• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2359-2362
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• 2007

MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

• JSTS:Journal of Semiconductor Technology and Science
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• 제2권3호
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• pp.205-212
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• 2002

The growth characteristics of metal-organic chemical vapor deposition (MOCVD) $Pb(Zr_xTi_{1-x})O_3 (PZT) thin films were investigated for the application of high-density ferroelectric random access memories (FRAM) devices beyond 64Mbit density. The supply control of Pb precursor plays the most critical role in order to achieve a reliable process for PZT thin film deposition. We have monitored the changes in the microstructure and electrical properties of films on increasing the Pb precursor supply into the reaction chamber. Under optimized conditions, $Ir/IrO_2/PZT(100nm)/Ir capacitor shows well-saturated hysteresis loops with a remanent polarization (Pr) of $~28{\mu}C/textrm{cm}^2$ and coercive voltage of 0.8V at 2.5V. Other issues such as step coverage, compositional uniformity and low temperature deposition was discussed in viewpoint of actual device application.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.542-546
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• 2001

Converter slag has some compositional similarities to portland cement. But it has no hydration properties due to it's quite high concentrations of FeO(20-35%), MnO(4-6.5%). So it is needed to reduce the concentrations of iron and manganese of converter slag to use as cement additives by enhancing it's hydration properties. In this study, converter slag was modified it's composition by mixing of silica, alumina and quenched BF slag and reduced in induction furnace and quenched in running water. The hydraulic properties and structures of modified and quenched converter slag are significantly changed depend on the amount and kinds of additives. The addition of alumina up to 10% and BFQ slag up to 20% by weight on converter slag was effective to enhance the hydraulic properties of modified and quenched slag. The addition of reduced and quenched converter slag up to 20% by weight in replacement of portland cement in mixing of concrete mortar were shown higher compressive strength than 100% cement concrete mortar.

• Toxicological Research
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• 제24권2호
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• pp.113-117
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• 2008

Chronic exposure to ethanol induces cumulative damage to the liver starting from fatty infiltration to cirrhosis depending on the dose and duration of exposure. The whole process leading to the development of alcoholic liver disease is very complex and the mechanisms involved are not fully understood. Among many experimental animal models, Lieber-DeCarli liquid diet provides moderate to severe pathophysiological outcome depending on the compositional changes. In the present study, we investigated the temporal changes in the early phase hepatic disease in rats fed with standard Lieber-DeCarli diet. Male Wistar rats were fed with Lieber-Decarli ethanol diet for 6 weeks and the liver samples were obtained after 2, 4 and 6 weeks. Mild fatty infiltration was observed in 2 weeks of feeding and it became evident in 4 and 6 week samples. The level of hepatic triglyceride showed a good agreement with the data obtained in the pathological analysis. Feeding mice with ethanol diet resulted in the maturation and translocation of SREBP-1 to nucleus in the liver. Western blot analysis of the pooled liver sample of control and ethanol fed animals showed a clear-cut time-dependent increase in the expression of nSREBP-1. These data provide important information for selecting proper time point in experimental intervention study in the field of drug development for alcoholic liver disease.

• Applied Microscopy
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• 제41권2호
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• pp.89-98
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• 2011

Atom Probe Tomography는 원자 수준의 분해능으로 원소의 위치 및 조성 정보를 3차원으로 제공해 주는 분석 장비이다. APT의 우수한 성능에도 불구하고 반도체 등, 저전도성 물질 분석에는 그 동안 적용이 어려웠다. 그러나 특정 시료 내 위치의 시편을 가공할 수 있는 FIB 시편 제조법과 laser펄스를 이용한 전계증발법의 개발로 APT의 분석 영역이 반도체에서 절연체까지 크게 확대 되고 있다. 본 논문에서는 최근에 적용되기 시작한 MOS-FET, GaN LED, Si-Nanowire 등 전자소자에서의 APT분석 응용사례에 대하여 살펴보았다.

• 전자공학회논문지A
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• 제29A권9호
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• pp.36-45
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• 1992

The Modified Multi-Quantum Well(MMQWAl) structures have been grown by Mental-Organic chemical Vapor Deposition(MOCVD) method and stripe type MMQW laser diodes have been investigated. In the case of GaAs/AlGaAs superlattice and quantum well growth by MOCVD, the periodicity, interface abruptess, Al compositional uniformity and layer thickness have been confirmed though the shallow angle lapping technique, double crystal x-ray diffractometry (DCXD) and photoluminescence (PL) measurement. stripe-type MMQW laser diodes have been fabricated using the process technology of photolithography, chemical etching, ohmic contact, back side removing and cleaving. As the result of the electrical and opticalmeasurement of these laser diodes, we have achieved the series resistance of $1[\Omega}~2{\Omega}$ by current-voltage measurements, the threshold current of 200-300mA by currnt-light measurements and the lasing wavelength of 8000-8400$\AA$ by lasing spectrum measurements.

• Computers and Concrete
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• 제29권 6호
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• pp.433-444
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• 2022

Concrete's compressive strength is widely studied in order to understand many qualities and the grade of the concrete mixture. Conventional civil engineering tests involve time and resources consuming laboratory operations which results in the deterioration of concrete samples. Proposing efficient non-destructive models for the prediction of concrete compressive strength will certainly yield advancements in concrete studies. In this study, the efficiency of using radial basis function neural network (RBFNN) which is not common in this field, is studied for the concrete compressive strength prediction. Complementary studies with back propagation neural network (BPNN), which is commonly used in this field, have also been carried out in order to verify the efficiency of RBFNN for compressive strength prediction. A total of 13 input parameters, including novel ones such as cement's and fly ash's compositional information, have been employed in the prediction models with RBFNN and BPNN since all these parameters are known to influence concrete strength. Three different train: test ratios were tested with both models, while different hidden neurons, epochs, and spread values were introduced to determine the optimum parameters for yielding the best prediction results. Prediction results obtained by RBFNN are observed to yield satisfactory high correlation coefficients and satisfactory low mean square error values when compared to the results in the previous studies, indicating the efficiency of the proposed model.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.51.2-51.2
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• 2015

Understanding interfacial phenomena has been one of the main research issues not only in semiconductors but only in life sciences. I have been trying to meet the atomic scale surface and interface analysis challenges from semiconductor industries and furthermore to extend the application scope to biomedical areas. Optical imaing has been most widely and successfully used for biomedical imaging but complementary ion beam imaging techniques based on mass spectrometry and ion scattering can provide more detailed molecular specific and nanoscale information In this presentation, I will review the 27 years history of medium energy ion scattering (MEIS) development at KRISS and DGIST for nanoanalysis. A electrostatic MEIS system constructed at KRISS after the FOM, Netherland design had been successfully applied for the gate oxide analysis and quantitative surface analysis. Recenlty, we developed time-of-flight (TOF) MEIS system, for the first time in the world. With TOF-MEIS, we reported quantitative compositional profiling with single atomic layer resolution for 0.5~3 nm CdSe/ZnS conjugated QDs and ultra shallow junctions and FINFET's of As implanted Si. With this new TOF-MEIS nano analysis technique, details of nano-structured materials could be measured quantitatively. Progresses in TOF-MEIS analysis in various nano & bio technology will be discussed. For last 10 years, I have been trying to develop multimodal nanobio imaging techniques for cardiovascular and brain tissues. Firstly, in atherosclerotic plaque imaging, using, coherent anti-stokes raman scattering (CARS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS) multimodal analysis showed that increased cholesterol palmitate may contribute to the formation of a necrotic core by increasing cell death. Secondly, surface plasmon resonance imaging ellipsometry (SPRIE) was developed for cell biointerface imaging of cell adhesion, migration, and infiltration dynamics for HUVEC, CASMC, and T cells. Thirdly, we developed an ambient mass spectrometric imaging system for live cells and tissues. Preliminary results on mouse brain hippocampus and hypotahlamus will be presented. In conclusions, multimodal optical and mass spectrometric imaging privides overall structural and morphological information with complementary molecular specific information, which can be a useful methodology for biomedical studies. Future challenges in optical and mass spectrometric imaging for new biomedical applications will be discussed.

• 복식문화연구
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• 제25권5호
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• pp.611-628
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• 2017

As a plan for establishing Korea's cultural identity and its competitive edge in the world market and for enhancing Korea's cultural status, creative and unique high value-added cultural products need to be developed utilizing our inherent cultural assets. Accordingly, this study focused on the development of the design of fashion cultural products that utilize the convergence of Hangeul our peculiar font style and Korea's cultural heritage, which is registered as part of UNESCO's World Heritage. A design method was devised that converges archetypal images of cultural property with the unique Hangeul font in a way that targets Korea's symbolic architectures. The symbolic architecture includes Korea's world-heritage pagoda architecture, such as Seokgatap pagoda and Dabotap pagoda at Bulguksa temple. It also included the architecture of royal palace, such as Injeongjeon hall at Changdeokgung palace. Finally, it also included the architecture of the fortress wall, such as Paldalmun gate in Hwaseong fortress. Thus, by developing cultural assets made from a convergence between architecture and the Hangeul font as a consumer-product image that has universality, the possibility of cultural products was pursued by applying color planning after an analysis that involved extracting the compositional colors of the flags of the world. This research and approach will lead to opportunities for further progress for Korea's cultural products in the global market as a results of additional recognition for their value, excellence, and universal appeal.

• 한국정보과학회논문지:소프트웨어및응용
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• 제31권2호
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• pp.235-244
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• 2004

본 논문에서는 한국어 구문 분석 및 구문 트리 표현을 위한 복합 레이블 생성 방법을 제안한다. 기존의 구문 트리 표현에서는 미리 정의된 구문 트리 레이블을 사용하여 구문 정보를 표현하였다. 본 논문에서는 이진 규칙하에서 품사태그 정보만을 이용하여 구문 레이블을 자동으로 생성하는 방법을 제시한다. 제안된 구문 레이블은 두 개의 하위 구성체의 품사정보를 적절히 구성하여 형성되며, 동시에 현 구성체의 상태 및 역할 정보를 표현할 수 있도록 고안되었다. 이와 같이 함으로써 품사태그 정보가 가지고 있는 정보를 그대로 구문 트리에 반영시킬 수 있었다. 또한, 품사 정보와 이진규칙만을 이용하여 구문 트리를 표현하기 때문에, 다양한 구문 규칙을 채택하고 있는 서로 다른 구문 분석기의 결과를 정규화 하는 데 적용할 수 있을 것이며, 일본어와 같은 다른 언어에도 쉽게 적용 가능하다. 약 31,080 문장에 대한 구문 분석의 결과, 79.30%의 정확도를 얻을 수 있었으며, 이는 제안된 구문 트리 표현 방법이 구문 분석기의 효율에도 좋은 영향을 미침을 보이는 것이다.