• Title/Summary/Keyword: Complex behavior

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Precipitation and Precipitate Coarsening Behavior According to Nb Addition in the Weld HAZ of a Ti-containing Steel (Nb의 첨가에 따른 Ti 첨가 저합금강 용접열영향부에서의 석출물 거동 변화)

  • Moon, Joon-Oh;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.26 no.1
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    • pp.76-82
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    • 2008
  • The effect of Nb addition on the precipitation and precipitate coarsening behavior was investigated in Ti and Ti + Nb steel weld HAZ. A dilatometer equipped with a He-quenching system was used to simulate the weld thermal cycle. Compared to $TiC_yN_{1-y}$ precipitate in a Ti containing steel, $Ti_xNb_{1-x}C_yN_{1-y}$ complex particle with addition of Nb is precipitated in a Ti + Nb containing steel. Meanwhile, precipitate coarsening occurred more easily in Ti + Nb steel, which may be because the high temperature stability of $Ti_xNb_{1-x}C_yN_{1-y}$ complex particle is deteriorated by the Nb addition.

Molecular Modeling of Complexation Behavior of p-tert-Butylcalix[5]arene Derivative toward Butylammonium Ions

  • Choe, Jong-In;Chang, Suk-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.23 no.1
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    • pp.48-52
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    • 2002
  • Using several molecular modeling programs we have performed computer simulations to investigate the complexation behaviors of an ester derivative of p-tert-butylcalix[5]arene (1e) toward a variety of butylammonium ions. Semi-empirical AM1 method was used for calculating the binding energies and the formation enthalpies. MM and CVFF forcefields for molecular mechanics calculations were adapted to express the complexation energies of the host. Molecular dynamics were performed to the calculated complex systems to simulate the ionophoric behavior of the host-guest complexes. The absolute Gibbs free energies of the host (1e) complexed with four kinds of butylammonium ions have been calculated using the Finite Difference Thermodynamic Integration (FDTI) method in Discover. Calculation results show that the trend in complex formation is n-$BuNH_3^+$ > iso-$BuNH_3^+$ >> sec-$BuNH_3^+$ > tert-$BuNH_3^+$, which is in good agreement with the experimental results.

AC & DC Electrical Characterization of PTC $BaTiO_3$ and Electrodes (PTC $BaTiO_3$ 및 전극의 직류 및 교류 특성)

  • 전표용;최경만
    • Journal of the Korean Ceramic Society
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    • v.28 no.2
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    • pp.101-108
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    • 1991
  • 0.2 mo1% La doped BaTiO3 samples were prepared by a wet chemical process (Pechini process) and electrical conductivity were measured from annealing temperatures(800-110$0^{\circ}C$) to room temperature continuously. 2 probe I-V characteristics showed that Pt electrodes were non-ohmic below about 80$0^{\circ}C$ for Ladoped sample. I-V curves showed varistor behavior and breakdown voltages showed PTC-like behavior. AC complex impedance of 0.2 La and 0.05 Mn mo1% doped BaTiO3 samples with three different electrodes (electroless Ni, Pt, Ag electrodes) were measured with temperature variation. Complex impedance plots showed that the samples with electroless Ni electrodes have negligible electrode resistance. Samples with Ag or Pt paste electrodes showed large electrode resistance. PTC effect, which is defined as the ratio of maximum resistance to minimum resistance, was found to be less than 10 for 0.2 mo1% La doped dense sample however greater than 105 with codoping of 0.05 mo1% Mn and 0.2 mol% La.

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Instability of Electrically Driven Polymer Liquid Jets

  • Lee Min-Hyung;Kang Seung-Baik;Park Joo-Hyuk
    • Journal of Mechanical Science and Technology
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    • v.20 no.3
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    • pp.409-417
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    • 2006
  • Polymer nanofibers can be generated by a electrospinning process. The process involves electrically charged jet of polymer solutions evolving from a droplet. The jet stretches in vertical direction due to the difference between charged particle and constant current located at the collector, while the Coulomb and viscoelastic forces start to contribute to radial and azimuthal (torsional) stretching. In this paper, the unstable dynamics of the liquid polymer jet is examined experimentally and theoretically. A complex viscoelastic rheological model has been adopted to analyze the behavior of a charged liquid jet. The model includes complex phenomena of stress relaxation of the liquid jet resulting from the competing force components. The experimental data of the jet paths captured by high-speed videocamera also confirm the similar behavior with the predictions.

Kinetic model for the coarsening of complex particle in weld HAZ (용접 열영향부에서의 복합 석출물의 조대화 거동 예측 모델)

  • Mun, Jun-O;Kim, Sang-Hun;Lee, Chang-Hui;Jeong, Hong-Cheol;Lee, Jong-Bong
    • Proceedings of the KWS Conference
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    • 2005.11a
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    • pp.201-203
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    • 2005
  • A kinetic model for particle coarsening behavior in the weld heat affected zone (HAZ) was proposed. Unlike the conventional approach, where the mean-sized particle is considered to grow continuously, the proposed model considered the critical particle size which can be derived from the Gibbs-Thomson equation. In this study, the proposed particle coarsening model was applied to study the behavior of (Ti, Nb )(C, N) complex particle in the weld HAZ. The predicted particle size distributions using the proposed model were in agreement with the experimental results.

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A study on design effect models for complex sample survey (설계효과모형 적용에 관한 연구)

  • Park, Inho
    • Journal of the Korean Data and Information Science Society
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    • v.25 no.3
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    • pp.523-531
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    • 2014
  • Design effect is often used in designing and planning sample surveys and/or in evaluating the efficiency of complex design features of the surveys. In this study, we applied Gabler et al. (2006)'s design effect model to 2013 Consumer behavior survey for food that was carried out by stratified two-stage sampling. Usability and adequacy of the design model to a real survey data are discussed and evaluated.

Polarographic Behavior of Cadmium-Tartrate Complexes in Weak Acid and Alkaline Media

  • Lee, Kyung-Ae;Choi, Q.-Won;Ha, Young-Gu;Choy, Jin-Ho;Kim, Ha-Suck
    • Bulletin of the Korean Chemical Society
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    • v.10 no.5
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    • pp.414-418
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    • 1989
  • The electrochemical behavior of cadmium(Ⅱ) in tartrate solution has been studied over the pH range of 6 to 13.6 in order to explain the phenomena of the changes in limiting current depending on the pH. The polarographic limiting current showed a constant value up to pH of 7.8, after which it decreased sharply to show a minimum at pH between 11 and 12. The limiting current, then, increased again with increasing pH. The number of peaks in cyclic voltammogram was 1 to 3 depending on the pH of the solution. Two other voltammetric peaks could be observed when the main reduction peak diminished. The decrease of limiting current at 7.5$Cd(C_4H_3O_6)^-$. The increase of limiting current at strong alkaline solution, however, was due to the complex $Cd(Tart)_2(OH)_2^{4-}$.

[ $Ag^+$ ]-Chitosan Complex Membranes for Propylene/Propane Separation

  • Kim, Jeong-Hoon;Lee, Soo-Bok;Feng, Xianshe
    • Korean Membrane Journal
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    • v.8 no.1
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    • pp.36-42
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    • 2006
  • We have prepared new water-swollen chitosan-$Ag^+$ complex membranes and studied their permeation and separation behavior for propylene and propane gases. The $Ag^+$ containing chitosan complex membranes were prepared from chitosan and $AgNO_3$ aqueous solution. The $AgNO_3$ and water content in the membrane were controlled by adjusting $AgNO_3$ concentration of casting solution. The permeation properties of propylene and propane were investigated as a function of $AgNO_3$ concentration, and various operation conditions. High permeability of above 17 barrer and high selectivity of above 170 could be obtained with the membranes prepared from 3 M $AgNO_3$ aqueous solution. Periodic regeneration test confirmed these membranes could be very useful for the separation of propylene/propane and other olefin/paraffin separation.

The Investigation of Structural Behavior with Variations in the Lower Stories of Complex Buildings using Push-over Analysis (Push-over 해석을 사용한 복합구조물의 하부골조 층수변화에 따른 거동분석)

  • 강병두;전대한;김재웅
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2001.04a
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    • pp.398-405
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    • 2001
  • Upper wall-lower frame(complex building) can be divided into three partition, namely, upper wall, lower frame, and transfer system which link two partitions. The purpose of this study is to investigate the elasto-plastic response characteristics of structures with variation in the stories of lower frame of complex buildings. The conclusions of this study was following; 1) In the push-over analysis for vertically irregular building, the distribution of lateral forces is judged which consider the effects of higher mode. 2) In proportion as the stories of lower frame increase inter-story displacement of lower frame increased, but that of upper wall decreased. 3) The appearance of yielding hinge with variations in the lower stories of complex buildings differed in lower frame of each model, but was almost the same in upper wall.

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Evolution of Cooperative Behavior in Distributed Social Dilemma

  • Yamashita, Tomohisa;Suzuki, Keiji;Yamamoto, Masahito;Ohuchi, Azuma
    • Proceedings of the IEEK Conference
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    • 2000.07a
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    • pp.97-100
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    • 2000
  • In previous research of social dilemma, there is no extended game that the players can select one game out of some social dilemma games. We propose this kind of game as "Distributed Social Dilemma" In this game, each player tries to acquire the adaptive strategy throughout local interactions. We make use of GA as evolutionary operations. In this paper, our purpose is to examine how the game selection of players influences the evolution of cooperation in distributed social dilemma. In order to examine, we formulate distributed social dilemma by Game Theory and use agent-based simulation that each agent is regard as player

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