• Title/Summary/Keyword: Complex structure

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Crystal Structures and Characterization of Copper(II) Complexes of N,N,N'N'-Tetrakis(2-pyridylmethyl)-1,2-ethanediamine

  • Yoon, Doo-Cheon;Lee, Uk;Oh, Chang-Eon
    • Bulletin of the Korean Chemical Society
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    • v.25 no.6
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    • pp.796-800
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    • 2004
  • The structure of [Cu(tpen)]$(ClO_4)_2$ (tpen = N,N,N',N'-tetrakis(2-pyridylmethyl)-1,2-ethanediamine) has been identified by X-ray crystallography. The copper(II) ion is surrounded by two amine N atoms and three pyridine N atoms of the ligand, making a distorted trigonal-bipyramid. Among the six potential N donor atoms (two amine N and four pyridine N atoms), only one pyridine N atom remains uncoordinated. We examined structural changes on addition of $Cl^-$ to $[Cu(tpen)]^{2+}$(1). The addition of $Cl^-$ in methanol resulted in the formation of a novel dinuclear copper(II) complex $[Cu_2Cl_2(tpen)](ClO_4)_2{\cdot}H_2O$. The structure of the dinuclear complex was verified by X-ray crystallography. Each copper(II) ion in the dinuclear complex showed a distorted square planar geometry with two pyridine N atoms, one amine N atom and one $Cl^-$ ion.

On the Fuzzy Approach to Integrated Evaluation of Complex Systems (퍼지 평가의 통합특성에 관하여)

  • 이철영;임봉택
    • Journal of Korean Port Research
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    • v.13 no.1
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    • pp.79-86
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    • 1999
  • This paper deals with the evaluation problem of complex systems by introducing a fuzzy approach. The authors are functionally supposing a hierarchical structure model of a complex system and give light on the following problems. First for the purpose of clarifying the characteristics of measures the property and differences between two method such as linear and fuzzy viewpoint are discussed through two level-down evaluation process. Second the integrated evaluation process which keeps reversibility between hierarchical levels is discussed and obtained some necessary conditions for reversibility of fuzzy evaluation. From these results it is expected that the fuzzy approach overcomes partly the limitation of reductionism at the hierarchical evaluation of complex systems.

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HOLOMORPHIC FUNCTIONS ON ALMOST COMPLEX MANIFOLDS

  • Han, Chong-Kyu;Kim, Hye-Seon
    • Journal of the Korean Mathematical Society
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    • v.49 no.2
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    • pp.379-394
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    • 2012
  • Given an almost complex structure ($\mathbb^{C}^m$, J), $m\geq2$, that is defined by setting $\theta^{\alpha}=dz^{\alpha}+a_{\beta}^{\alpha}d\bar{z}^{\beta}$, ${\alpha}=1,\ldots$,m, to be (1, 0)-forms, we find conditions on ($a_{\beta}^{\alpha}$) for the existence of holomorphic functions an classify the almost complex structures by type ($\nu$,q). Then we determine types for several examples in $\mathbb{C}^2$ and $\mathbb{C}^3$ including the natural almost complex structure on $S^6$.

An Establishment the Work Breakdown Structure for Owners in the Multi-Complex Project (입체·복합 프로젝트에서 발주자 중심의 WBS 구축방향)

  • Ko, Dae-Jun;Choi, Eun-A;Seo, Young-Chil;Lee, Sang-Beom
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.05a
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    • pp.127-131
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    • 2008
  • The successful project management is based on definition of project goals in construction industry. The WBS(Work Breakdown Structure) is one of the major factors which defines works related to project goals. The necessity of the WBS for owners in multi complex projects which would help them to understand the whole project is rising because the multi-complex project in the construction industry has increasing recently. Therefore, this study suggests directions to establish the WBS for owners through investigating a concept of the multi-complex project first and analyzing types of project, domestic and foreign WBS, and case studies.

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Dynamic analysis for complex structures using the improved component mode method (개선된 콤포넌트 모드법을 이용한 거대구조물의 동적해석)

  • 심재수;박명균
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1993.04a
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    • pp.37-44
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    • 1993
  • There are a lot of linear dynamic analysis methods for complex structures. Each method has advantages and shortcomings. Method of dynamic analysis for complex structure is selected considering characteristics of dynamic loading, computer facility available number of degree of freedem and accuracy of results. It is a main point of view to get economical results rather then accurate ones for analysis of general complex structures, Mode superposition method and direct integration method are generally used. However, the characteristics of load is not considered in mode superpositon method, the personal computer cannot be used in direct integration methods. To over-come these shortcomings, the component mode method incorporating Ritz algorithm updated is proposed to solve economically dynamic behavior of the structures. The purpose of study is a formulation of algorithm, and computer programing suitable for dynamic analysis of the complex structure in personal computer environment.

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Template Synthesis, Crystal Structure, and Magnetic Properties of a Dinuclear Copper(II) Complex with Cooperative Hydrogen Bonding

  • Kang, Shin-Geol;Nam, Kwang-Hee;Min, Kil-Sik;Lee, Uk
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.1037-1040
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    • 2011
  • The dinuclear complex 1 with cooperative hydrogen bonds can be prepared by the metal-directed reaction of Eq. (2). This work shows that the coordinated hydroxyl group trans to the secondary amino group is deprotonated more readily than that trans to the tertiary amino group and acts as the hydrogen-bond accepter. The lattice water molecules in 1 act as bridges between the two mononuclear units through hydrogen bonds. The complex is quite stable as the dimeric form even in various polar solvents. The complex exhibits a weak antiferromagnetic interaction between the metal ions in spite of relatively long Cu$\cdots$Cu distance. This strongly supports the suggestion that the antiferromagnetic behavior is closely related to the cooperative hydrogen bonds.

Adaptive fluid-structure interaction simulation of large-scale complex liquid containment with two-phase flow

  • Park, Sung-Woo;Cho, Jin-Rae
    • Structural Engineering and Mechanics
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    • v.41 no.4
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    • pp.559-573
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    • 2012
  • An adaptive modeling and simulation technique is introduced for the effective and reliable fluid-structure interaction analysis using MSC/Dytran for large-scale complex pressurized liquid containment. The proposed method is composed of a series of the global rigid sloshing analysis and the locally detailed fluid-structure analysis. The critical time at which the system exhibits the severe liquid sloshing response is sought through the former analysis, while the fluid-structure interaction in the local region of interest at the critical time is analyzed by the latter analysis. Differing from the global coarse model, the local fine model considers not only the complex geometry and flexibility of structure but the effect of internal pressure. The locally detailed FSI problem is solved in terms of multi-material volume fractions and the flow and pressure fields obtained by the global analysis at the critical time are specified as the initial conditions. An in-house program for mapping the global analysis results onto the fine-scale local FSI model is developed. The validity and effectiveness of the proposed method are verified through an illustrative numerical experiment.

Contemporary Characteristics of Fashion-textile Design Applying Paisley Ornament (페이즐리 오너먼트를 활용한 패션텍스타일 디자인의 현대적 특징 연구)

  • Chung, Ha Jeong;Park, Juhee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.44 no.5
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    • pp.950-968
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    • 2020
  • This study derives the modern characteristics of the paisley ornament through an analysis of the paisley ornament shown in fashion since the 2010s based on a theoretical review of the paisley ornament used in Kashmir India shawls for artistic inspiration in the fashion-textile field. It classified the paisley ornament in fashion since the 2010s into types of 'basic structure of body and coif', 'abnormal paisley ornament shapes', 'complex structure of paisley ornament', 'complex structure with other motif', 'a pair of symmetrical reflection motif', 'regular of repetitive arrangement', 'complex arrangement of irregularity and regularity' and 'free arrangement of irregularity'. A comparative analysis with the historical paisley ornament shows that paisley ornaments have contemporary characteristics like 'Bisector structure of centerline in criterion of the body', 'Composite structure of extended 1-repeat', and 'Free structure of engineered placement'. A modern design was inspired by the historical art forms; however, it was used in free utilization of motifs and patterns in terms of size, direction, proportion and space. These were the expression of a design identity that originated from the aesthetic ability and career of a designer as well as the technology of computer programs for the improvements in time and cost efficiency.

Comparative Analysis of T4SS Molecular Architectures

  • Mishghan Zehra;Jiwon Heo;Jeong Min Chung;Clarissa L Durie
    • Journal of Microbiology and Biotechnology
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    • v.33 no.12
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    • pp.1543-1551
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    • 2023
  • The recently published high-resolution R388 T4SS structure provides exciting new details about the complete complex of T4SS, including the components making up the stalk and arches, numerous symmetry mismatches between regions of the complex, and an intriguing interpretation of the closed stalk and radial symmetry of the inner membrane complex, which is related to pilus biogenesis assembly. However, there are a few unidentified densities in the electron microscopy map and portions of the identified component sequences for which the structure is not yet known. It is also unclear how well this minimized DNA-transporting T4SS predicts the structure of other T4SSs, such as expanded systems and those that transport proteins rather than DNA. In this review, we evaluate what can be inferred from the recent high-resolution structure of the R388 T4SS with respect to the Cag and Dot/Icm systems. These systems were selected because, given what is currently known about these systems, we expect them to present most structural differences compared to the R388 T4SS structure. Furthermore, we discuss bacterial physiology and diversity, the T4SS structures and their variations between different bacterial species. These insights may prove beneficial for researchers who elucidate the structure and functions of T4SS in different bacterial species.

Humidity Effect on the Characteristics of the Proton Conductor Based on the BaR0.5+xTa0.5-xO3-δ (R=Rare Earth) System (BaR0.5+xTa0.5-xO3-δ (R=희토류 금속)계 Proton 전도체 특성에 미치는 수분의 영향)

  • Choi, Soon-Mok;Seo, Won-Sun;Jeong, Seong-Min;Kim, Shin;Lee, Hong-Lim
    • Journal of the Korean Ceramic Society
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    • v.45 no.5
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    • pp.290-296
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    • 2008
  • $AB'_{0.5}B"_{0.5}O_3$ type complex perovskite structures which have been reported as proton conductors over $600^{\circ}C$ were studied. The $AB'_{0.5}B"_{0.5}O_3$ type complex perovskite structure is known to be more easily synthesized and has better stability than normal $ABO_3$ perovskite structure. And it is stable at about $800^{\circ}C$ in the $CO_2$ atmosphere, whereas the $BaCeO_3$ perovskite is easily decomposed into carbonate. In addition, this $AB'_{0.5}B"_{0.5}O_3$ type complex perovskite structure could simply produce oxygen vacancies within their structure not by introducing additional doping oxides but by just controling the molar ratio of $B'^{+3}$ and $B"^{+5}$ metal ions in the B site. Hence it is easy to design the structure which shows highly sensitive electrical conductivity to humidity. In this study, the single phase boundary of $BaR_{0.5+x}Ta_{0.5-x}O_{3-{\delta}}$(R = rare earth) complex perovskite structures and it's phase stability were investigated with changes in composition, x. And the humidity dependance of electrical conductivity at different $P_{H2O}$ conditions was investigated.