• Polymer(Korea)
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• v.30 no.6
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• pp.538-544
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• 2006

Two kinds of novel bifunctional methacrylated prepolymers (170-2MA and 631-2MA) which have similar structure with 2,2-bis[4- (2'-hynroxy-3'-methacryloyloxypropoxy)phenyl] propane (Bis-GMA) was synthesized for dental applications as an alternative to Bis-GMA containing bisphenol A that is doubtful as an endocrine disrupter. The organic matrices were prepared by mixing a diluent and/or a monomer with the synthesized methacrylated prepolymers. The yield, viscosity, and chemical structures of the prepolymers and the physical and methanical properties of the organic matrices were evaluated. The yields of the prepolymers synthesized through a ring-opening reaction of epoxy compound and methacrylic acid were above 90% and the viscosities of the prepolymers were much lower than that of the Bis-GMA control. From the results of $^1H-NMR$ and FTIR analyses, the chemical structures of the prepolymers were similar to that of Bis-GMA. In addition, the curing time, poly-merization shrinkage, photoconversion, polymerization depth, and compressive strength of the organic matrices formulated with 170-2MA and 631-2MA prepolymers exhibited comparable to or better than those of the existing Bis-GMA-based one. These results suggest that the novel methacrylated prepolymers which have no endocrine disrupter can be an alternative to Bis-GMA and be applicable to dental polymer materials.

• The Korean Journal of Food And Nutrition
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• v.16 no.4
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• pp.423-429
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• 2003

Kimchi has been worldwide recognized as a traditional Korean fermented food, In the Chinese cabbage's pickling, salt content of evenly penetrate into the tissue affects on the texture of matured kimchi, But the previous method which usually using brine salting has a disadvantage of uneven penetration of salt into the leaves and stems. The purpose of the study is to develope the method which produce superior kimchi by evenly penetrate the salt into the tissue rapidly, The dry salting method is directly spread the salt on the surface of chinese cabbage as percentage in weight with 10, 12, 14, 16%(s) and pickled in this state for 5 hours. Brine salting method is soaking chinese cabbage in the 16% salt solution(16%B) for 20 hours. Sensory evaluation, contents of salt, properties of mechanical hardness and micro structure were studied among fresh cabbage, 16%B and 10, 12, 14, 16%(s) cabbage, The result of salt contents in all groups of pickled chinese cabbage were significantly increased compared with fresh cabbage. The compressive force of cabbage's steams by mechanical measurement was significantly decreased but cutting force was increased. In pickled cabbage, the cutting force was the highest correlated with salt content, In the sensory evaluation, the salty taste of leaves and chewy degree were significantly increased, but the hardness and crips of the stems were significantly decreased by increasing salt contents. Therefore the dry salting is the most excellent pickling method in small amount of kimchi production by saving salt amount and time, furthermore due to even penetration of salt into leaves and stems.

• Journal of Conservation Science
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• v.32 no.4
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• pp.459-469
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• 2016

The goal of this study was to examine property changes induced by the choice of filler used with an epoxy resin that was developed in 2014 to restore cultural assets and consider the applicability of the resin as a restorative agent. The properties of putty mixed with 9 types of fillers and as-developed resins were compared with those of existing materials with regard to stability, superiority and applicability. The potential of the putty as an alternative material was also examined. The materials produced the best adhesiveness, color change and hardness results when mixed with lime. Micro balloon produced the best wear rates and hardening times, while diatomite produced the best tensile and compressive strengths. A plaster and white mineral pigment mixture produced the best specific gravity. Every material except for lime exhibited about 2.5-20 times higher wear rates than the existing material, which is thought to exhibit an excellent cutting force. The hardening time was enhanced by about 0.5-9 times to improve convenience. The stability of the relic was also ensured by improving hand staining without any shrinkage or deformation. The material exhibited about 0.5-27 times less yellowing. Thus, it is thought to be a material that can reduce property changes and reduce the degree of relic fatigue which occurs during reprocessing and sense of difference from relic.

• Journal of the Korea Concrete Institute
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• v.14 no.4
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• pp.449-456
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• 2002

Recently, the application of high strength and high performance concrete has been gradually increased as an important construction material for high rise and huge scaled construction. However, high performance concrete has undesirable characteristics of spalling subjected to high temperature due to its dense microstructure content. A spalling by fire brings surface failure and falling off concrete member. It is considered that spalling by fire should be taken into account for the safety of the concrete structure under fire. Therefore, in this paper, tests are carried out using high performance concrete containing polypropylene(PP) fiber in order to improve the fire resistance performance. PP fiber contents and member sizes are varied. According to experimental results, as for the influence of PP fiber contents, all the test specimens without PP fiber show entire failure in W/C of 35％, while they show nearly sound shape except some kinds of surface fracture in W/C of 55％. When PP fiber is contained more than 0.07％, favorable prevention effects of spatting by fire are obtained. As for the effects of test specimens size, it tends to increase the possibilities of spatting by fire as test specimens become larger. And spatting by fire at the edge of test specimens occurs more frequently than at the surface of test specimens. Residual compressive and tensile strength shows 45∼65 ％ of its original strength at W/C of 35％, and 30∼40％ at W/C of 55 ％.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.307-314
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• 2002

Utilization of demolished-concrete as recycled aggregate has been researched for the purpose of substituting for insufficient natural aggregate, saving resources and protecting environment. There, however, are some Problems not only the large difference of dualities in recycled aggregates but also a little deterioration of mechanical properties in recycled aggregate concrete in comparison with that of natural aggregate concrete. In this study, the test results of freez and thaw durability of concrete with demolished-concrete recycled aggregate(DRA) arc as follows. Improvement of crushing process is an important assignment because that adhered mortar on source-concrete recycled aggregate(SRA) and DRA highly affects thc qualifies of recycled aggregate. The compressive strength of recycled aggregate concrete was not highly different in comparison with that of control concrete. But the resistance to penetration of Cl in recycled aggregate concrete was shown smaller than that of control concrete because of adhered mortar on recycled aggregate. The resistance to frcezing and thawing of recycled aggregate concrete was highly different due to adhered mortar on recycled aggregate, and durability factor of concrete with NA-SRA and DRA was more decreased than that of control concrete. On the other hand, durability factor of concrete with AA-SRA was larger than that of control concrete. It, therefore, is necessarily required that recycled aggregate including adequate entrained air should be used for satisfying the freez and thaw durability of recycled aggregate concrete.

• Journal of the Korea Concrete Institute
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• v.15 no.3
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• pp.409-416
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• 2003

The effects of polymer-cement ratio, antifoamer content and shrinkage-reducing agent content on the air content, setting time, drying shrinkage and strength of polymer-modified mortars using redispersible polymer powder are examined. As a result, the air content of the polymer-modified mortars using redispersible polymer powder tend to decrease with increasing polymer-cement ratio and antifoamer content. Regardless of the antifoamer content, the setting time of the polymer-modified mortars using redispersible polymer powder tend to delayed with increasing polymer-cement ratio. Irrespective of the antifoamer content, the drying shrinkage of the polymer-modified mortars using redispersible polymer powder tend to decrease with increasing polymer-cement ratio and shrinkage-reducing agent content. Regardless of the antifoamer content, the flexural and tensile strengths of the ultrarapid-hardening polymer-modified mortars using redispersible polymer powder tend to increase with increasing polymer-cement ratio, and tend to decrease with increasing shrinkage-reducing agent content. However, the compressive strength of the ultrarapid-hardening polymer-modified mortars using redispersible polymer powder decrease with increasing polymer-cement ratio and shrinkage-reducing agent content.

• Journal of the Korea Concrete Institute
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• v.24 no.2
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• pp.111-120
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• 2012

This paper is a report about lap splice performance of rebar embedded in the strain-hardening cement-based composites (SHCCs) under monotonic and repeated tension loading. Ten mix proportions of cement-based composites such as SHCCs and normal concrete were investigated. The study parameters are comprised of (1) types of reinforcing fibers (polyethylene and steel fiber), (2) replacement levels of expansive admixture (EXA, 0% and 10%), and (3) compressive strength (30 and 100 MPa) of cement-based composites. Lap splice lengths (ld) of rebars in SHCC materials and normal concrete were 60% and 100% of splice length calculated by code requirements for structural concrete, respectively. Test results indicated that SHCCs materials can lead to enhancements in the lap splice performance of embedded rebar. All of the fiber reinforcement conditions (PE-SHCC and PESF-SHCC) considered in this study produced considerable improvements in the tensile strength, cracking behavior, and bond strength of lap-spliced rebar. Furthermore, adding EXA to SHCC matrix improved the tensile lap splice performance of rebar in SHCC materials. However, for controlling crack behavior, the performance of PE-SHCC was better than that of PESF-SHCC due to its mechanical properties. This study demonstrated an effective approach for reducing required development length of lap spliced rebar by using SHCC materials.

• Journal of the Korea Concrete Institute
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• v.23 no.1
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• pp.3-12
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• 2011

The structural behavior of continuous reinforced concrete deep beams is mainly controlled by the mechanical relationships associated with the shear span-to-effective depth ratio, flexural reinforcement ratio, load and support conditions, and material properties. In this study, a simple indeterminate strut-tie model which reflects characteristics of the complicated structural behavior of the continuous deep beams is presented. In addition, the reaction and load distribution ratios defined as the fraction of load carried by an exterior support of continuous deep beam and the fraction of load transferred by a vertical truss mechanism, respectively, are proposed to help structural designers for the analysis and design of continuous reinforced concrete deep beams by using the strut-tie model approaches of current design codes. In the determination of the load distribution ratio, a concept of balanced shear reinforcement ratio requiring a simultaneous failure of inclined concrete strut and vertical steel tie is introduced to ensure a ductile shear failure of reinforced concrete deep beams, and the primary design variables including the shear span-to-effective depth ratio, flexural reinforcement ratio, and concrete compressive strength are implemented after thorough parametric numerical analyses. In the companion paper, the validity of the presented model and load distribution ratio was examined by applying them in the evaluation of the ultimate strength of multiple continuous reinforced concrete deep beams, which were tested to failure.

• Journal of the Korea Concrete Institute
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• v.23 no.1
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• pp.77-86
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• 2011

The concrete creep deformation of a hybrid composite section can cause additional deformation of the composite section and the stress relaxation of pre-compressive stress on the concrete section due to partial restraint of the deformation. In this study, the stress relaxation coefficient method (SRCM) is derived for simple analysis of complicate hybrid or composite sections for engineering purpose. Also, an equation of the stress relaxation coefficient (SRC) required for the SRCM is proposed. The SRCM is derived with the parameters of a creep coefficient, section and loading properties using the same method as the constant-creep step-by-step method (CC-SSM). The errors of the SRCM is improved by using the proposed SRC equation than the average SRC's which were estimated from the CC-SSM. The root mean square error (RMSE) of the SRCM with the proposed SRC equation for concrete with creep coefficient less than 3 was less than 1.2% to the creep deformation at the free condition and was 3.3% for the 99% reliability. The proposed SRC equation reflects the internal restraint of composite sections, and the effective modulus of elasticity computed with the proposed SRC can be used effectively to estimate the rigidity of a composite section in a numerical analysis which can be applied in analysis of the external restrain effect of boundary conditions.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.1
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• pp.113-119
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• 2006

It is now established that more than two types of blended aggregate have beneficial effects on quality and supply of concrete in the long run. However, studies on blended aggregate have not widely been progressive and the evaluation method of its most favorable mixture proportion is still needed. Therefore this study investigated the most favorable mixture proportion through the physical experiment of fresh and hardened state's cement mortar, in response to three types of composite ratio, natural fine aggregate(Ns), crushed fine aggregate(Cs) and recycled fine aggregate(Rs). Test showed that increase of blending ratio of Ns and Cs improved fluidity of mot1ar. For the properties of compressive and flexural strength, mortar blending Ns and Cs properly, exhibited similar value to one using only Cs, while mortar mixing Rs showed lower strength value as less as 6% of control one. Mortar using only Rs exhibited the largest drying shrinkage value. In addition, even thought it is not a clear quantitative analysis, technical-imaging-skill presenting the most favorable mixture proportion 3-dimensionally is proposed in this research, in order to notify the proportion easily.