• Transactions of the Korean hydrogen and new energy society
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• v.31 no.2
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• pp.184-193
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• 2020

One of the technical methods to increase the volumetric energy density of hydrogen is to pressurize the gaseous hydrogen and then contain it in a rigid vessel. Especially for automotive systems, the compressed hydrogen storage can be found in cars as well as at refueling stations. During the charging the pressurized hydrogen into a vessel, the temperature increases with the amount of stored hydrogen in the vessel. The temperature of the vessel should be controlled to be less than a limitation for ensure stability of material. Therefore, the accurate estimation of temperature is of significance for safely storing the hydrogen. In this work, three well-known cubic equations of state (EOSs) were adopted to examine the accuracy in regenerating thermodynamic properties of hydrogen within the temperature and pressure ranges for the compressed hydrogen storage. The formulations representing molar volume, internal energy, enthalpy, and entropy were derived for Redlich-Kwong (RK), Soave-Redlioch-Kwong (SRK), and Peng-Robinson (PR) EOSs. The calculated results using the EOSs were compared with literature data given by NIST. It was revealed that the accuracies of RK and SRK EOSs were satisfactorily compatible and better than the results by PR EOS.

• Journal of Auto-vehicle Safety Association
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• v.14 no.4
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• pp.113-119
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• 2022

The structural safety of hydrogen buses is being evaluated for the successful introduction of hydrogen buses. The crash test methodology, for example, side impact test procedure is being discussed for hydrogen bus structure safety with a compressed hydrogen storage system located under the bus floor. Thus this study describes a new experiment method for side impact test with compressed hydrogen storage system independently based on finite element analysis instead of side impact test using full hydrogen bus. A side crash procedure of conceptual compressed hydrogen storage structure was investigated and impact simulations were performed. The finite element models of hydrogen bus, simplified structures, fuel tank system and side impact moving barrier were set up and simulation results reported model performance and result comparison of three different simplified models. Computational results and research discussion proposed the fundamental test framework for safety assessment of the compressed hydrogen storage system.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.607-615
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• 2022

In this study, economic analysis program was developed for economic evaluation of hydrogen production, storage/delivery, and utilization technologies as well as overseas import of hydrogen. Economic analysis program can be used for the estimation of the levelized cost of hydrogen for hydrogen supply chain technologies. This program include five hydrogen production technology on steam methane reforming and water electrolysis, two hydrogen storage technologies (high compressed gas and liquid hydrogen storage), three hydrogen delivery technologies (compressed gas delivery using tube trailer, liquid hydrogen, and pipeline transportation) and six hydrogen utilization technologies on hydrogen refueling station and stationary fuel cell system. In the case of overseas import hydrogen, it was considered to be imported from five countries (Austraila, Chile, India, Morocco, and UAE), and the transportation methods was based on liquid hydrogen, ammonia, and liquid organic hydrogen carrier. Economic analysis program that was developed in this study can be expected to utilize for planning a detailed implementation methods and hydrogen supply strategies for the hydrogen economy road map of government.

• Transactions of the Korean hydrogen and new energy society
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• v.9 no.2
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• pp.53-64
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• 1998

Thermal analysis on a Linde-Hampson hydrogen liquefaction system using cryogenic refrigerators as precooling has been carried out. Three commercially available models of cryogenic refrigerators, such as CTI l020CP, CVI CGR009 and CVI CGR011, are considered in the performance analysis. The effect of ortho-para conversion process during hydrogen liquefaction is also studied in detail. The results obtained indicate that the optimal hydrogen mass flow rate and the optimal compressed pressure exist for the maximum hydrogen liquefaction rate. The optimal compressed pressure is increased in the range of 80 - 120 bar with an increase in the hydrogen mass flow rate. It is also found that better performance could be obtained with a cryogenic refrigerator, which produces high cooling capacity at precooling temperature in the range of 80 - 100 K.

• Transactions of the Korean hydrogen and new energy society
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• v.26 no.2
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• pp.89-95
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• 2015

Pollution emission control of the 20th century, for transportation energy, are being enhanced, and then as alternative to this, because hydrogen emit only water gas emissions to be environmentally friendly energy, so hydrogen as a sustainable clean energy is in the limelight. Used in compressed natural gas engines to mix hydrogen and natural gas in both domestic and international technology development and demonstration is being carried out. The hydrogen-compressed natural gas(HCNG) charging infrastructure can be used to build a hydrogen infrastructure in the transitional aspects of a future hydrogen economy society. In this paper, for a demonstration of HCNG charging infrastructure we made and operated a $30Nm^3/h$ hydrogen generating unit and analyzed the result of the operation. We was identified the operating conditions of a reforming reactor and water gas shift reactor from an analysis result, the thermal efficiency was calculated according to the operating conditions of the total hydrogen production process.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.5
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• pp.356-364
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• 2021

During the hydrogen fueling process, hydrogen temperature inside the compressed tank were limited below 85℃ due to the allowable pressure of tank material. The chiller system to cool compressed hydrogen used R407C, greenhouse gas with a high global warming potential (GWP), as a refrigerant. To reduce greehouse gas emission, it should be replaced by refrigerant with a low GWP. This study proposes a chiller system for fueling hydrogen with R290, consisted in propane, by applying the C3 pre-cooled system use d in the LNG liquefaction process. The proposed system consisted of hydrogen compression and cooling sections and optimized the operating pressure through exergy analysis. It was also compared to the exergy efficiency with the existing system at the optimal operating pressure. The result showed that the optimal operating pressure is 700 kPa in 2-stage, 840 kPa/490 kPa in 3-stage, and the exergy efficiency increased by 17%.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.644-647
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• 2009

In this paper, the study is researched for related safety standards having experiments concerning temperature changes in type IV cylinder of the Hydrogen fuel cell vehicle. Experiments were performed to acquire temperature data of type IV cylinder according to filling time. The experimental results are shown that internal temperatures of type Ⅳ vessel are over $85^{\circ}C$ at all measured points after 5 minutes at filling 35 MPa and the highest temperature is getting lower when the residual gases are more remained. Consequently, the safety standards need properly limited value through further study for filling flow rate and filling time.

• Journal of Environmental Health Sciences
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• v.46 no.5
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• pp.555-564
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• 2020

Objectives: To identify and investigate through qualitative and quantitative analysis the hazardous substances generated when compressed wood was burned at a live fire-training center. Methods: Four types of compressed wood that are actually used in live fire training were burned in a chamber according to KS F2271. The gaseous material was sampled with a gas detector tube and conventional personal samplers. Results: 1,3-butadiene, benzene, toluene, xylene, formaldehyde, hydrogen chloride, hydrogen cyanide, ammonia, carbon monoxide, and nitric acid were detected. In particular, 1,3-butadiene (497.04-680.44 ppm), benzene (97.79-125.02 ppm), formaldehyde (1.72-13.03 ppm), hydrogen chloride (4.71-15.66 ppm), hydrogen cyanide (3.64-8.57 ppm), and sulfuric acid (3.85-5.01 ppm) exceeded the Korean Occupational Exposure Limit as measured by sampling pump according to the type of compressed wood. Conclusions: We found through the chamber testing that firefighters could be exposed to toxic substances during live fire training. Therefore, firefighter protection is needed and more research is required in the field.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.226.2-226.2
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• 2010

수소경제로 가는 길목에서의 압축천연가스에 수소를 첨가한 수소-압축천연가스(HCNG)는 자동차 연료로서의 뛰어난 효과로 인해 미국, 캐나다, 유럽 등에서는 강화되고 있는 자동차의 배출가스 규제에 대해 만족할 수 있는 차세대 천연가스 자동차의 대안으로서 관련 기술개발과 실증사업에 주력하고 있다. 향후 수소시대의 도래에 즈음하여 HCNG의 사용은 수소사용에 대한 인식 향상과 아울러 수소사용을 안정적으로 공급할 수 있는 토대를 마련하고 수소제조 등 여러 분야에서 기술개발을 할 수 있는 부가적인 효과가 있다고 하겠다. 따라서 최근 국내에서 시내버스와 청소차등에서 천연가스 차량의 보급이 확대되고 있고, 충전소도 점차 확대되고 있는 상황에서 HCNG 연료의 적용가능성을 확인하기 위한 연구가 진행되고 있다. 본 논문에서는 선진국과 국내의 기술개발 현황을 소개하고 향후 우리에게 필요한 과제가 무엇인지를 생각해보는 기회를 갖고자 하였다.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 1999.02a
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• pp.194-197
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• 1999

Thermodynamic cycle analysis has been performed to maximize the liquid amount for two hydrogen liquefaction systems using two-stage GM(Gifford-McMahon) refrigerator. the optimal operating conditions have been analytically sought with real properties of normal hydrogen for the two-stage GM direct contact system and the two-stage GM precooled L-H (Linde-Hampson) system. In the precooled system, there existed optimal values for compressed mass flow and compressed pressure to maximize the liquefied mass. It was recommended to use a cryocooler, which had a large precooling capacity between 70 and 100K.