• Title/Summary/Keyword: Combustion product

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The Utilization of Waste Seashell for High Temperature Desulfurization

  • Kim, Young-Sik;Hong, Sung-Chul
    • Journal of Environmental Health Sciences
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    • v.36 no.2
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    • pp.136-140
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    • 2010
  • The integrated gasification combined cycle (IGCC) is one of the most promising proposed processes for advanced electric power generation that is likely to replace conventional coal combustion. This emerging technology will not only improve considerably the thermal efficiency but also reduce or eliminate the environmentally adverse effects normally associated with coal combustion. The IGCC process gasifies coal under reducing conditions with essentially all the sulfur existing in the form of hydrogen sulfide ($H_2S$) in the product fuel gas. The need to remove $H_2S$ from coal derived fuel gases is a significant concern which stems from stringent government regulations and also, from a technical point of view and a need to protect turbines from corrosion. The waste seashells were used for the removal of hydrogen sulfide from a hot gas stream. The sulphidation of waste seashells with $H_2S$ was studied in a thermogravimetric analyzer at temperature between $600^{\circ}C$ and $800^{\circ}C$. The desulfurization performance of the waste seashell sorbents was experimentally tested in a fixed bed reactor system. Sulfidation experiments performed under reaction conditions similar to those at the exit of a coal gasifier showed that preparation procedure and technique, the type and the amount of seashell, and the size of the seashell affects the $H_2S$ removal capacity of the sorbents. The pore structure of fresh and sulfided seashell sorbents was analyzed using mercury porosimetry, nitrogen adsorption, and scanning electronmicroscopy.

A study on the calculation model for emissivities of combustion gases (燃燒氣體의 放射率 計算模型에 관한 硏究)

  • 허병기;이청종;양지원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.6
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    • pp.904-912
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    • 1987
  • The main mode of heat transfer of combustion gases at high temperature is thermal radiation of nonluminous gases, CO$_{2}$ and H$_{2}$O. Therefore the information of the emissivities of CO$_{2}$ and H$_{2}$O would be very important in the thermal performance analysis of furnace. In this study, an exponential model for the emissivities of CO$_{2}$ and H$_{2}$O was derived as function of P$_{g}$L and polynomial of reciprocal of temperature. Error analysis between the calculated values from present model and the valued of Hottel Chart was performed over temperature range of 1000-5000 R and a partial-pressure-length product range of 0.003 to 20 ft-atm. For CO$_{2}$ gray gas, the error percent between the calculated values and the values from Hottel Chart was distributed within 2.5% in case of using a polynomial in 1/T of degree 4. For H$_{2}$O gray gas, the model has an error range of 0 to 2.5% in case of using a polynomial in 1/T of degree 3.

The Effects of Combustion Products Dilution and Wall Temperature on the Ignition of Methane Fuel (메탄연료의 점화특성에 미치는 연소 생성물 희석 및 벽면온도의 영향)

  • Song, Keum-Mi;Oh, Chang-Bo
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.9-15
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    • 2012
  • The ignition characteristics in a confined axisymmetric coflow $CH_4$ jet were investigated numerically with the Fire Dynamics Simulator(FDS). The $CH_4$ fuel stream was diluted with main combustion product gases, such as $O_2$, $N_2$, CO, $CO_2$, and $H_2O$, and the mixed fuel stream was heated up to the sufficient temperature where a supplying fuel stream can be ignited. For the calculation of chemical reaction in the simulation, a 2-step global finite chemistry model was considered. Boundary condition for confined wall was optimized by investigating the effects of wall temperature on the ignition characteristics of fuel stream. In addition, the effects of composition of diluents in the fuel stream and fuel stream temperature on the ignition of fuel steam were investigated. The ignition characteristics of $CH_4$ stream with diluents were very sensitive to the wall temperature, composition of diluents in the fuel stream and fuel stream temperature.

Effects of $CO_2$ and $O_2$ Addition on Methane Dry Reforming Using Arc-Jet Plasma Reactor (아크제트 플라즈마를 이용한 메탄건식개질 반응에서 $CO_2$$O_2$ 첨가의 영향)

  • Hwang, N.K.;Cha, M.S.;Song, Y.H.
    • Journal of the Korean Society of Combustion
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    • v.13 no.4
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    • pp.47-53
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    • 2008
  • The reaction mechanism of methane dry reforming has been investigated using an arc-jet reactor. The effects of input power, $CO_2/CH_4$ and added $O_2$ were investigated by product analysis, including CO, $H_2$, $C_{2}H_{Y}$ and $C_{3}H_{Y}$ as well as $CH_4$ and $CO_2$. In the process, input electrical power activated the reactions between $CH_4$ and $CO_2$ significantly. The increased feed ratio of the $CO_2$ to $CH_4$ in the dry reforming does not affect to the $CH_4$ conversion. but we could observe increase in CO selectivity together with decreasing $H_2$ generation. Added oxygen can also increase not only CO selectivity but also $CH_4$ conversion. However, hydrogen selectivity was decreased significantly due to a increased $H_{2}O$ formation.

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An Experimental Study on Relationship Between Global Equivalence Ratio and Fire Characteristics in Full-Scale Compartment Fires (실제 규모의 구획화재에서 총괄당량비와 화재특성의 상관관계에 관한 실험적 연구)

  • Hwang, Cheol-Hong;Park, Chung-Hwa;Ko, Gwon Hyun;Lock, Andrew
    • Journal of the Korean Society of Combustion
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    • v.15 no.3
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    • pp.32-39
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    • 2010
  • An experimental study was conducted to investigate the relationship between global equivalence ratio(GER) and fire characteristics in an ISO 9705 room. Heptane fuel was burned with different fuel flow rates and doorway widths in order to force the room to be placed in different GER conditions. It was observed that after the onset of under-ventilated fire conditions, temperature and unburned fuel components such as CO and soot increased with increasing heat release rate (HRR), regardless of the doorway width. From the analysis of local mixture fraction, it was reconfirmed that the inclusion of soot production in the product composition was very important to predict accurately the chemical conditions inside the compartment, particularly for the under-ventilated fire conditions. In addition, the local equivalence ratio (LER) was directly proportional to the GER with a unit gradient regardless of doorway width when the soot production was included in the chemical products. This finding provided an important potential that the GER could be used to correlate the local thermal and chemical environment measured at the upper layer of a full-scale enclosure when soot was included.

Characteristics of Solid Electrolyte $CO_2$ Gas Sensors (고체전해질을 사용한 $CO_2$가스센서의 응답기구)

  • Kim, G.Y.;Park, Y.P.;Lee, S.I.;Lee, W.J.;Hong, J.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.562-564
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    • 2002
  • In recent years, environments of our globe has been getting worse as a result of rapid growth of socioeconomic activities. The global environmental issues of acid rain, green house effect and ozone depletion are caused by various chemical pollutants, emitted from industries, automobiles and home. Most of these pollutants are produced by combustion processes. CO2 as a chief criminal of the greenhouse effect is a main combustion product of fossil fuels. Development of solid-state electrochemical devices for detecting CO2 is demonstrated based on various combination of solid electrolytes and auxiliary sensing materials. The object of this research is to develop various sensor performance for solid electrolyte gas sensor, and to test gas sensor performance manufactured. So we try to present a guidance for developing potential type gas sensor. We concentrated on development of manufacturing process and performance test.

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Indoor, Outdoor, and Personal Exposure to Nitrogen Dioxide Comparing Industrial Complex Area with Country Area (공단지역과 시골지역 주택 실내, 실외 및 개인의 이산화질소 노출평가)

  • Yang, Won-Ho;Im, Sung-Guk;Son, Bu-Soon
    • Journal of Environmental Health Sciences
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    • v.34 no.3
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    • pp.183-187
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    • 2008
  • Indoor air quality can be affected by indoor sources, ventilation, decay, and outdoor levels. Various indoor and out-door combustion sources produce nitrogen dioxide ($NO_2$), which is a by-product of high temperature fossil fuel combustion. Especially, the presence of gas ranges and smoking have been identified as major factors contributing to indoor $NO_2$ exposures. In this study, we compared an industrial complex area with a country area by assessing the personal exposure to $NO_2$with measurements of indoor and outdoor $NO_2$ levels in residences and by house characteristics and questionnaire. Personal exposure concentrations were significantly correlated with indoor $NO_2$ concentrations of residences in both the industrial complex area and the country area with correlation coefficients of 0.561 and 0.664, respectively, compared to outdoors. Multiple regression analysis, indicated that indoor $NO_2$ levels in residences were only affected by outdoor levels (p = 0.000) in spite of higher indoor sources such as smoking. Therefore, it is suggested that outdoor air quality as well as indoor air quality should be considered in the reduction of the personal exposure to air pollutants.

Evaluation of Specific Impulse for Liquid Rocket Engine Adopting Gas Generator Cycle (가스발생기 사이클 액체로켓엔진의 비추력 평가)

  • Cho, Won-Kook;Seol, Woo-Seok
    • Aerospace Engineering and Technology
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    • v.9 no.1
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    • pp.93-97
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    • 2010
  • The analysis of specific impulse of the liquid rocket engine employing gas generator cycle with LOx/kerosene as propellant has been performed. The relative error of performance of 300 ton level engine is 0.1%s for specific impulse and 12% for optimal combustion pressure comparing with the published data. The difference of the performance model and the material property models of gas generator product gas are the presumed major reason of discrepancy. The optimal condition of 30 ton level engine is combustion pressure of 68 bar and mixture ratio of 2.2 for maximum specific impulse. This optimal condition can be changed by performance models.

A Study on the progressive die design and making of gas boiler exhaust pipe (가스보일러 연소배기관 프로그레시브금형의 설계와 제작에 관한 연구)

  • Lee, Chun-Kyu;Kim, Young-Choon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.9
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    • pp.4111-4116
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    • 2013
  • The progressive die producing continuously while transferring in order a multiple process is processing law that it is efficient and quality is excellent. In this study the position of precision secured that it occurred when be welded exhaust efficiency of gas boiler combustion exhaust pipe and the exhaust pipe which is cause of incomplete combustion for the purpose of productivity increase. it add burring to a product form and progressive die make die don't disassemble and it be able to exchange burring punch the position of precision and productivity by progressive die is able to improve.

Removal of Flooding in a PEM Fuel Cell at Cathode by Flexural Wave

  • Byun, Sun-Joon;Kwak, Dong-Kurl
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.104-114
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    • 2019
  • Energy is an essential driving force for modern society. In particular, electricity has become the standard source of power for almost every aspect of life. Electric power runs lights, televisions, cell phones, laptops, etc. However, it has become apparent that the current methods of producing this most valuable commodity combustion of fossil fuels are of limited supply and has become detrimental for the Earth's environment. It is also self-evident, given the fact that these resources are non-renewable, that these sources of energy will eventually run out. One of the most promising alternatives to the burning of fossil fuel in the production of electric power is the proton exchange membrane (PEM) fuel cell. The PEM fuel cell is environmentally friendly and achieves much higher efficiencies than a combustion engine. Water management is an important issue of PEM fuel cell operation. Water is the product of the electrochemical reactions inside fuel cell. If liquid water accumulation becomes excessive in a fuel cell, water columns will clog the gas flow channel. This condition is referred to as flooding. A number of researchers have examined the water removal methods in order to improve the performance. In this paper, a new water removal method that investigates the use of vibro-acoustic methods is presented. Piezo-actuators are devices to generate the flexural wave and are attached at end of a cathode bipolar plate. The "flexural wave" is used to impart energy to resting droplets and thus cause movement of the droplets in the direction of the traveling wave.