• Title/Summary/Keyword: Composite Mineral

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Preparation of graphene-$TiO_2$ composite by aerosol process and it's characterization for dye-sensitized solar cell (에어로졸 공정에 의한 Graphene-$TiO_2$ 복합체 제조 및 염료감응 태양전지 특성평가)

  • Jo, Eun Hee;Kim, Sun Kyung;Jang, Hee Dong;Chang, Hankwon;Roh, Ki-Min;Kim, Tae-Oh
    • Particle and aerosol research
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    • v.9 no.2
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    • pp.51-57
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    • 2013
  • A graphene(GR)-$TiO_2$ composite was synthesized from colloidal mixture of graphene oxide(GO) nanosheets and $TiO_2$ nanoparticles by an aerosol assisted self-assembly. The morphology, specific surface area and pore size of asprepared GR-$TiO_2$ composite were characterized by FE-SEM, BET, and BJH respectively. The shape of GR-$TiO_2$ composite was spherical. The average particle size was 0.5-1 ${\mu}m$ in diameter and the pore diameter ranged 20-50 nm. Photovoltaic characteristics of a mixture of the GR-$TiO_2$ and $TiO_2$ nanoparticles were measured by a solar simulator under simulated solar light. The highest photoelectric conversion efficiency of the mixture photoanode was 5.1%, which was higher than that of $TiO_2$ photoanode.

Sliding Wear and Friction Properties of Composite Materials for Friction Bushing (Friction Bushing용 복합재료의 미끄럼 마찰마모특성에 관한 연구)

  • Lee Han-Young;Heo Dae-Hong;Kim Tae-Jun;Cho Yong-Jae;Cho Bum-Rae;Hur Man-Dae
    • Tribology and Lubricants
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    • v.22 no.1
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    • pp.1-7
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    • 2006
  • The sliding friction and wear properties of mineral fiber reinforced composite(MF) and glass fiber reinforced composites(GF) are investigated to clarify their field of use and the role of each fiber in friction material. Friction and wear test reveals that GF composite has better wear resistance even though with low friction coefficient, comparing with MF composite. Glass fiber strengthen effectively the matrix and may absorb friction energy to convert it into the fracture energy of them, as well as its lubricative role. However, mineral fiber in MF composite is too small to strengthen the matrix. Then MF composite are easily plowed and worn out by asperity on counter material. Friction coefficient of MF composite is higher friction coefficient than that of GF composite and varied widely with test.

Synthesis of Multiwall Carbon Nanotube/Graphene Composite by Aerosol Process and Its Characterization for Supercapacitors (에어로졸 공정에 의한 Multiwall carbon nanotube/Graphene 복합체 제조 및 슈퍼커패시터 특성평가)

  • Jo, Eun Hee;Kim, Sun Kyung;Chang, Hankwon;Lee, Chong Min;Park, Su-Ryeon;Choi, Ji-hyuk;Jang, Hee Dong
    • Particle and aerosol research
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    • v.12 no.4
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    • pp.127-134
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    • 2016
  • A multiwall carbon nanotube (MWCNT)/graphene (GR) composite was synthesized for an enhanced supercapacitor. Aerosol spray pyrolysis (ASP) was employed to synthesize the MWCNT/GR composites using a colloidal mixture of MWCNT and graphene oxide (GO). The effect of the weight ratio of the MWCNT/GO on the particle properties including the morphology and layered structure were investigated. The morphology of MWCNT/GR composites was generally the shape of a crumpled paper ball, and the average composite size was about $5{\mu}m$. MWCNT were uniformly dispersed in GR sheets and the MWCNT not only increase the basal spacing but also bridge the defects for electron transfer between GR sheets. Thus, it was increasing electrolyte/electrode contact area and facilitating transportation of electrolyte ion and electron in the electrode. Electrochemical data demonstrate that the MWCNT/GR (weight ratio=0.1) composite possesses a specific capacitance of 192 F/g at 0.1 A/g and good rate capability (88% capacity retention at 4 A/g) using two-electrode testing system.

New Produce Development Strategies : The Case of the Advanced Mineral Aggregate Composite Industry (석재복합 신제품 개발전략 탐색)

  • Kim, Jai-Myung
    • Korean Business Review
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    • v.11
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    • pp.173-194
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    • 1998
  • This study suggests the theoretical framework and strategy of new product development in the advanced mineral aggregate composite industry. The advanced mineral aggregate composite area needs to prepare the plan and guidelines on the new product development owing to the characteristic of the related technology. Alternative scenarios on the hierachy of new product idea is effective to the success of new product development strategy. Especially, the existing market, product, and the technological advantages affects the possibility of the success of new product development of the small firms. Also considering the interrelationship between the technological trends is important to the new product development of advanced mineral aggregate composite industry.

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Synthesis of Ag-Cu Composite Powders for Electronic Materials by Electroless Plating Method (무전해 도금법을 이용한 전자소재용 은-구리 복합분말의 제조)

  • Yoon, C.H.;Ahn, J.G.;Kim, D.J.;Sohn, J.S.;Park, J.S.;Ahn, Y.G.
    • Journal of Powder Materials
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    • v.15 no.3
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    • pp.221-226
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    • 2008
  • Silver coated copper composite powders were prepared by electroless plating method by controlling the activation and deposition process variables such as feeding rate of silver ions solution, concentration of reductant and molar ratio of activation solution $(NH_4OH/(NH_4)_2SO_4)$ at room temperature. The characteristics of the product were verified by using a scanning electron microscopy (SEM), X-ray diffraction (XRD) and atomic absorption (A.A.). It is noted that completely cleansing the copper oxide layers and protecting the copper particles surface from hydrolysis were important to obtain high quality Ag-Cu composite powders. The optimum conditions of Ag-Cu composite powder synthesis were $NH_4OH/(NH_4)_2SO_4$ molar ratio 4, concentration of reductant 15g/l and feeding rate of silver ions solution 2 ml/min.

Biodegradable Starch-Based Resin Reinforced with Continuous Mineral Fibres-Processing, Characterisation and Mechanical Properties

  • Wittek, Thomas;Tanimoto, Toshio
    • Advanced Composite Materials
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    • v.18 no.2
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    • pp.167-185
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    • 2009
  • Environmental problems caused by extensive use of polymeric materials arise mainly due to lack of landfill space and depletion of finite natural resources of fossil raw materials like petroleum or natural gas. The substitution of synthetic petroleum-based resins with natural biodegradable resins appears to be one appropriate measure to remedy the above-mentioned situation. This study presents the development of a composite that uses environmentally degradable starch-based resin as matrix and natural mineral basalt fibres as reinforcement, and investigates the fibre's and the composite's mechanical properties. The tensile strength of single basalt fibres was verified by means of single fibre tensile tests and statistically investigated by means of a Weibull analysis. Prepreg sheets were manufactured by means of a modified doctor blade system and hot power press. The sheets were used to manufacture specimens with fibre volume contents ranging from 33% to 61%. Specimens were tested for tensile strength, flexural strength and interlaminar shear strength. Composites manufactured during this study exhibited tensile and flexural strength of up to 517 MPa and 157 MPa, respectively.

Preparation of Graphene-Palladium Composite by Aerosol Process and It's Characterization for Glucose Biosensor (에어로졸 공정에 의한 그래핀-팔라듐 복합체 제조 및 글루코스 바이오센서 특성평가)

  • Kim, Sun Kyung;Jang, Hee Dong;Chang, Hankwon;Choi, Jeong-Woo
    • Particle and aerosol research
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    • v.10 no.2
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    • pp.53-59
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    • 2014
  • Palladium (Pd) nanoparticles attached graphene (GR) composite was synthesized for an enhanced glucose biosensor. Aerosol spray pyrolysis (ASP) was employed to synthesize the GR-Pd composite using a colloidal mixture of graphene oxide (GO) and palladium chloride ($PdCl_2$) precursor. The effects of the weight ratio of the Pd/GR on the particle properties including the morphology and crystal structure were investigated. The morphology of GR-Pd composites was generally the shape of a crumpled paper ball, and the average composite size was about $1{\mu}m$. Pd nanoparticles less than 20 nm in diameter were deposited on GR sheets and the Pd nanoparticles showed clear crystallinity. The characteristic of the glucose biosensor fabricated with the as-prepared GR-Pd composite was tested through cyclic voltammetry measurements. The biosensor exhibited a high current flow as well as clear redox peaks, which resulted in a superior ability of the catalyst in terms of an electrochemical reaction. The highest sensitivity obtained from the amperometric response of the glucose biosensor was $14.4{\mu}A/mM{\cdot}cm^2$.

Paper Properties Improvement by adding Microfibrillated Cellulose-Mineral Composites (Microfibrillated Cellulose (MFC)와 중질탄산칼슘 (GCC)로 구성된 복합충전제를 이용한 종이 물성 향상)

  • Lee, Jung Myoung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.83-90
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    • 2016
  • Increasing the amount of filler in paper is of high interest for paper industry while maintaining its key sheet quality properties. In this study, a MFC-GCC composite, made through a co-grinding NBSK (Northern bleached softwood kraft) pulp with a ground calcium carbonate (Intracarb 60), was used as a strength aid in paper in order to evaluate a potential cost reduction through filler increase without sacrificing paper quality. Hand-sheets were made of NBSK and/or eucalyptus pulp by using white water recirculation in a Tappi sheet former and was compared its properties without or with MFC additions at different filler levels. It was found that the MFC-GCC composite has a large surface area compared to the fiber, allowing the formation of more hydrogen bonds in the web, thus giving natural strength to the paper. Overall results are encouraging that the MFC-GCC composite allows papermaker to reduce basis weight and maintain critical sheet properties.

Modeling of sulfate ionic diffusion in porous cement based composites: effect of capillary size change

  • Gospodinov, Peter N.
    • Computers and Concrete
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    • v.4 no.2
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    • pp.157-166
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    • 2007
  • The paper considers a theoretical model to study sulfate ion diffusion in saturated porous media - cement based mineral composites, accounting for simultaneous effects, such as filling micro-capillaries (pores) with ions and chemical products and liquid push out of them. Pore volume change and its effect on the distribution of ion concentration within the specimen are investigated. Relations for the distribution of the capillary relative radius and volume within the composite under consideration are found. The numerical algorithm used is further completed to consider capillary size change and the effects accompanying sulfate ion diffusion. Ion distribution within the cross section and volume of specimens fabricated from mineral composites is numerically studied, accounting for the change of material capillary size and volume. Characteristic cases of 2D and 3D diffusion are analyzed. The results found can be used to both assess the sulfate corrosion in saturated systems and predict changes occurring in the pore structure of the composite as a result of sulfate ion diffusion.