• Title/Summary/Keyword: Composite Effect

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Effect of Fluoride Recharging on Fluoride Release and Surface Properties of Orthodontic Bracket Adhesives (불소 적용 후 교정용 브라켓 접착제 종류에 따른 불소 재흡수성과 표면 변화에 관한 연구)

  • Byeon, Seon Mi
    • Journal of dental hygiene science
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    • v.18 no.4
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    • pp.218-226
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    • 2018
  • The aim of this study was to compare fluoride release and surface changes according to different orthodontic bracket adhesives the application of fluoride products. We used non-fluoridated composite resin Transbond fluoridated composite resins Blugloo and LightBond, resin-modified glass ionomer Rely $X^{TM}$ Luting 2, and conventional glass ionomer Fuji $I^{(R)}$. Fluoride release of five orthodontic bracket adhesives and fluoride release ability after application of three fluoride products (1.23% acidulated phosphate fluoride gel, Tooth Mousse $Plus^{(R)}$, Fluor Protector, and a toothbrush with sodium fluoride-containing toothpaste) were measured using a fluoride electrode that was connected to an ion analyzer. After 4 weeks of fluoride application, the surface roughness and surface morphology were examined using a surface roughness tester and field emission scanning electron microscopy. The amounts of fluoride release were observed not only on application of Tooth Mousse $Plus^{(R)}$ and Fluor Protector on resin-modified glass ionomer Rely $X^{TM}$ Luting 2 and Fuji $I^{(R)}$, but also during tooth brushing using fluoride-containing toothpaste. After application of Tooth Mousse $Plus^{(R)}$, except Transbond XT, the surface roughness increased, and all orthodontic adhesives showed a partial drop of micro-particle filler. On application of 1.23% acidulated phosphate fluoride gel on all orthodontic bracket adhesives, their surface roughness increased. To bond the orthodontic bracket, resin-modified glass ionomer Rely $X^{TM}$ Luting 2 and Fuji $I^{(R)}$ adhesives are highly recommended if the amount of fluoride release is considered to confer a preventative effect on dental caries, and among the fluoride products, Tooth Mousse $Plus^{(R)}$ and Fluor Protector are better than 1.23% acidulated phosphate fluoride gel, and these are expected to prevent dental caries even during tooth brushing with fluoride-containing toothpaste.

The Preparation of Non-aqueous Supercapacitors with LiMn2O4/C Composite Positive Electrodes (LiMn2O4/C 복합 양극을 이용한 비수계 슈퍼커패시터의 제조)

  • Kim, Kyoungho;Yoo, Jeeyoung;Kim, Minsoo;Yeu, Taewhan
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.178-182
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    • 2007
  • Non-aqueous supercapacitors by using activated C and $LiMn_2O_4$ as an active material in a positive electrode were prepared and characterized. From the cyclic voltammetry and AC impedance analysis, the capacitive effect by electric double layer of activated carbon and the faradic effect by intercalation/deintercalation of $Li^+$ ion were observed. Increasing the ratio of $LiMn_2O_4$, specific capacitances and energy densities of supercapacitor were increased. At the ratio of 0.86:0.14 ($LiMn_2O_4:C$), the maximum specific capacitance of 17.51 Wh/L and energy density of 23.83 F/cc were obtained, which were more than twice of those for a conventional electric double layer capacitor. Even after 1,000 charge/discharge cycle, the supercapacitor by using the electrode containing 14% of activated carbon and 86% of $LiMn_2O_4$ showed 60% better specific capacitance and energy density than that by using the electrode containing 100% activated carbon.

Effect of Compatibilizers on the Mechanical Properties of Waste Polypropylene/Waste Ground Rubber Tire Composites (상용화제의 첨가에 따른 재생 폴리프로필렌/폐타이어 분말 복합체의 기계적 특성 분석)

  • Park, Ki-Hun;Kim, Dong-Hak;Jung, Jong-Ki;Kim, Seong-Gil;Bang, Daesuk;Oh, Myung-Hoon;Kim, Bong-Suk
    • Resources Recycling
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    • v.23 no.1
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    • pp.70-79
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    • 2014
  • In this study, waste polypropylene and waste ground rubber tire(WGRT) composites were prepared by using a modular intermeshing co-rotating twin screw extruder. The effect of three main factors such as WGRT contents, particle size, compatibilizers on the properties of waste PP/WGRT composites was extensively investigated. Tensile strength of the composites was decreased with an increase in WGRT contents, whereas elongation at break and impact strength were increased. The tensile strength, elongation at break and impact strength of the composites with the smaller size of the WGRT were more enhanced. Addition of PP-g-MA into waste PP/WGRT composites exhibited better tensile strength. However, elongation at break and impact strength were slightly decreased with increasing of PP-g-MA. On the other hand, tensile strength, impact strength and elongation at break of the composites were increased by adding the EPDM-g-MA and SEBS-g-MA. Especially, elongation at break was significantly increased compared to the composite with PP-g-MA.

An Improved Bond Slip Model of CFT Columns for Nonlinear Finite Element Analysis (CFT 기둥의 비선형 유한요소해석을 위한 개선된 강관-콘크리트 간 부착 모델 개발)

  • Kwon, Yangsu;Kwak, Hyo-Gyoung;Hwang, Ju-Young;Kim, Jin-Kook;Kim, Jong-Min
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.28 no.2
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    • pp.213-220
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    • 2015
  • CFT column has a lot of structural advantages due to the composite behavior between in-filled concrete and steel tube. This paper deals with the development of an effective numerical model which can consider the bond-slip behavior between both components of concrete matrix and steel tube without taking double nodes. Since the applied axial load to in-filled concrete matrix is delivered to steel tube by the confinement effect and the friction, the governing equation related to the slip behavior can be constructed on the basis of the force equilibrium and the compatability conditions. In advance, the force and displacement relations between adjacent two nodes make it possible to express the slip behavior with the concrete nodes only. This model results in significant savings in the numerical modeling of CFT columns to take into account the effect of bond-slip. Finally, correlation studies between numerical results and experimental data are conducted to verifying the efficiency of the introduced numerical model.

Gross Profitability Premium in the Korean Stock Market and Its Implication for the Fund Distribution Industry (한국 주식시장에서 총수익성 프리미엄에 관한 분석 및 펀드 유통산업에 주는 시사점)

  • Yoon, Bo-Hyun;Liu, Won-Suk
    • Journal of Distribution Science
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    • v.13 no.9
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    • pp.37-45
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    • 2015
  • Purpose - This paper's aim is to investigate whether or not gross profitability explains the cross-sectional variation of the stock returns in the Korean stock market. Gross profitability is an alternative profitability measure proposed by Novy-Marx in 2013 to predict cross-sectional variation of stock returns in the US. He shows that the gross profitability adds explanatory power to the Fama-French 3 factor model. Interestingly, gross profitability is negatively correlated with the book-to-market ratio. By confirming the gross profitability premium in the Korean stock market, we may provide some implications regarding the well-known value premium. In addition, our empirical results may provide opportunities for the fund distribution industry to promote brand new styles of funds. Research design, data, and methodology - For our empirical analysis, we collect monthly market prices of all the companies listed on the Korea Composite Stock Price Index (KOSPI) of the Korea Exchanges (KRX). Our sample period covers July1994 to December2014. The data from the company financial statementsare provided by the financial information company WISEfn. First, using Fama-Macbeth cross-sectional regression, we investigate the relation between gross profitability and stock return performance. For robustness in analyzing the performance of the gross profitability strategy, we consider value weighted portfolio returns as well as equally weighted portfolio returns. Next, using Fama-French 3 factor models, we examine whether or not the gross profitability strategy generates excess returns when firmsize and the book-to-market ratio are controlled. Finally, we analyze the effect of firm size and the book-to-market ratio on the gross profitability strategy. Results - First, through the Fama-MacBeth cross-sectional regression, we show that gross profitability has almost the same explanatory power as the book-to-market ratio in explaining the cross-sectional variation of the Korean stock market. Second, we find evidence that gross profitability is a statistically significant variable for explaining cross-sectional stock returns when the size and the value effect are controlled. Third, we show that gross profitability, which is positively correlated with stock returns and firm size, is negatively correlated with the book-to-market ratio. From the perspective of portfolio management, our results imply that since the gross profitability strategy is a distinctive growth strategy, value strategies can be improved by hedging with the gross profitability strategy. Conclusions - Our empirical results confirm the existence of a gross profitability premium in the Korean stock market. From the perspective of the fund distribution industry, the gross profitability portfolio is worthy of attention. Since the value strategy portfolio returns are negatively correlated with the gross profitability strategy portfolio returns, by mixing both portfolios, investors could be better off without additional risk. However, the profitable firms are dissimilar from the value firms (high book-to-market ratio firms); therefore, an alternative factor model including gross profitability may help us understand the economic implications of the well-known anomalies such as value premium, momentum, and low volatility. We reserve these topics for future research.

Field Applicability Evaluation Using Effective Microorganism Brewing Cycle for Contaminated Soil in Water Retention Basin (복합발효미생물을 이용한 하천유수지 오염토의 현장적용성 평가)

  • Shin, Eunchul;Jung, Minkyo;Kim, Kyeongsig;Kang, Jeongku
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.11
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    • pp.35-43
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    • 2016
  • In this study, by using a Effective Microorganisms Brewing Cycle, it confirmed the purification effect of pollutants that are adsorbed on the basins stench removal and retarding soil. On the basis of on-site application test, a soil decontamination system will be suggested. Using a Effective Microorganisms Brewing Cycle, the odor concentration is reduced 2.5 times than that of natural purification treatment method. It was measured and found that the quality of the pore water discharged from the soil is improved. In addition, it was found that a composite of copper and lead with the fermentation microorganisms adsorbed on soil particles from the surface of the stirred experiments lagoon mixed soil is reduced to 65% and 66%, respectively, The TPH organic component was confirmed that the reduction effect of 85%. Restoration of reservoir contaminated soils using the effective microorganism brewing cycle needs to be more developed and implemented as a long-term purification system. This study may be a good reference of developing more complete microorganism brewing system which will efficiently reduce the odor and soil contamination based on optimal stirring and mixing ratio of the compound solutions and contaminated soils in reservoir.

Sensitivity Measurement of the Piezoelectric Paint Sensor according to the Poling Electric Field (분극 전계에 따른 압전 페인트 센서 감도 측정)

  • Han, Dae-Hyun;Park, Seung-Bok;Kang, Lae-Hyong
    • Composites Research
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    • v.27 no.4
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    • pp.146-151
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    • 2014
  • In this study, the experimental study has been performed by varying the polarization of the electric field and impact force to check the piezoelectric characteristics of piezoelectric paint sensor. Piezoelectric paint sensor used in this study is composed of epoxy resin with a hardener and PNN-PZT powder in 1:1 weight ratio. The dimensions of the paint sensor specimen are $40{\times}40{\times}1mm^3$ and regular specimens were made using a mold. The voids are removed from the specimen in the vacuum desiccator. Both upper side and bottom side of the paint sensor were coated with silver paste for making an electrode and then dried at room temperature for a day. The poling treatment has been carried out under controlled conditions of the electric field in order to check the effect of piezoelectric sensitivities, while the poling temperature was fixed at room temperature and the poling time was set to 30 min. The piezoelectric sensitivities have been measured by comparing output voltage from paint sensor with output force from impact hammer when the impact hammer hits the paint sensor. In result, the effect of the electric field has been evaluated for the sensitivity and describe the result.

Effect of Seed Coating Layer on the Microstructure of NaA Zeolite Separation Layer Grown on ${\alpha}$-alumina Support (종결정 코팅층이 다공성 ${\alpha}$-알루미나 지지체 표면에 성장되는 NaA 제올라이트 분리층의 미세구조에 미치는 영향)

  • Kim, Min-Ji;Sharma, Pankaj;Han, Moon-Hee;Cho, Churl-Hee
    • Membrane Journal
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    • v.24 no.5
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    • pp.375-385
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    • 2014
  • NaA zeolite/${\alpha}$-alumina composite membranes were hydrothermally synthesized at $100^{\circ}C$ for 24 hr by using nanosize seed of 100 nm in diameter and an ${\alpha}$-alumina support of $0.1{\mu}m$ in pore diameter, and then effect of seed coating layer on the microstructure of NaA zeolite separation layer was systematically investigated. In cases when nanosize seed was coated with a monolayer, increment in seed coverage induced small grained and thick NaA zeolite separation layer. On the other hand, in case when nanosize seed was coated with a multilayer, much small grained and thick separation layer was formed. It was clear that an uniform monolayer seed coating is required to grow hydrothermally a thin and defect-free NaA zeolite separation layer. In the present study, it was clearly announced that seed coating layer is a key factor to determine the microstructure of NaA zeolite layer, secondary grown on a porous support.

EFFECT OF COLLAGEN DISSOLUTION IN ACID CONDITIONED DENTIN ON RESIN-DENTIN HYBRID LAYER (산표면처리 후 노출된 상아질 교원섬유의 용해가 하이브리드층 형성에 미치는 영향)

  • Jeon, Seong-Min;Son, Ho-Hyun;Lee, Kwang-Won
    • Restorative Dentistry and Endodontics
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    • v.21 no.1
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    • pp.227-241
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    • 1996
  • The effect of collagen dissolution in acid conditioned dentin was morphologically examined by both scanning and transmission electron microscopy. 18 freshly extracted human molars and dentin bonding systems of All Bond 2, Scotchbond Multipurpose, Superbond D-Liner were used in this study. For SEM preparation, each 3 of ~ exposed dentin surfaces were acid conditioned by using various acids within the above three bonding systems respectively. After acid conditioning of the other 3 exposed dentin surfaces as above, they were treated with 1.7% NaOCl for 2 minutes. The remaining 3 dentin surfaces were acid conditioned and treated with 3.3 % NaOCl for 2 minutes. All of the specimens were then fixed in 4 % glutaraldehyde for 12 h at $4^{\circ}C$ and dehydrated in ethanols grades from 50 % to 100 %, then surface changes of the specimens were observed by using SEM. For TEM preparation, exposed dentin surfaces were acid conditioned with the same acid as SEM specimens and treated with 1.7%, 3.3 % NaOCl respectively, then applied with corresponding bonding agents. After the procedures were finished, composite resin were applied on the dentin surfaces and light cured. Small, rectangular sticks with end dimensions of approximately 1 by 1 mm were sectioned and further sample preparative techniques for transmission electron microscopy were performed in accordance with the procedures used for ultrastructural TEM observations of calcified tissues. The results were as follows : 1. In the 1.7 % NaOCl retreated specimens after acid conditioning, the porous dentin surface of intertubular dentin and wide opening of dentinal tubules were appeared. And there were fine irregularities on the intertubular dentin, indicating a clear difference as compared with the acid conditioned specimens. 2. In the 3.3% NaOCl retreated specimens after acid conditioning, the intertubular dentin was further eroded causing a more porous and wider opening of dentinal tubules. Moreover, sharp irregularities on the intertubular dentin were more evident than those of acid conditioned and 1.7% NaOCl retreated specimens. 3. In all of the acid conditioned specimens, the resin-dentin hybrid layer of approximately 3.5mm thickness was formed and the collapsed collagen layer was observed on the uppermost part of hybrid layer in the specimens applied with All Bond 2. The collgen fibrils of intertubular dentin in specimens applied with Scotchbond Multipurpose were running perpendicular to the interface, and electron dense black layer demarcated from the deep unaltered dentin was more evident in the specimen applied with Superbond D-Liner than any other specimens. 4. In the 1.7 % NaOCl retreated specimens after acid conditioning, the resin-dentin hybrid layer of approximately 2.5-3.0mm thickness was formed and the collapsed collagen layer and longitudinally running collagen fibrils as shown in the acid conditioned specimens were observed in the specimens applied with All Bond 2 and Superbond D-Liner. 5. In all of the 3.3% NaOCl retreated specimens after acid conditioning, the evidence of resin-dentin hybrid layer was not identified ; nevertheless, the longitudinally running collagen fibrils remained slightly in the specimens applied with All Bond 2.

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EFFECT OF THERMOCYCLING ON BONDING OF COMPOSITE RESIN AFTER DENTIN SURFACE TREATMENTS (상아질 표면처리후 복합레진 수복시 온도변화가 결합에 미치는 영향)

  • Lee, Yong-Woo;Son, Ho-Hyun
    • Restorative Dentistry and Endodontics
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    • v.16 no.2
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    • pp.126-142
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    • 1991
  • The purpose of this study was to evaluate the effect of various dentin surface treatments on shear bond strength, microhardness and fracture mode before and after thermocycling. Recently extracted 75 human molars were used. The teeth were sagittal sectioned faciolingually to obtain 150 specimens. They were randomly divided into six groups. Mesial and distal dentinal surfaces of specimens were exposed by grinding and treated respectively with GC-DENTIN CONDITIONER. 10-3 solution of 4-Meta, Cleansar and Primer of GLUMA, Scotchprep of Scotchbond 2, DENTIN CONDITIONER and PRIMER A, B of ALL BOND according to the manufacturers directions. Specimens of one group were not treated. Adhesive agent of Scotchbond 2, were applied and cured on the treated dentin surfaces. After P-50 were cured on them, specimens were stored in 31c water for 24 hours before shear bond strength measurement Shear bond strength was measured in 10 specimens of each group. 10 specimens of each group were thermocycled in $20^{\circ}C$, $60^{\circ}C$,$20^{\circ}C$, $4^{\circ}C$, $20^{\circ}C$ water in order, for 30 seconds respectively, 100 times a day for 7 days. After thermocycling shear bond strength was measured. Microhardness was checked on treated dentin surface and fractured dentin surface in 10 specimens respectievly. Francture modes were observed with SEM The following results were obtained. 1. Before thermocycling. shear bond strengths in the specimens treated with DENTIN CONDITIONER and PRIMER A, B of ALL BOND were significantly higher than those in other specimens(P<0.01). 2. After thermocycling. shear bond strengths in the specimens treated with Cleanser and Primer of GLUMA, Scotchprep of Scotchbond 2 and DENTIN CONDITIONER and PRIMER A, B of AIL BOND were significantly higher than those in specimens not: treated, treated with GC-DENTIN CONDITIONER and 10-3 solution of 4-Meta(P<0.01). Shear bond strengths in the specimens treated with GC-DENTIN CONDITIONER and PRIMER A, B of ALL BOND were significantly higher than those in other specimens except those treated with Scotchprep of Srotchbond 2(P<0.01). 3. Shear bond strengths after thermocycling were reduced in the specimens not treated, treated with GC-DENTIN CONDITIONER and 10-3 solution of 4-Meta and were increased in the specimens treated with Cleanser and Primer of GLUMA, Scotchprep of Scotchbond 2, without significance, compared with those before thermocycling. In the specimens treated with DENTIN CONDITIONER and PRIMER A, B of ALL BOND, shear bond strengths after thermocycling were significantly increased, compared with those before thermocycling(P<0.01). 4. Microhardnesses in the fractured surfaces after shear bond strength measurement were significantly increased in the specimens treated with 10-3 solution of 4-Meta and significantly decreased in the specimens treated with DENTIN CONDITIONER and PRIMER A, B of ALL BOND, compared with those in the treated dentin surfaces(P<0.01). 5. In the specimens treated with Cleanser and Primer of GLUMA, Scotchprep of Scotchbond 2 and DENTIN CONDITIONER and PRIMER A, B of ALL BOND, cohesive fracture modes were observed more than adhesive fracture modes.

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