG than that of the L-PS (PS using the L-VUM) on the particle surface. Thus, the reaction and stabilizing mechanism of the macromonomers for the formation of PS particles is proposed.

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Morphological, Mechanical and Rheological Properties of Poly(acrylonitrile-butadiene-styrene)/Polycarbonate/Poly$({\varepsilon}-caprolactone)$ Ternary Blends

  • Hong, John-Hee;Song, Ki-Heon;Lee, Hyung-Gon;Han, Mi-Sun;Kim, Youn-Hee;Kim, Woo-Nyon
    • Macromolecular Research
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    • 제15권6호
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    • pp.520-526
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    • 2007
  • The effects of poly($({\varepsilon}$-caprolactone) (PCL) on poly(acrylonitrile-butadiene-styrene) (ABS) and polycarbonate (PC) blends were studied. Blends of ABS/PC (70/30, wt%) with PCL as a compatibilizer were prepared by a twin screw extruder. From the glass transition temperature $(T_g)$ results of the ABS/PC blends with PCL, the $T_g$(PC) of the ABS/PC (70/30) blends decreased with increasing PCL content. From the results of the morphology of the ABS/PC (70/30) blends with PCL, the phase separation between the ABS and PC phases became less significant after adding PCL in the ABS/PC blends. In addition, the morphological studies of the ABS/PC blends etched by NaOH indicated that the shape of the droplet was changed from regular round to irregular round by adding PCL in the ABS/PC blends. These results for the mechanical properties of the ABS/PC blends with PCL indicated that the tensile, flexural and impact strengths of the ABS/PC (70/30) blends peaked at a PCL content of 0.5 phr. From the results for the rheological properties of the ABS/PC (70/30) blends with PCL content, the storage modulus, loss modulus and complex viscosity increased at PCL content up to 5 phr. From the above results of the $T_g$, mechanical properties, morphology and complex viscosity of the ABS/PC blends with PCL, it was concluded that the compatibility was increased with PCL addition in the ABS/PC (70/30, wt%) blends and that the optimum concentration of PCL as a compatibilizer is 0.5 phr.