• 제목/요약/키워드: Complex permeability

검색결과 228건 처리시간 0.02초

Modification of Nafion Membranes for Reduction of Methanol Transport Rate

  • Kang, Dong-Hoon;Kim, Duk-Joon
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.127-128
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    • 2006
  • Nafion/basic polymer composite membranes were prepared to reduce the methanol crossover for the application of direct methanol fuel cell. The thermal and mechanical properties increased with increasing basic polymer contents due to the formation of complex via acid/basic interaction. The water uptake, proton conductivity, methanol permeability decreased with increasing basic polymer concentration by reduction of acidity associated with the formation of acid/base complex. The molecular effect on those properties was not considerable.

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Performance evaluation of binary blends of Portland cement and fly ash with complex admixture for durable concrete structures

  • Yang, Dingyi;Sun, Wei;Tan, Yongquan
    • Computers and Concrete
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    • 제2권5호
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    • pp.381-388
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    • 2005
  • This paper presents the results of a study on binary blends of Portland cement and fly ash with complex admixture used for the concrete structures to meet specific performance objectives in east coastal area of China. The concretes were evaluated for workability, strength, water permeability, drying shrinkage, sulfate resistance and electrical resistance. Environmental Scanning Electron Microscopy (ESEM) was used to examine the microstructure of concrete made by complex admixture compared with control batches without complex admixture. The combined efforts of fly ash and complex admixture led to an improvement in the workability, strength and durability.

초고주파 유전체공진기의 복소유전율 측정 (Microwave Measurement of Complex Permittivity of Dielectric Resonators)

  • 김정필;박위상
    • 대한전자공학회논문지
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    • 제27권11호
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    • pp.9-19
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    • 1990
  • 원통형 및 환형 유전체공진기의 복소유전율과 투자율을 측정하기 위한 이론적인 해석과 측정방법을 제시하였다. 두 개의 평면도체 사이에 유전체공진기를 놓고 공진주파수와 무부하 Q, 그리고 치수를 측정하면 복소유전율과 투자율을 구할 수 있으며 이 방법을 고차모우드에 대하여 반복적으로 행하면 더 넓은 주파수 범위에서 측정이 가능하다. 이 때 각각의 공진모우드는 유전체공진기의 방위각과 축방향에 대한 전계 세기의 변화를 측정함으로써 결정할 수 있다. 그리고 여러가지 오차의 요인들을 고려한 측정오차의 해석으로부터 $TE_{0np}$ 또는 quasi-TE 모우드를 측정에 이용할 경우 복소유전율의 실수부분은 $0.5{\%}$, 허수부분은 $4{\%}$ 이내의 측정오차를 가짐이 밝혀졌다.

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[ $Ag^+$ ]-Chitosan Complex Membranes for Propylene/Propane Separation

  • Kim, Jeong-Hoon;Lee, Soo-Bok;Feng, Xianshe
    • Korean Membrane Journal
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    • 제8권1호
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    • pp.36-42
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    • 2006
  • We have prepared new water-swollen chitosan-$Ag^+$ complex membranes and studied their permeation and separation behavior for propylene and propane gases. The $Ag^+$ containing chitosan complex membranes were prepared from chitosan and $AgNO_3$ aqueous solution. The $AgNO_3$ and water content in the membrane were controlled by adjusting $AgNO_3$ concentration of casting solution. The permeation properties of propylene and propane were investigated as a function of $AgNO_3$ concentration, and various operation conditions. High permeability of above 17 barrer and high selectivity of above 170 could be obtained with the membranes prepared from 3 M $AgNO_3$ aqueous solution. Periodic regeneration test confirmed these membranes could be very useful for the separation of propylene/propane and other olefin/paraffin separation.

FeSiCr에 Fe50Ni가 첨가된 폴리머 복합 시트의 전자파 흡수 특성 (Electromagnetic Wave Absorbing Properties of FeSiCr and Fe50Ni Flaky Powder-Polymer Composite Sheet)

  • 이석문;김상문
    • 한국전기전자재료학회논문지
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    • 제27권7호
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    • pp.462-467
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    • 2014
  • In this paper, we studied the magnetic composite sheets for electromagnetic wave noise absorber of quasi-microwave band by using soft magnetic FeSiCr and Fe50Ni flakes with the thickness of about $1{\mu}m$ and polymer. The magnetic hysteresis curve including saturation magnetization and residual magnetization and the complex permeability characteristics of the composite sheets were investigated to clarify the mixing effect on electromagnetic wave absorption properties. The saturation magnetization was decreased about 10% while the residual magnetization was increased about 15% and the real parts of complex permeability at below 500 MHz were increased 0.6~4 while those values at above 500 MHz were decreased 0.4~2.5 according to the change of contents of FeSiCr and Fe50Ni powders. As a result, the reflection loss can be moved to the lower frequency from 2~3 GHz to 1~1.5 GHz as the contents of Fe50Ni flaky powder into FeSiCr flaky powder was increased up to 50%.

NiCuZn 페라이트의 제조 조건에 따른 전자파흡수 특성에 관한 연구 (A Study on the Electromagnetic Wave Absorption Properties by the Preparing Condition of NiCuZn Ferrite)

  • 이영구;박찬규;이문수
    • 한국전자파학회:학술대회논문집
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    • 한국전자파학회 2001년도 종합학술발표회 논문집 Vol.11 No.1
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    • pp.304-309
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    • 2001
  • With the development of electromagnetic communication technology and increased use of electromagnetic wave, the countermeasure of EMI(Electromagnetic Interference) becomes more important socially, and interest for the electromagnetic wave absorber has also increased. In this paper, we have studied characteristics of frequency dependency on complex permittivity and complex permeability according to the changes of composition rate and sintering temperature of NiCuZn ferrite also known as electromagnetic wave absorber and further looked into effect of electromagnetic wave absorption properties. From the measurement where the composition of Fe$_2$O$_3$ and ZnO of NiCuZn ferrite was fixed at 49 and 34 mol% respectively while composition of NiO and CuO has been varied at each test, we found out that initial permeability and permittivity were high and the absorbing ability of electromagnetic wave recorded best with loss tangent(${\mu}$r"/${\mu}$r′) displays more than 1 within the frequency band of 2MHz~9.5MHz when the composition ratio of NiO was ranged around 8.5~9.5 mol% and the sintering temperature was 1,080$^{\circ}C$.

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변성 셀룰로오즈 막내의 물의 상태 (The State of Water in Modified Cellulose Membranes)

  • 이순홍;이영무;김진일;김재진
    • 공업화학
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    • 제4권1호
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    • pp.125-131
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    • 1993
  • 두 종류의 변성 셀룰로오즈 막내의 물의 상태를 시차열분석계를 이용하여 분석하였다. 셀룰로오즈막들은 카르복시메틸 셀룰로오즈(CMC)-젤라틴 고분자전해질 복합체막과 아크릴산 가교 메틸셀룰로오즈(MC)전해질막이다. 동결수(자유수)와 비동결수(결합수) 양을 측정하여서 막을 통한 용질들의 투과도와의 관계를 조사하였다. 막내의 물의 상태는 막의 조성, 모폴로지, 그리고 수화도의 영향을 받는 것을 알았다. 수화된 막들을 통한 확산 투과도의 차이를 자유수와 결합수의 차이로 설명하였다.

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