• 제목/요약/키워드: Compound distribution

검색결과 369건 처리시간 0.03초

지리산 신갈나무와 졸참나무의 식물화학적 변이 양상 - 분류학적, 생태학적 의미 - (Phytochemical variation of Quercus mongolica Fisch. ex Ledeb. and Quercus serrata Murray (Fagaceae) in Mt. Jiri, Korea - Their taxonomical and ecological implications -)

  • 박진희
    • 한국환경생태학회지
    • /
    • 제28권5호
    • /
    • pp.574-587
    • /
    • 2014
  • 본 연구에서는 우리나라 신갈나무(Quercus mongolica Fisch. ex Ledeb.)와 졸참나무(Q. serrata Murray) 두 종의 수직분포 양상을 관찰하고, 지리산 지역을 중심으로 두 종간의 교잡이입 및 유전자 전달 가능성을 식물화학적 분석을 통해 추론하고자 하였다. 우리나라의 신갈나무와 졸참나무의 수직분포는 위도에 따라 지역 간 차이가 난다. 중부지방에서는 신갈나무가 해발 100~200m의 낮은 고도에서부터 고재대에 이르기까지 널리 분포하나 남부지방의 경우 일반적으로 해발 300m 이하 저지대에서는 거의 분포하지 않으며, 졸참나무는 중부지방의 경우 저지대에서 주로 관찰되며 해발 500~700m이상에서는 거의 발견되지 않으나 남부지방의 경우 해발 1,000m이상에서도 관찰된다. 두 종은 분포대가 달라 신갈나무는 주로 높은 해발고도에서 졸참나무는 주로 낮은 해발고도에서 생육하나, 상당한 범위의 고도 구간에서 두 종은 혼생한다. 지리산 지역을 위주로 설악산, 소백산, 마니산 등에서 채집된 신갈나무와 졸참나무의 잎 플라보노이드 성분을 분석한 결과, 2종 37개체로부터 총 23종류의 서로 다른 화합물이 분리, 동정되었다. 이들 플라보노이드 화합물은 flavonol인 kaempferol, quercetin, myricetin 및 isorhamnetin에 당이 결합된 flavonol glycoside이었으며, 4 종류의 acylated flavonoid compound가 동정되었다. 이들 중 kaempferol 3-O-glucoside, quercetin 3-O-glucoside와 quercetin 3-O-galactoside 및 이들의 acylated compounds가 주요 성분으로 두 종의 모든 개체에서 나타났다. 신갈나무의 플라보노이드 조성은 졸참나무에서는 나타나지 않는 diglycoside인 quercetin 3-O-arabinosylglucoside가 분포하며, acylated compound인 acylated kaempferol 3-O-glucoside, acylated quercetin 3-O-galactoside 및 acylated quercetin 3-O-glucoside가 다량 분포한다는 점에서 졸참나무의 flavonoid 조성과 구분된다. 졸참나무의 flavonoid 조성은 3개의 rhamnosyl flavonol compounds가 전체 졸참나무 개체에 걸쳐서 나타나며 또한 신갈나무에 비해 다량으로 나타나고, diglycoside인 kaempferol 3-O-rhamnosylglucoside를 함유하는 특징을 갖는다. 두 종 개체들의 flavonoid 조성은 고도에 따라 종내 개체 간 변이가 있었으며, 동소적으로 분포하는 두 종의 개체들은 대체로 상대 종의 플라보노이드 조성을 정량적으로 또는 정성적으로 닮는 경향이 있었다. 이러한 사실은 지리산 지역에서 두 종간에 교잡이입을 통한 유전자 교환이 일어나고 있음을 강하게 암시한다. 이와 같은 상호 교배 및 교잡이입 가능성으로 볼 때, 형태적으로 신갈나무와 졸참나무의 중간적인 특징을 나타내는 물참나무는 두 종을 부모종으로 하는 교잡에 의해 생긴 잡종분류군일 가능성이 높은 것으로 사료된다.

제주도 한림항내 표층퇴적물 중의 부틸주석화합물의 분포 (Distribution of Butyltin Compounds in Surface Sediments inside Hallim Harbor of Jeiu Island, Korea)

  • 감상규;김현정;허철구;최영찬;이민규
    • 한국환경과학회지
    • /
    • 제12권7호
    • /
    • pp.753-762
    • /
    • 2003
  • Butyltin compounds (BTs), namely tributyltin (TBT), dibutyltin (DBT) and monobutyltin (MBT), were measured in surface sediments collected in 2001 inside Hallim Harbor where a lot of shipping occurs as one of major harbors of Jeju Island, in order to evaluate their distribution. BTs were detected in surface sediments of all stations and their concentrations were comparable to those in surface sediments of other sites of domestic and foreign countries. The main species among BTs was MBT, although there was a little difference with a survey site. No correlations were obtained between organic matter or particles size of surface sediments and total BTs, indicating that these factors did not affect on the distribution of BTs. It was estimated that more complex factors including BTs loads and surrounding sedimentary environments, affected on the distribution of BTs. The high correlations between BTs indicated that DBT and MBT were mainly degraded from TBT based on antifouling paints of vessel etc. and other sources, such as DBT and MBT, could be ignored. The butyltin degradation indexes ([DBT] + [MBT]/[TBT]) Ivere in the range of 1.5∼3.3 (mean 2.5), indicating that the parent compound, TBT, were inflowed into the surface sediments a long years ago and degraded.

Ecdysteroid 화합물들의 화학구조 특성에 대한 비교연구 (A Comparative Study on the Chemicostructural Characteristics of Ecdysteroids)

  • 황갑수
    • 한국환경보건학회지
    • /
    • 제38권4호
    • /
    • pp.351-359
    • /
    • 2012
  • Objectives: This study was conducted in order to investigate the specific correlation between physicochemical properties and bioactivity in ecdysteroids found in living organisms. Methods: The examined steroidal compounds were classified into three groups according to their relevance to ecdysone activity. Each compound molecule was completely drawn to automatically calculate its physicochemical parameters and docked against 20-hydroxyecdysone to calculate the total distance. Electronic charge distribution was also observed for each molecule. All procedures were conducted using a computational chemistry program. Results: Ecdysone agonists showed different ranges of parameter values, such as log P, hydrophilic-lipophilic balance (HLB), solubility parameter (SP), hydrophilic surface (HPS), hydrogen bond (HB) and Kappa 2, when compared with antagonists and steroids without ecdysone activity. They also showed a similar electronic charge distribution that is significantly different from the electron charge distribution of antagonists and steroids without ecdysone activity. The total distance values of agonists, estimated by docking them with 20-hydroxyecdysone, were relatively small but showed no correlation with binding affinity with receptor ligand. Conclusions: These results suggest that physicochemical properties such as steric and electronic effects, hydrophobicity and hydrogen bonding may operate in combination to determine the binding activity of ecdysteroids to the receptor protein.

휘도분포영상을 이용한 공간평가분석에 관한 연구 (A Study on Analysis of Space Evaluation Using the Luminance Distribution Images)

  • 한상필;김종윤;조남철;이용규;김남진
    • 한국태양에너지학회 논문집
    • /
    • 제33권5호
    • /
    • pp.76-81
    • /
    • 2013
  • In our former study, we proposed that the AC-Model might be applied to various conditions. And we also introduced the method for daylighting that it was possible to reduce discomfort glare and to improve visual impressions as the supplementary type and blind-control type on the compound lighting. The purpose of this study was to examine the relationship between physical elements and psychological evaluation of lighting space. The study was made using an full-size space, which were equipped with various luminaries. We investigated the relationship between subjective evaluation and characteristics of light distribution and showed the high correlation between the evaluation rating and luminance distribution over whole room.

A Study on Improvement of Distribution Facility in Wholesale Agricultural Products Market

  • Gal, Won-Mo;Kwon, Ki-Tae;Lee, Woo-Sik;Choi, Eun-Mee;Kwon, Lee-Seung;Seong, Seung-Hwan;Kwon, Woo-Taeg
    • 유통과학연구
    • /
    • 제16권2호
    • /
    • pp.53-65
    • /
    • 2018
  • Purpose - The purpose of this study is to investigate the effect of gamma - irradiation on the effluent from food distribution in the large agricultural and marine products market. This study will contribute to the distribution process as well as the agricultural and fishery distribution facilities. Research design, data, and methodology - In order to reduce the odor, the smell was examined in the anaerobic digestion process by irradiating gamma rays to the wastewater of mixed food discharged from a large restaurant. An odor determination panel list was constructed to determine if the odor was present in the air dilution drainage and the odor concentration was analyzed by instrumental analysis. Results - It was confirmed that the sulfur content increased gradually from 3 months. Ammonia decreased from 33.57ppm at the initial measurement to 4.12 ppm at the end of the experiment. Methane production was highest at 100kGy when exposed to gamma rays of 0-200kGy at pH 12. In other words, it is considered that gamma irradiation doses are most effective at 100kGy and are suitable for large capacity wastewater treatment facilities in terms of economic feasibility. Conclusions - In pre-treatment of compound food wastewater, gamma irradiation is most cost effective when examined at 100kGy. The economic efficiency of the pre-treatment method by gamma irradiation is much higher than the wastewater treatment in the large-scale agricultural and marine products distribution market.

이온 窒化된 SW3코일 스프링의 疲勞擧動에 관한 硏究 (Study on the Fatigue Behavior of Ion-Nitrided SW3 Coil Spring)

  • 염영하;장성대
    • 대한기계학회논문집
    • /
    • 제7권4호
    • /
    • pp.355-360
    • /
    • 1983
  • This paper deals with fatigue behavior of ion-nitrided coil spring. It is found that fatigue limit can be significantly increased by ion-nitriding. Ion-nitribed specimen which is treated at 550.deg. C for 5 hours improves in the fatigue limit by 30 percent in comparison with that of non-nitrided specimen. On the other hand, the value of spring constant K has nothing to do with nitriding time and temperature in this experimental range. Besides fatigue behavior, the following effects are discussed such as compound layer, diffusion layer, hardness distribution and their relations.

3차원 자동 연마장치의 개발 (Development of 3 dimensional Automatic Polishing System)

  • 정윤교;김남우;문병준
    • 한국공작기계학회:학술대회논문집
    • /
    • 한국공작기계학회 2002년도 춘계학술대회 논문집
    • /
    • pp.314-318
    • /
    • 2002
  • Recently, new polishing tool which was made by magnetic intelligent compound(Magic) was invented. The distribution of abrasives in this new tool can be controlled by magnetic field. Therefore, we can make a special polishing tool which has well arranged abrasives after cooling. In this study, 3 dimensional polishing machine was developed in order to polish complicated - shaped inner surfaces of molds. The performance of developed machine was investigated by measuring the roughness of polished surface using new polishing tool.

  • PDF

ON THE ORDERING OF ASYMPTOTIC PAIRWISE NEGATIVELY DEPENDENT STRUCTURE OF STOCHASTIC PROCESSES

  • BAEK, JONG IL;KIM, SO YOUN
    • Journal of applied mathematics & informatics
    • /
    • 제35권5_6호
    • /
    • pp.543-550
    • /
    • 2017
  • In this paper, we introduced a new asymptotic pairwise negatively dependent(APND) structure of stochastic processes. We are also important to know the degree of APND-ness and to compare pairs of stochastic vectors as to their APND-ness. So, we introduced a definitions and some basic properties of APND ordering. Some preservation results of APND ordering are derived. Finally, we shown some examples and applications.

ON THE WEAKLY POSITIVE ORTHANT DEPENDENCE ORDERING

  • Baek, Jong-Il;Seok, Eun-Yang
    • Journal of applied mathematics & informatics
    • /
    • 제7권3호
    • /
    • pp.1059-1068
    • /
    • 2000
  • In this paper we introduce a new concept of weakly positive upper orthant dependence POD of hitting times of stochastic processes. This concept is weaker than the positively orthant dependent and it is closed under a certain statistical operations of W POD ordering. Examples are given to illustrate these concepts.

Development of High Performance Valve Seat Insert Materials for Gas Engines

  • Kawata, Hideaki;Maki, Kunio
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
    • /
    • pp.391-392
    • /
    • 2006
  • Sintered materials have been applied widely in Valve Seat Inserts (VSI). The amount of wear on VSIs increases when used in gas (LPG, CNG) engines because of their dry environments. In this paper, two newly developed high performance VSI materials for gas engines are introduced. These materials applied new techniques, which are both high performance hard particle and new distribution method of solid lubricant, to increase wear resistance.

  • PDF