• Macromolecular Research
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• 제15권6호
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• pp.520-526
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• 2007

The effects of poly($({\varepsilon}$-caprolactone) (PCL) on poly(acrylonitrile-butadiene-styrene) (ABS) and polycarbonate (PC) blends were studied. Blends of ABS/PC (70/30, wt%) with PCL as a compatibilizer were prepared by a twin screw extruder. From the glass transition temperature $(T_g)$ results of the ABS/PC blends with PCL, the $T_g$(PC) of the ABS/PC (70/30) blends decreased with increasing PCL content. From the results of the morphology of the ABS/PC (70/30) blends with PCL, the phase separation between the ABS and PC phases became less significant after adding PCL in the ABS/PC blends. In addition, the morphological studies of the ABS/PC blends etched by NaOH indicated that the shape of the droplet was changed from regular round to irregular round by adding PCL in the ABS/PC blends. These results for the mechanical properties of the ABS/PC blends with PCL indicated that the tensile, flexural and impact strengths of the ABS/PC (70/30) blends peaked at a PCL content of 0.5 phr. From the results for the rheological properties of the ABS/PC (70/30) blends with PCL content, the storage modulus, loss modulus and complex viscosity increased at PCL content up to 5 phr. From the above results of the $T_g$, mechanical properties, morphology and complex viscosity of the ABS/PC blends with PCL, it was concluded that the compatibility was increased with PCL addition in the ABS/PC (70/30, wt%) blends and that the optimum concentration of PCL as a compatibilizer is 0.5 phr.

• 폴리머
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• 제35권5호
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• pp.451-457
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• 2011

라텍스 기법으로 제조한 폴리스티렌(PS)/다중벽 탄소나노튜브(MWCNT) 나노복합재료의 라텍스 입자 크기에 따른 유변학적, 전기적 물성을 고찰하였다. 나노복합재료는 무유화제 유화중합과 분산중합으로 합성한 단분산 PS 입자에 MWCNT를 초음파 분산시킨 다음 동결건조 과정을 거쳐 제조하였다. PS/MWCNT 나노복합재료는 MWCNT 함량이 증가할수록 점차 네트워크 구조를 형성하여 저장 탄성률, 복소 점도 및 전기 전도도가 급격하게 증가하였다. MWCNT 함량에 따른 저장 탄성률 및 복소 점도 증가 효과는 라텍스 입자 크기가 큰 경우 더욱 뚜렷하였다. 입자 크기에 따른 전기적 물성은 MWCNT 함량에 따라 상이한 경향을 보여 주었는데, 함량이 적은 경우 작은 입자로 제조한 나노복합재료가 높은 전기 전도도를 보여 주었으나 함량이 증가할수록 큰 입자의 경우가 높은 값을 보여 주었다.

• 대한조선학회논문집
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• 제52권1호
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• pp.25-33
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• 2015

Following the previous works on the natural frequency of heaving circular cylinder, i.e. Lee and Lee (2013) and Kim and Lee (2013), an investigation of the same spirit on the 2-dimensional cylinder of Lewis form has been conducted. As before, the natural frequency is defined as that corresponding to the local maximum of the MCFR (Modulus of Complex Frequency Response), which is given by the equation of motion in the frequency domain analysis. Hydrodynamic coefficients were found by using the Ursell-Tasai method, and numerical results for them were obtained up to much higher frequencies than before, for which the method was known as numerically unstable in the past. For a wide range of H, the beam-draft ratio, and ${\sigma}$, the sectional area coefficient, including their practical ranges for a ship, results for the natural frequency were computed and presented in this work. Two approximate values for the natural frequency, one proposed by Lee (2008) and another one by the damped harmonic oscillator, were also compared with the current results, and for most cases it was observed that the current result is between the two values. Our numerical results showed that the values of the local maximum of MCFR as well as the natural frequencye increase as ${\sigma}$ increases while H decreases. At present, extension of the present finding to the 3-dimensional ship via the approximate theory like the strip method looks promising.

• 펄프종이기술
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• 제42권5호
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• pp.74-82
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• 2010

Curtain stability without curtain contraction is critical for a successful operation in curtain coating, and this can be influenced by the change in particle dynamics and rheological properties of coating colors. In this study, polyvinyl alcohol (PVA) and carboxymethyl cellulose (CMC) were added to control the rheology of GCC based curtain coating colors. Surface tension was increased slightly with increasing content of cobinder. Shear-thinning of viscosity was more pronounced for the CMC containing GCC coating colors. Complex modulus decreased when small amount of PVA was used as a cobinder, but it increased in other coating colors. Extensional viscosity was increased with increasing of the cobinder content, but CMC was more effective. Results indicate that pigment interaction with PVA is different from that with CMC. Dispersibility of coating colors was improved due to steric stabilization when small amounts of PVA was used, but flocculation occurred by bridging when the amount of PVA was increased. Dispersibility of coating colors was improved when small amount of CMC was added, while flocculation was observed by depletion effect when the concentration of CMC was increased in coating colors. Addition of cobinders at proper levels gave positive effects both in rheological properties and curtain stability. On the other hand, excessive amount of cobinders caused particle flocculation and this resulted in rheological and curtain stablity problems.

• 대한치과보철학회지
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• 제45권4호
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• pp.457-468
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• 2007

Statements of problem: The fracture of acrylic resin dentures remains an unsolved problem. Therefore, many investigations have been performed and various approaches to strengthening acrylic resin, for example, the reinforcement of heat-cured acrylic resin using glass fibers, have been suggested over the years. Silane is important for bonding between glass fiber and resin. Purpose: The aim of the present study was to investigate the effect of various silane on the strength of PMMA resin and roughness of resin-glass fiber complex after abrasion test. Material and methods: 3mm glass fiber (Chopped strand, Hankuk fiber Co., Milyang, Korea) was treated with 3 kinds of silane (MPS, EPS, APS) (Sila-ace, Chisso chemical, Tokyo, Japan) and mixed with PMMA resin(Vertex RS, Vertex Dental B.V., Zeist, Netherlands). Transverse strength and Young's modulus was measured using Instron (Instron model 4466, Instron, Massachusetts, USA). After abrasion test (The 858 Mini Bionix II Test System, MTS System Co., Minnesota, USA) surface roughness was evaluated using tester (Form Talysurf plus, Taylor Hopson Ltd., Leicester England). Examination of scanning electron microscope was also performed. Results: Within this study, the following conclusions were drawn. 1. Surface treatment of glass fiber with MPS and APS increased transverse strength of PMMA resin complex, but surface treatment with EPS decreased transverse strength of PMMA resin complex (p<0.05). 2. Silane treated glass fiber increased Young's modulus of PMMA resin complex compared to desized glass fiber (p<0.05). 3. Roughness increased after abrasion test in case of PMMA resin reinforced with desized glass fiber (p<0.05). 4. Roughness change was not observed after abrasion test in case of PMMA resin reinforced with silane treated glass fiber (p>0.05).

• 구강회복응용과학지
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• 제24권3호
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• pp.311-316
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• 2008

Calcium phosphate cement (CPC)는 우수한 생체 친화성을 바탕으로 치과 및 의과 쪽에서 성공적인 bone substitute로 사용되어 왔다. 긴 경화시간 및 washout tendency 등 CPC의 단점을 개선하기 위해 다양한 종류의 경화액 및 첨가제등에 대한 연구가 이루어졌다. 그러나 첨가제의 종류에 따른 CPC paste의 점탄성을 정량적으로 비교한 연구는 많지 않다. 이 연구에서는 2% hydroxyprophyl methylcellulose (HPMC)와 35% polyacrylic acid (PAA)의 두 가지 경화액과 혼합된 CPC의 유변학적 성질을 관찰하고 비교하고자 하였다. Dicalcium phosphate dihydrate (DCPD)를 2% HPMC 및 35% PAA와 각각 1:1의 분액비로 30초간 섞은 후 cone and plate geometry를 가지는 rheometer를 사용하여 frequency sweep test와 time sweep test를 통해 shear storage modulus (G'), shear loss modulus (G''), 그리고 complex viscosity (${\eta}^*$)를 측정하였다. 2% HPMC군과 35% PAA군의 complex viscostiy의 차이를 Mann-whitney test with Bonferroni's collection을 사용하여 분석하였다. 실험결과 2% HPMC 및 35% PAA 군 모두에서 shear thinning과 yield behavior등 pseudoplastic property를 보였으며 complex viscosity는 HPMC 군에서 PAA 군보다 통계적으로 유의성 있게 높았다. (p<0.05).

• 대한기계학회논문집A
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• 제25권8호
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• pp.1189-1196
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• 2001

The objective of this paper is to investigate the applicability of acoustic emission(AE) technique to monitor the progress of the thermal shock damage on alumina ceramic. For this purpose, alumina ceramic specimen was heated in the furnace and then was quenched in the water tank. When the specimen was quenched in the water tank, complex AE signals due to the initiation of micro-cracks and boiling effect were generated by the progress of thermal shock damage. These mixed AE signals have to be classified for monitoring the degree of the thermal shock damage of alumina ceramics. In this paper, the mixed AE signals generated from both the boiling effect and the crack initiation under thermal shock test was analyzed. The characteristics of AE signals were also discussed by considering the variation of bending strength and Yongs modulus of specimens.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2007년도 춘계학술대회 논문집
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• pp.1827-1832
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• 2007

The purpose of a railway track is to provide a smooth surface for safe and economical train transportation. The performance of the track results from a complex interaction of the track and subgrade components in response to train loading and environmental actions. In the past, the role of subgrade as the track foundation were not recognized adequately. There are insufficient information and inadequate methods for subgrade design, assessment and improvement. This situation has survived for a long time largely because a subgrade defect can often be adjusted by adding more ballast under the ties or applying more frequent track maintenance. Therefore, the application of reinforced roadbed technology will be expected to increase in the future. The reinforced roadbed thickness is set depending on subgrade reaction modulus$(K_{30})$ in the condition of upper subgrade through PBT in both conventional railroad and KTX railroads. As train velocity (V), train passing tonnage (N), and train axial load (P) are not considered in design, the roadbed thickness could be overestimated (or underestimated). Therefore, In this study, the computer model, GEOTRACK, was analyzed the influence of reinforced roadbed thickness factors on track modulus and the characteristics of stress pulses in track and subgrade generated by repeated axle loading.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2007년도 추계학술대회 논문집
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• pp.1279-1286
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• 2007

The purpose of a railway track is to provide a smooth surface for safe and economical train transportation. The performance of the track results from a complex interaction of the track and subgrade components in response to train loading and environmental actions. In the past, the role of subgrade as the track foundation were not recognized adequately. There are insufficient information and inadequate methods for subgrade design, assessment and improvement. This situation has survived for a long time largely because a subgrade defect can often be adjusted by adding more ballast under the ties or applying more frequent track maintenance. Therefore, the application of reinforced roadbed technology will be expected to increase in the future. The reinforced roadbed thickness is set depending on subgrade reaction modulus($K_{30}$) in the condition of upper subgrade through PBT in both conventional railroad and KTX railroads. As train velocity (V), train passing tonnage (N), and train axial load (P) are not considered in design, the roadbed thickness could be overestimated (or underestimated). Therefore, in this study has proposed a determination method of reinforced roadbed thickness using design chart made by resilience modulus and properties of earthwork materials.

• 한국음향학회지
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• 제11권4호
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• pp.22-30
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• 1992

섬유강화 복합재료의 동탄성계수와 감쇠특성을 규명하기 위하여 랜덤하게 분포된 무한 실린더 형상의 산란계를 가진 메질내에서, 축방향으로 분극되어 조화운동을 하는 탄성파의 전파에 관하여 연구하였다. 단일 실린더에 대한 산란계수로부터 Lax의 준결정근사법을 이용하여 다중산란에 관한 이론을 유도하였고, 매질내에서의 파동전파특성을 내포하는 분산관계식을 얻었다. 다중 산란에 의한 실린더간의 상호작용을 수식화하기 위하여 필요한 실린더의 쌍분포함수는 몬테카를로 모의실험을 이용하여 구하였다. 수치적으로 구한 감쇠계수 및 유효전단강성을 주파수와 면적밀도의 함수로 제시하였다.