• Title/Summary/Keyword: Combustion system

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Post-combustion CO2 capture with potassium L-lysine (Potassium L-lysine을 이용한 연소 후 이산화탄소 포집)

  • Lim, Jin Ah;Yoon, Yeo Il;Nam, Sung Chan;Jeong, Soon Kwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.9
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    • pp.4627-4634
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    • 2013
  • Carbon dioxide is one of the main causes of global warming. In order to develop a novel absorbent, the characteristics of amino acid salts solution as a solvent for $CO_2$ capture in continuous process were investigated. The cost of $CO_2$ capture is almost 70% of total cost of CCS (carbon dioxide capture and storage). In the carbon dioxide capture process, process maintenance costs consist of the absorbent including the absorption, regeneration, degradation, and etc. It is very important to study the characteristics of absorbent in continuous process. In this study, we have investigated the properties of potassium L-lysine (PL) for getting scale-up factors in continuous process. To obtain optimum condition for removal efficiency of $CO_2$ in continuous process by varying liquid-gas (L/G) ratio, concentration of $CO_2$ and absorbent (PL) were tested. The stable condition of absorber and regenerator (L/G) ratio is 3.5. In addition, PL system reveals the highest removal efficiency of $CO_2$ with 3.5 of L/G and 10.5 vol% $CO_2$ ($1.5Nm^3/h$).

An Experimental Study on the Influence of the Spread of Firebrand on Building Exterior Materials and Roofing Materials in Urban Areas (도심지 인접 산불의 불티 확산이 건축물 외장재와 지붕재에 미치는 영향에 관한 실험적 연구)

  • Min, Jeong-Ki
    • Journal of the Society of Disaster Information
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    • v.17 no.3
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    • pp.617-626
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    • 2021
  • Purpose: The purpose of this study is to evaluate the fire srpead risk of building exterior and roofing materials due to the firebrand of forest fire occurring in the urban areas. Method: In order to achieve this research purpose, by selecting building materials used for exterior and roofing materials of buildings, the time to ignition, total heat release, and heat release rate were investigated, and a forest fire firebrand system was established to the possibility of fire spread was confirmed. Result: As a result of the cone calorimeter test, the roofing material had a similar or faster ignition time due to radiant heat compared to the exterior material with the steel plate exposed to the outside, and showed a higher heat release rate and total heat release than the exterior material. Although it was affected by the flammable material, it was confirmed that it did not spread easily due to the limited amount of combustible material, and carbonization marks appeared inside. Conclusion: The cone calorimeter test method has been shown to be useful in understanding the combustion characteristics of building materials by radiant heat, but the fire spread due to a firebrand in a forest fire is directly affected by the flame due to the ignition of surrounding combustibles, so finding a direct correlation with the cone calorimeter method is difficult. It is judged that the roof material may be more vulnerable to the spread of fire due to the fire than the exterior material.

Vulnerability Assessment for Fine Particulate Matter (PM2.5) in the Schools of the Seoul Metropolitan Area, Korea: Part I - Predicting Daily PM2.5 Concentrations (인공지능을 이용한 수도권 학교 미세먼지 취약성 평가: Part I - 미세먼지 예측 모델링)

  • Son, Sanghun;Kim, Jinsoo
    • Korean Journal of Remote Sensing
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    • v.37 no.6_2
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    • pp.1881-1890
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    • 2021
  • Particulate matter (PM) affects the human, ecosystems, and weather. Motorized vehicles and combustion generate fine particulate matter (PM2.5), which can contain toxic substances and, therefore, requires systematic management. Consequently, it is important to monitor and predict PM2.5 concentrations, especially in large cities with dense populations and infrastructures. This study aimed to predict PM2.5 concentrations in large cities using meteorological and chemical variables as well as satellite-based aerosol optical depth. For PM2.5 concentrations prediction, a random forest (RF) model showing excellent performance in PM concentrations prediction among machine learning models was selected. Based on the performance indicators R2, RMSE, MAE, and MAPE with training accuracies of 0.97, 3.09, 2.18, and 13.31 and testing accuracies of 0.82, 6.03, 4.36, and 25.79 for R2, RMSE, MAE, and MAPE, respectively. The variables used in this study showed high correlation to PM2.5 concentrations. Therefore, we conclude that these variables can be used in a random forest model to generate reliable PM2.5 concentrations predictions, which can then be used to assess the vulnerability of schools to PM2.5.

Feasibility Study of Fuel Property for Fuel Processing Design on Ship and Warship (선박의 연료품질 기반 군용선박의 연료품질 적용가능성 분석)

  • Hwang, Gwang-Tak
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.4
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    • pp.281-286
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    • 2021
  • The International Maritime Organization recently proposed a policy to establish a preemptive response strategy for exhaust gas pollution on board ships according to the recent strengthening of the sulfur content regulations. Discussions on improving the fuel oil quality and reducing emissions are also ongoing. Fuel oil quality information, which is one of the main concerns internationally, is increasing as the sulfur content standard is being applied from the current 3.5% to 0.5% by 2020. From the perspective of shipping companies and recipients, the essential quality of fuel oil is also requested for domestic and international fuel oil information, basic properties, correlation information between characteristics for application of solid ships and ships. The current standard for the basic quality of fuel oil is generally used, but the nature and composition of the fuel oil are very complex, and the interpretation of the basic quality is complicated because there are many cases outside the scope of the basic standard. Various factors were analyzed for the basic quality of fuel oil in terms of the basic quality of fuel oil, optimization of operation in ships, and fuel efficiency in ships. Moreover, the possibility of applying the standard according to the dilution was suggested.

Study on Characteristics of Change of Physical/Chemical property of Refined Fuel Oil(Reduced-pressure) by Mixing with By-product Fuel Oil(No. 2) (부생연료유(2호) 혼합에 따른 정제연료유(감압)의 물성 변화 특성 연구)

  • Doe, Jin-woo;Lim, Tae-yun;Yim, Eui-soon;Lee, Joung-min;Kang, Hyung-kyu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1349-1358
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    • 2018
  • In addition to responding to the environmental pollution caused by fossil fuels, the enforcement of Renewable Fuel Standard(RFS) system has increased the utilization of renewable energy such as refined fuels oil. The by-product fuel oil(No. 2) and the refined fuel oil(reduced-pressure) are strictly regulated by the domestic legislation and the chemical property changes of the refined fuel oil(reduced-pressure) mixed with the by-product fuel oil(No. 2) were analyzed. As a result of analyzing the physical properties of refined fuel oil(reduced pressure) obtained by mixing 1 : 1 of by-product fuel oil(No. 2), it satisfied the quality standards stipulated by the domestic Enforcement Decree of the Wastes Control Act. However, the results of the additional tests related to the fuel showed a high aromatic content. The high content of aromatic in a fuel is likely to cause the soot and ehaust emission gas during the combustion of the used equipment.

A Study on the Effect of De-NOx Device on GHG Emissions (De-NOx 저감장치가 온실가스 배출량에 미치는 영향 연구)

  • Kim, Sungwoo;Kim, Jeonghwan;Kim, Kiho;Oh, Sang-Ki
    • Journal of ILASS-Korea
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    • v.23 no.4
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    • pp.212-220
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    • 2018
  • As increase the number of vehicles, the issue of greenhouse gas that was emitted by them became important. As a result, greenhouse gas (GHG) regulations are being strengthened and efforts are being actively made to reduce greenhouse gas emissions in the automotive industry. In the other hand, regulations for harmful emission of vehicles have been reinforced by step. Especially, the lastly applied step, so called Euro 6, not only decreased NOx limit down to half of Euro 5 but also introduced real driving emission limit for NOx and PN. It is a challenge for manufacturers to meet the recent GHG regulation as well as the latest emission regulation. To overcome these regulations a De-NOx after-treatment system is being applied to diesel vehicles that are known emitting the lowest GHG among conventional internal combustion engines. At the time of the introduction of Euro 6 emission standard in Korea, in the domestic fuel economy certification test, some diesel vehicles emitted more $CH_4$ than Euro 5 vehicles. As a result, it was confirmed that LNT-equipped vehicles emitted a high level $CH_4$ and the level exceeded the US emission standard. In order to determine the reason, various prior literature was investigated. However, it was difficult to find a detailed study on the methane increase with LNT. In this paper, to determine whether the characteristics of vehicles equipped with LNT the affects the above issue and other greenhouse gases, 6 passenger cars were tested on several emission test modes and ambient temperatures with a environment chamber chassis dynamometer. 2 cars of these were equipped with LNT only, other 2 cars had SCR only, and LNT + SCR were applied to remaining 2 cars. The test result shown that the vehicles equipped with LNT emitted more $CH_4$ than the vehicles with SCR only. Also, $CH_4$ tended to increase as the higher acceleration of the test mode. However, as the test temperature decreases, $CH_4$ tended to decreased. $CO_2$ was not affected by kinds of De-NOx device but characteristic of the test modes.

A Study on the Uniform Mixing of Ammonia-Air with the Change of Ammonia Supply Device Shape in a De-NOx System (탈질설비에서 암모니아 혼합기의 형상에 따른 암모니아-공기 균일 혼합에 관한 연구)

  • Ha, Ji Soo
    • Journal of the Korean Institute of Gas
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    • v.23 no.3
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    • pp.20-26
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    • 2019
  • Selective catalytic reduction(SCR) method is widely used among various methods for reducing nitrogen oxides in combustion devices of coal power plant. In the present study, the computational fluid dynamic analysis was accomplished to derive the optimal shape of ammonia-dilution air mixing device in a ammonia injection grid. The distribution characteristics of flow and $NH_3$ concentration had been elucidated for the reference shape of ammonia mixing device(Case 1). In the mixing device of Case 1, it could be seen that $NH_3$ distribution was shifted to the wall opposite to the inlet of the ammonia injection pipe. For the improvement of $NH_3$ distribution, the case(Case 2) with closing one upper injection hole and 4 side injection holes, the case(Case 3) with installing horizontal plate at the upper of ammonia injection pipe, the case(Case 4) with installing horizontal plate and horizontal arc plate at he upper of ammonia injection pipe were investigated by analyzing flow and $NH_3$ concentration distributions. From the present study, it was found that the % RMS of $NH_3$ for Case 4 was 4.92%, which was the smallest value among four cases, and the range of $R_{NH3}$ also has the optimally uniform distribution, -10.82~8.34%.

CFD Analysis on the Internal Reaction in the SNCR System (SNCR 시스템 내부의 물질 반응에 관한 전산해석적 연구)

  • Koo, Seongmo;Yoo, Kyung-Seun;Chang, Hyuksang
    • Clean Technology
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    • v.25 no.1
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    • pp.63-73
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    • 2019
  • Numerical analysis was done to evaluate the chemical reaction and the reduction rate inside of selective non-catalytic reduction to denitrification in combustion process. The $NO_X$ reduction in selective non-catalytic reduction is converted to not only nitrogen but also nitrous oxide. Simultaneous $NO_X$ reduction and nitrous oxide generation suppressing is required in selective non-catalytic reduction because nitrous oxide influences the global warming as a greenhouse gas. The current study was performed compare the computational analysis in the same temperature and amount of NaOH, and in comparison with the previous research experiments and confirmed the reliability of the computational fluid dynamics. Additionally, controlling the addition amount of NaOH to predict the $NO_X$ reduction efficiency and nitrous oxide production. Numerical analysis was done to check the mass fraction of each material in the measurement point at the end of selective non-catalytic reduction. Experimental Value and simulation value by numerical analysis showed an error of up to 18.9% was confirmed that a generally well predicted. and it was confirmed that the widened temperature range of more than 70% $NO_X$ removal rate is increased when the addition amount of NaOH. So, large and frequent changes of the reaction temperature waste incineration facilities are expected to be effective.

Recycling of useful Materials from Fly Ash of Coal-fired Power Plant (석탄화력발전소에서 발생되는 비회로부터 유용성분의 회수)

  • Kim, Dul-Sun;Han, Gwang Su;Lee, Dong-Keun
    • Clean Technology
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    • v.25 no.3
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    • pp.179-188
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    • 2019
  • Upon the combustion of coal particles in a coal-fired power plant, fly ash (80%) and bottom ash (20%) are unavoidably produced. Most of the ashes are, however, just dumped onto a landfill site. When the landfill site that takes the fly ash and bottom ash is saturated, further operation of the coal-fired power plant might be discontinued unless a new alternative landfill site is prepared. In this study, wet flotation separation system (floating process) was employed in order to recover unburned carbon (UC), ceramic microsphere (CM) and cleaned ash (CA), all of which serving as useful components within fly ash. The average recovered fractions of UC, CM, and CA from fly ash were 92.10, 75.75, and 69.71, respectively, while the recovered fractions of UC were higher than those of CM and CA by 16% and 22%, respectively. The combustible component (CC) within the recovered UC possessed a weight percentage as high as 52.54wt%, whereas the burning heat of UC was estimated to be $4,232kcal\;kg^{-1}$. As more carbon-containing UC is recovered from fly ash, UC is expected to be used successfully as an industrial fuel. Owing to the effects of pH, more efficient chemical separations of CM and CA, rather than UC, were obtained. The average $SiO_2$ contents within the separated CM and CA had a value of 53.55wt% and 78.66wt%, respectively, which is indicative of their plausible future application as industrial materials in many fields.

Evaluating meteorological and hydrological impacts on forest fire occurrences using partial least squares-structural equation modeling: a case of Gyeonggi-do (부분최소제곱 구조방정식모형을 이용한 경기도 지역 산불 발생 요인에 대한 기상 및 수문학적 요인의 영향 분석)

  • Kim, Dongwook;Yoo, Jiyoung;Son, Ho Jun;Kim, Tae-Woong
    • Journal of Korea Water Resources Association
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    • v.54 no.3
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    • pp.145-156
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    • 2021
  • Forest fires have frequently occurred around the world, and the damages are increasing. In Korea, most forest fires are initiated by human activities, but climate factors such as temperature, humidity, and wind speed have a great impact on combustion environment of forest fires. In this study, therefore, based on statistics of forest fires in Gyeonggi-do over the past five years, meteorological and hydrological factors (i.e., temperature, humidity, wind speed, precipitation, and drought) were selected in order to quantitatively investigate causal relationships with forest fire. We applied a partial least squares structural equation model (PLS-SEM), which is suitable for analyzing causality and predicting latent variables. The overall results indicated that the measurement and structural models of the PLS-SEM were statistically significant for all evaluation criteria, and meteorological factors such as humidity, temperature, and wind speed affected by amount of -0.42, 0.23 and 0.15 of standardized path coefficient, respectively, on forest fires, whereas hydrological factor such as drought had an effect of 0.23 on forest fires. Therefore, as a practical method, the suggested model can be used for analyzing and evaluating influencing factors of forest fire and also for planning response and preparation of forest fire disasters.