• Title/Summary/Keyword: Composite cluster

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Thick Film Type duster in Mg2SiO4/Glass composite ceramics for Anion Generation (Mg2SiO4/Glass Composite계 세라믹스를 이용한 음이온 발생용 후막형 클러스터)

  • Yeo, Dong-Hun;Shin, Hyo-Soon;Hong, Youn-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.2
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    • pp.118-123
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    • 2010
  • The eco-friendly technologies have been extended as matter of international concern due to various diseases and syndromes according to an environmental pollution. In this study, we have manufactured a ceramic cluster with thick film type for anion generation equipment which is maximized anion but minimized ozone contents generated. To develop the formulation of ceramic cluster, we conducted the $Mg_2SiO_4$ powders doped with 10 vol% glass frits as Na-Zn-B-O system and sintered at $1050^{\circ}C$ for 2 hours in air for starting materials and investigated the matching properties between the Ag-Pd electrode and the starting materials. The sintered sample for the composition of cluster has 6.7 of dielectric constant and 32 kV/mm of withstand voltage. The yield of anions was measured according to an electrode pattering, discharge gap between electrode, and thickness of electrode protective layer in the cluster of thick film type. We have manufactured the ceramic clusters with optimized thick film structure that have an anion over a hundred particles and the ozone of 0.6 ppb generated.

Combining cluster analysis and neural networks for the classification problem

  • Kim, Kyungsup;Han, Ingoo
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 1996.10a
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    • pp.31-34
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    • 1996
  • The extensive researches have compared the performance of neural networks(NN) with those of various statistical techniques for the classification problem. The empirical results of these comparative studies have indicated that the neural networks often outperform the traditional statistical techniques. Moreover, there are some efforts that try to combine various classification methods, especially multivariate discriminant analysis with neural networks. While these efforts improve the performance, there exists a problem violating robust assumptions of multivariate discriminant analysis that are multivariate normality of the independent variables and equality of variance-covariance matrices in each of the groups. On the contrary, cluster analysis alleviates this assumption like neural networks. We propose a new approach to classification problems by combining the cluster analysis with neural networks. The resulting predictions of the composite model are more accurate than each individual technique.

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Construction and Characterization of Poly (Phenylene Oxide)-Based Organic/Inorganic Composite Membranes Containing Graphene Oxide for the Development of an Anion Exchange Membrane with Extended Ion Cluster (확장된 이온 클러스터를 갖는 음이온 교환막 개발을 위한 그래핀 옥사이드를 함유한 폴리(페닐렌 옥사이드) 기반 유·무기 복합막의 제조 및 특성분석)

  • CHU, JI YOUNG;YOO, DONG JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.524-533
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    • 2021
  • In this study, a series of anion conductive organic/inorganic composite membranes with excellent ionic conductivity and chemical stability were prepared by introducing graphene oxide (GO) inorganic nanofiller into the quaternized poly(phenylen oxide (Q-PPO) polymer matrix. The fabricated organic/inorganic composite membranes showed higher ionic conductivity than the pristine membrane. In particular, Q-PPO/GO 0.7 showed the highest ionic conductivity value of 143.2 mS/cm at 90℃, which was 1.56 times higher than the pristine membrane Q-PPO (91.5 mS/cm). In addition, the organic/inorganic composite membrane showed superior dimensional stability and alkaline stability compared to the pristine membrane, and the physicochemical stability was improved as the content of inorganic fillers increased. Therefore, we suggest that the as-prepared organic/inorganic composite membranes are very promising materials for anion exchange membrane applications with high conductivity and alkaline stability.

Preparation and Characterization of Nafion Composite Membranes Containing 1-ethyl-3-methylimidazolium Tetracyanoborate

  • Shin, Mun-Sik;Park, Jin-Soo
    • Journal of the Korean Electrochemical Society
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    • v.15 no.1
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    • pp.35-40
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    • 2012
  • The composite membranes using Nafion as matrix and 1-ethyl-3-methylimidazolium tetracyanoborate (EMITCB) as ion-conducting medium in replacement of water were prepared and characterized. The amount of EMITCB in Nafion varied from 30 to 50wt%. The composite membranes are characterized by ion conductivity, thermogravitational analyses (TGA) and small-angle X-ray scattering (SAXS). The composite membranes containing EMITCB of 40wt% showed the maximum ionic conductivity which was ~0.0146 S $cm^{-1}$ at 423.15 K. It is inferred that the decrease in ionic conductivity of all the composite membranes might be due to the decomposition of a tetracyanoboric acid formed in the composite membranes. The results of SAXS indicated that the ionic clusters to conduct proton in the composite membranes were successfully formed. In accordance with the results of ionic conductivity as a function of a reciprocal temperature, SAXS showed a proportional decrease in scattering maximum $q_{max}$ as the amount of EMITCB increases in the composite membranes, which results in the increase in ionomer cluster size. The TGA showed no significant decomposition of the ionic liquid as well as the composite membranes in the range of operating temperature ($120-150^{\circ}C$) of high temperature proton exchange membrane fuel cells (HTPEMFC). As a result, EMITCB is able to play an important role in transferring proton in the composite membranes at elevated temperatures with no external humidification for proton exchange membrane fuel cells.

Characterization of the Ceramic Reinforced AC4C Matrix Composites Processed by Squeeze Casting (용탕단조법으로 제조된 AC4C 합금기 세라믹강화 복합재료의 특성연구)

  • Kim, Eok-Soo
    • Journal of Korea Foundry Society
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    • v.25 no.2
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    • pp.88-94
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    • 2005
  • The microstructure and mechanical property of the ceramic reinforced AC4C matrix composites processed by squeeze casting were investigated. In this study Kaowool and Saffil fiber which are ceramic reinforcements are used as preform materials. As a matrix material, Al-7wt.%Si-0.3wt.%Mg(AC4C) has been used. In case of Kaowool and Saffil/AC4C composites, 7.5 MPa squeezing pressure and minimum 7.0% binder amount are needed to produce sound composite materials. The tensile strength of Kaowool/ AC4C composite is lower than the matrix metal and this can be explained by the melt unfilling due to formed cluster of Kaowool reinforcements. But the mechanical properties of hardness, wear resistance and thermal expansion are better than the matrix materials due to the strengthening effect of ceramic reinforcements.

INFLUENCE OF CONSTANT HEAT SOURCE/SINK ON NON-DARCIAN-BENARD DOUBLE DIFFUSIVE MARANGONI CONVECTION IN A COMPOSITE LAYER SYSTEM

  • MANJUNATHA, N.;SUMITHRA, R.;VANISHREE, R.K.
    • Journal of applied mathematics & informatics
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    • v.40 no.1_2
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    • pp.99-115
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    • 2022
  • The problem of Benard double diffusive Marangoni convection is investigated in a horizontally infinite composite layer system consisting of a two component fluid layer above a porous layer saturated with the same fluid, using Darcy-Brinkman model with constant heat sources/sink in both the layers. The lower boundary of the porous region is rigid and upper boundary of the fluid region is free with Marangoni effects. The system of ordinary differential equations obtained after normal mode analysis is solved in closed form for the eigenvalue, thermal Marangoni number for two types of thermal boundary combinations, Type (I) Adiabatic-Adiabatic and Type (II) Adiabatic -Isothermal. The corresponding two thermal Marangoni numbers are obtained and the essence of the different parameters on non-Darcy-Benard double diffusive Marangoni convection are investigated in detail.

Gas Separation Membranes Containing $Re_6Se_8(MeCN)_6^{2+}$ Cluster-Supported Cobalt-Porphyrin Complexes

  • Park Su Mi;Won Jongok;Lee Myung-Jin;Kang Yong Soo;Kim Se-Hye;Kim Youngmee;Kim Sung-Jin
    • Macromolecular Research
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    • v.12 no.6
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    • pp.598-603
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    • 2004
  • Cellulose nitrate (CN) composite membranes, containing cobalt porphyrin (CoP) complexes self-assembled within nanometer-sized rhenium clusters (ReCoP), have been prepared and their oxygen and nitrogen gas perme­abilities were analyzed. The solubility of ReCoP and the characteristics of the corresponding composite membranes were analyzed using a Cahn microbalance, FT-IR spectroscopy, wide-angle X-ray scattering, and differential scanning calorimetry. The nitrogen permeability through the CN composite membranes decreased upon addition of ReCoP and CoP, which implies that the presence of these oxygen carrier complexes affects the structure of the polymer matrix. The oxygen permeability through the composite membranes containing small quantities of ReCoP decreased, but it increased upon increasing the concentration. The oxygen gas transport was affected by the matrix at low ReCoP concentrations, but higher concentrations of ReCoP increased the oxygen permeability as a result of its reversible and specific interactions with oxygen, effectively realizing ReCoP carrier-mediated oxygen transport.

Strengthening Mechanism of Hybrid Short Fiber/Particle Reinforced Metal Matrix Composites (섬유/입자 혼합 금속복합재료의 강화기구 해석)

  • 정성욱;이종해;정창규;송정일;한경섭
    • Composites Research
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    • v.13 no.1
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    • pp.50-60
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    • 2000
  • This paper presents an analytical method considering tensile strength enhancement in hybrid $Al_2O_3$ fiber/particle/aluminum composites(MMCs). The tensile strength and elastic modulus of the hybrid MMCs are even 20% higher than those of the fiber reinforced MMCs with same volume fraction of reinforcements. This phenomenon is explained by the cluster model which is newly proposed in this research, and the strengthening mechanisms by a cluster is analyzed using simple modified rule of mixtures. From the analysis, it is observed that cluster structure in hybrid MMCs increase the fiber efficiency factor for the tensile strength and the orientation factor for the elastic modulus. The present theory is then compared with experimental results which was performed using squeeze infiltrated hybrid MMCs made of hybrid $Al_2O_3$ short fiber/particle preform and AC8A alloy as base metal, and the agreement is found to be satisfactory.

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Multivariate Analysis of Water Quality Data at 14 Stations in the Geum-River Watershed (금강유역 14개 관측점의 수질자료를 이용한 수질의 다변량분석)

  • 임창수
    • Journal of Environmental Science International
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    • v.8 no.3
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    • pp.331-336
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    • 1999
  • The monthly water quality data measured at 14 stations located in the Geum-River watershed were clustered into 2 to 7 clusters. Furthermore, factor analyses were conducted on Gabcheon and Yugucheon to characterize the water qualtiy, based on the information obtained from the results of culster analysis. The results of cluster analysis show that the water quality charactersitic of main stream of the Geum-River is somewhat different from that of substream of the Geum-River. Furthermore, the water quality characteristic of Gabcheon which is expected to have the most serious water quality problems in the Geum-River watershed shows the most different water quality characteristic from Yugucheon. Based ont he factor loadings in each factor, Gabcheon and Yugucheon have their own water quality characteristics. This is mainly because of composite factors such as different population density, industrial activities, and land use conditions in Gabcheon and Yugucheon subwatersheds.

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Excellent properties of Indium Tin Oxide-Carbon Nano tube Nano composites at low temperatures by Nano Cluster Deposition technique

  • Pammi, S.V.N.;Park, Jong-Hyun;Chanda, Anupama;Park, Yeon-Woong;Ahn, Jun-Ku;Yoon, Soon-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.7-7
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    • 2010
  • Indium tin oxide (ITO) - SWNT nano crystalline composites was synthesized at low temperature(${\sim}250^{\circ}C$)using Nano Cluster Deposition technique by Metal Orhoganic Chemical Vapor Deposition method. XRD patterns of ITO- SWNT composite shows pure cubic phases without any secondary phase. I-V measurement gives resistance of 12 ohms for Sn doped (3 wt %) indium oxide-SWNT composites. The electrical conductivity of the nano composites is significantly enhanced compared to the SWNT.

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