• Composites Research
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• 제37권3호
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• pp.186-189
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• 2024

본 연구는 나노필러가 혼합된 열가소성 탄소섬유강화 복합재료(Carbon fiber reinforced thermoplastic polymer, CFRTP)의 물성을 비교 평가하였다. Polyamide 6 (PA6) 수지에 Multi-wall carbon nano tube (MWCNT), Silicon oxide, Core shell rubber, Aramid nano fiber 등의 다양한 나노필러를 혼합한 후, 이를 기지재(Matrix)로 탄소섬유강화복합 재료(CFRP)를 제조하여 그 물성을 측정하였다. 나노필러의 종류와 혼합비율에 따라, 인장강도, 층간계면결합력 (Inter-laminar shear strength), Izod 충격 강도 등이 측정되었다. 인장 강도와 충격 강도의 경우 Core shell rubber를 혼합한 경우 가장 높은 물성을 가졌으나, 계면결합력은 silicon oxide를 1 wt.% 이하 혼합하였을 때 최적값을 가졌다.

• Bulletin of the Korean Chemical Society
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• 제32권5호
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• pp.1534-1538
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• 2011

Uniform, hollow nanosilica spheres were prepared by the chemical coating of cationic polystyrene (cPS) with tetraethylorthosilicate (TEOS), followed by calcination at 600 $^{\circ}C$ under air. cPS was synthesized by surfactant-free emulsion polymerization using 2,2'-azobis (2-methyl propionamidine) dihydrochloride as the cationic initiator, and poly(vinyl pyrrolidone) as a stabilizer. The resulting cPS spheres were 280 nm in diameter, and showed monodispersion. After coating, the hollow silica product was spherically shaped, and 330 nm in diameter, with a narrow distribution of sizes. Dispersion was uniform. Wall thickness was 25 nm, and surface area was 96.4 $m^2/g$, as determined by BET. The uniformity of the wall thickness was strongly dependent upon the cPS surface charge. The effects of TEOS and ammonia concentrations on shape, size, wall thickness, and surface roughness of hollow $SiO_2$ spheres were investigated. We observed that the wall thicknesses of hollow $SiO_2$ spheres increased and that silica size was simultaneously enhanced with increases in TEOS concentrations. When ammonia concentrations were increased, the irregularity of rough surfaces and aggregation of spherical particles were more severe because higher concentrations of ammonia result in faster hydrolysis and condensation of TEOS. These changes caused the silica to grow faster, resulting in hollow $SiO_2$ spheres with irregular, rough surfaces.

• 한국강구조학회 논문집
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• 제20권2호
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• pp.289-301
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• 2008

이중강판합성벽은 타이바로 연결된 강판외피 사이에 콘크리트를 충전시킨 구조벽으로서, 벽체의 구조성능을 향상시키고, 벽체의 두께를 줄이며, 별도의 거푸집 및 배근 공사없이 시공성을 향상시키기 위하여 개발되었다. 본 연구에서는 주기하중을 받는 이중강판합성벽의 비탄성거동특성 및 내진성능을 평가하기 위하여, 직사각형 및 T형 단면형상을 갖는 단일벽 및 병렬벽 실험체에 대하여 실험 연구를 수행하였다. 실험 결과, 이중강판합성벽은 주기하중에 대하여 핀칭이 없이 우수한 에너지소산능력을 나타냈다. 벽체하단부 기초의 접합상세와 단면형상에 따라 파괴모드 및 변형능력의 차이를 보였으며, 주로 벽체기초 또는 연결보 용접부의 파단과 강판국부좌굴에 의하여 파괴되었다. 적절한 용접 및 보강 상세를 갖는 실험체들은 2.0~3.7% 층간변형각의 변형능력을 보였다. 또한 벽체와 연결보의 비탄성강도를 고려하여 단일벽 및 병렬벽 실험체의 하중재하능력을 평가하였으며, 이를 실험결과와 비교하였다.

• Steel and Composite Structures
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• 제7권4호
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• pp.279-301
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• 2007

When coupling beams are proportioned appropriately in coupled core wall (CCW) systems, the input energy from ground motions is dissipated primarily through inelastic deformations in plastic hinge regions at the ends of the coupling beams. It is desirable that the plastic hinges form at the beam ends while the base wall piers remain elastic. The strength and stiffness of the coupling beams are, therefore, crucial if the desired global behavior of the CCW system is to be achieved. This paper presents the results of nonlinear response history analysis of two 20-story CCW buildings. Both buildings have the same geometric dimensions, and the components of the buildings are designed based on the equivalent lateral force procedure. However, one building is fitted with steel coupling beams while the other is fitted with diagonally reinforced concrete coupling beams. The force-deflection relationships of both beams are based on experimental data, while the moment-curvature and axial load-moment relationships of the wall piers are analytically generated from cross-sectional fiber analyses. Using the aforementioned beam and wall properties, nonlinear response history analyses are performed. Superiority of the steel coupling beams is demonstrated through detailed evaluations of local and global responses computed for a number of recorded and artificially generated ground motions.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2009년도 학술논문요약집
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• pp.84-85
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• 2009

New approaches for detecting, preventing and remedying environmental damage are important for protection of the environment. Procedures must be developed and implemented to reduce the amount of waste produced in chemical processes, to detect the presence and/or concentration of contaminants and decontaminate fouled environments. Contamination can be classified into three general types: airborne, surface and structural. The most dangerous type is airborne contamination, because of the opportunity for inhalation and ingestion. The second most dangerous type is surface contamination. Surface contamination can be transferred to workers by casual contact and if disturbed can easily be made airborne. The decontamination of the surface in the nuclear facilities has been widely studied with particular emphasis on small and large surfaces. The amount of wastes being produced during decommissioning of nuclear facilities is much higher than the total wastes cumulated during operation. And, the process of decommissioning has a strong possibility of personal's exposure and emission to environment of the radioactive contaminants, requiring through monitoring and estimation of radiation and radioactivity. So, it is important to monitor the radioactive contamination level of the nuclear facilities for the determination of the decontamination method, the establishment of the decommissioning planning, and the worker's safety. But it is very difficult to measure the surface contamination of the floor and wall in the highly contaminated facilities. In this study, the poly(styrene-ethyl acrylate) [poly(St-EA)] core-shell composite polymer for measurement of the radioactive contamination was synthesized by the method of emulsion polymerization. The morphology of the poly(St-EA) composite emulsion particle was core-shell structure, with polystyrene (PS)as the core and poly(ethyl acrylate) (PEA) as the shell. Core-shell polymers of styrene (St)/ethyl acrylate (EA) pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl sulfate (SOS) as an emulsifier using ammonium persulfate (APS) as an initiator. The polymer was made by impregnating organic scintillators, 2,5-diphenyloxazole (PPO) and 1,4-bis[5-phenyl-2-oxazol]benzene (POPOP). Related tests and analysis confirmed the success in synthesis of composite polymer. The products are characterized by IT-IR spectroscopy, TGA that were used, respectively, to show the structure, the thermal stability of the prepared polymer. Two-phase particles with a core-shell structure were obtained in experiments where the estimated glass transition temperature and the morphologies of emulsion particles. Radiation pollution level the detection about under using examined the beta rays. The morphology of the poly(St-EA) composite polymer synthesized by the method of emulsion polymerization was a core-shell structure, as shown in Fig. 1. Core-shell materials consist of a core structural domain covered by a shell domain. Clearly, the entire surface of PS core was covered by PEA. The inner region was a PS core and the outer region was a PEA shell. The particle size distribution showed similar in the range 350-360 nm.

• Advances in concrete construction
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• 제9권5호
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• pp.459-467
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• 2020

Mechanical and thermal properties of composite sandwich wall panels are affected by changes in their external environment. Humidity and temperature changes induce stress on wall panels and their core connectors. Under the action of ambient temperature, temperature on the outer layer of the wall panel changes greatly, while that on the inner layer only changes slightly. As a result, stress concentration exists at the intersection of the connector and the wall blade. In this paper, temperature field and stress field distribution of UHPC-RW-RC (Ultra-High Performance Concrete - Rock Wool - Reinforced Concrete) wall panel under high temperature-sprinkling and heating-freezing conditions were investigated by using the general finite element software ABAQUS. Additionally, design of the connection between the wall panel and the main structure is proposed. Findings may serve as a scientific reference for design of high performance composite sandwich wall panels.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2014년도 추계 학술논문 발표대회
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• pp.175-176
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• 2014

Recently, in the apartment house of our country, office building, apartment, and etc, the lightweight composite panel is much used as the partition wall body. This is due to be very convenient when the execution and dismantling is convenient and it forms the space which the consumer in the space desires. Therefore, in this research, the thermal conductivity property of the lightweight composite panel core according to the replacement ratio variation of the pearlite tries to be analyze. As the density test result and replacement ratio of the pearlite increased, the density showed the tendency to rise. the replacement ratio of the pearlite increased, the absorption rate showed the tendency to fall. And this is determined that absorption rate is degraded due to the increase in the density. the thermal conductivity test result and pearlite replacement ratio increased, the tendency that the thermal conductivity increases was represented.

• 한국구조물진단유지관리공학회 논문집
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• 제21권1호
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• pp.74-82
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• 2017

본 연구에서는 시멘트 복합체의 균열을 자기치유 할 수 있는 자기치유 캡슐을 제조하기 위한 일환의 기초 연구로써 자기치유 캡슐용 코어재료에 무기계 기반 코어재료를 적용하기 위하여 액상형태의 무기 소재를 기반으로한 코어재료를 제조하였다. 제조된 무기계 기반 코어재료는 캡슐화를 진행하기 전에 무기계 기반 코어재료를 직접 시멘트 복합체에 적용하여 균열부의 균열수복 성능뿐만 아니라 시멘트 복합체의 성능에 미치는 영향을 검토하였다. 평가결과, 무기계 기반 코어재료는 압축 및 부착강도 향상효과가 있는 것을 확인하였으며, 부착, 내흡수, 내투수 및 동결융해 저항 성능을 가진 것으로 판단된다. 본 논문의 결과를 통하여 자기치유 캡슐용 무기계 기반 코어재료를 적용할 경우에 얻을 수 있는 시멘트 복합체의 성능 및 차후 진보화된 자기치유 캡슐기술의 기반 자료로써 활용하고자 한다.

• 대한기계학회논문집A
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• 제34권1호
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• pp.55-60
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• 2010

틸팅형 고속열차의 차체에 적용되는 하니컴 복합재 조인트 구조물의 경우 운행중 외팔보형 굽힘하중을 받게된다. 하이브리드 복합재 조인트 구조물에 대한 굽힘시험평가를 수행하기 위해 실제 틸팅열차 차체 구조물에서 조인트부를 절단 채취하여 시험편으로 제작하였다. 굽힘시험결과 시험편의 파괴거동은 정적하중과 피로하중하에서 확연히 달라짐을 보였다. 정적굽힘하중 하에서는 하니컴 코어 영역에서 전단변형과 파괴가 발생하였으며, 피로굽힘하중 하에서는 복합재 표피층과 하니컴 코어층 사이에서 계면분리가 발생하거나, 또는 금속재 언더프레임과의 용접부에서 파괴가 발생하였다. 이러한 파괴거동은 다른 산업분야에서 사용되는 유사한 구조의 하니컴 복합재 조인트 구조물에서도 발생할 수 있기 때문에, 본 실험 결과를 하니컴 복합재 조인트 구조물의 설계변수를 개선하기 위해 이용될 수 있다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2015년도 춘계 학술논문 발표대회
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• pp.152-153
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• 2015

Recently, solar energy generation is one of the fastest growing industries for eco-friendly energy. Every year, solar energy generation industry grows to 42% on average. However, polysilicon sludge is generated from processing of polysilicon but, there is nothing to handle that. Therefore, we need research to recycle polysilicon sludge. Also, improved fire resistance efficiency of wall is required according to reinforced fire safety standards due to many cases of big fires in our country. This study focuses on density and strength properties according to the addition ratio of paper Ash for the lightweight composite panel core with polysilicon sludge. As a result of the test, adding paper ash 9% has the best density and strength properties.