• Title/Summary/Keyword: Combustion method

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Determination of Cholesterol, Fatty Acids and Polyaromatic Hydrocarbons in PM10 Particles Collected from Meat Charbroiling (고기구이 스모크에서 채취한 PM10입자에서 콜레스테롤, 지방산과 PAH의 분포)

  • Seo, Young-Hwa;Ko, Kwang-Youn;Jang, Young-Kee
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.2
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    • pp.155-164
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    • 2010
  • Emission from biomass combustion such as meat charbroiling is an important source of organic aerosol. Since source profiles are necessary input profiles for source apportionment of aerosol by a chemical mass balance model, meat cooking organic source profiles are developed by measuring organic marker compounds, including palmitic acid, stearic acid, oleic acid and cholesterol as well as PAH compounds. Emissions from meat and pork charbroiling are collected on quartz filters with a PM10-high volume sampler, extracted with organic solvents, derivatized with diazomethane/TMS and analyzed by GC/MS isotope dilution method. Organic and elemental carbon are also analyzed by an OCEC analyzer. Wt.% of cholesterol to the organic carbon(OC) content from beef and pork charbroiling is only 0.056 and 0.062, but wt. % of all saturated fatty acids to the OC content from beef and pork charbroiling is 2.727 and 2.022, and the wt% of all unsaturated fatty acids to the OC content is 0.278 and 0.438, respectively. Content of total PAH compounds to the OC content from beef charbroiling is higher than that from pork charbroiling, and those are 0.116 wt% and 0.044 wt%. Among PAH compounds benzo(a)pyrene as a single compound is account for 0.0071 wt% and 0.0023 wt% of OC content from beef and pork charbroiling. Ratios of marker compound to cholesterol are calculated, and those values are in good agreement with the values already reported at the food cooking emission, indicating that they can be used as organic source profiles for the apportionment of organic aerosol.

A Study on Greenhouse Gas Inventories for Regional Governments (A Case Study of Jeonbuk Province) (지자체 온실가스 인벤토리 구축연구 - 전라북도 사례)

  • Jang, Nam-Jung
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.565-572
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    • 2009
  • Greenhouse gas(GHG) inventories and basic strategies for Jeonbuk regional government were established to reduce greenhouse gas emissions. The method to construct GHG inventories of Jeonbuk followed the 'Revised IPCC 1996 Guidelines'which was used for the 'Third National Communication of the Republic of Korea under UNFCCC'. Korean government could use primary energy consumption for the energy industries section in the national GHG inventories. However, regional governments should use secondary energy consumption (included electricity consumption) for the energy industries section for their GHG inventories because they could not control the emission of energy transformation section. In the result of Jeonbuk GHG inventories in 2006, carbon dioxide($CO_2$) emissions from fuel combustion covered 87.1% of total emissions. Methane($CH_4$), carbon dioxide($CO_2$) from other sections, nitrous oxide($N_2O$) and F-gas(HFCs, PFCs, $SF_6$) accounted for 8.1, 2.2, 1.6 and 1.0% of total emissions, respectively. The sectional emission decreased in the order of the energy(88.0%), agriculture(7.6%), waste(2.3%) and industrial processes(2.1%) section. The energy industries section that contained electricity consumption was the most dominant emission source in the energy section. F-gas consumption, rice cultivation and waste incineration were main emission sources in the industrial processes, agriculture and waste section, respectively. In this study, basic directions of each section were established by the results of Jeonbuk GHG inventories in 2006.

Study on the Risk of Flammability & Combustion of Liquid Mixtures such as Alcohols (알코올류 등의 액체 혼합물에 대한 인화 및 연소 위험성에 관한 연구)

  • Koh, Jae-Sun
    • Journal of the Society of Disaster Information
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    • v.15 no.4
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    • pp.634-647
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    • 2019
  • Purpose: Currently, many chemicals are used in industrial and real life, and many substances are used in the form of a single substance, but most of them are used in the form of a mixture, and there is a need for a criterion for judging the danger of these substances. Method: Therefore, this study aims to confirm the risk criteria of the mixture through experimental studies on flammable mixtures in order to secure the effectiveness of the details of the existing Dangerous Goods Safety Management Act angerous Goods Judgment Criteria and to ensure the reliability and reproducibility of the dangerous goods judgment. Result: Experimental results show that alcohol flash point is mixed with water, which is a non-flammable liquid. Similar flash point trends occurred around 60% on an alcohol basis. In addition, in the case of flammable-combustible mixtures, there was little change in flash point if the flash point difference of the two materials was not large, and if the flash point difference of the two materials was low, the flash point tended to increase with the increase of the high flash point material. Conclusion: In the future, the test results may provide reference data on the experimental criteria for the flammable liquids that are cracked at the fire site.

Development of an Optimization Technique of CETOP-D Inlet Flow Factor for Reactor Core Thermal Margin Improvement (원자로심의 열적여유도 증대를 위한CETOP-D의 입구유량인자 최적화 기법 개발)

  • Hong, Sung-Deok;Lim, Jong-Seon;Yoo, Yeon-Jong;Kwon, Jung-Tack;Park, Jong-Ryul
    • Nuclear Engineering and Technology
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    • v.27 no.4
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    • pp.562-570
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    • 1995
  • The recent ABB/CE(Asea Brown Boveri Combustion Engineering) type pressurized oater reactor-s have the on-line monitoring system, i.e., the COLSS(core operating limit supervisory system), to prevent the specified acceptable fuel design limits from being violated during normal operation and anticipated operational occurrences. One of the main functions of COLSS is the on-line monitoring of the DNB(departure from nucleate boiling) overpower margin by calculating the MDNBR(mini-mum DNB ratio) for the measured operating condition at every second. The CETOP-D model, used in the MDNBR calculation of COLSS, is benchmarked conservatively against the TORC mod-el using an inlet flow factor of hot assembly in CETOP-D as an adjustment factor for TORC. In this study, a technique to optimize the CETOP-D inlet flow factor has been developed by elim-inating the excessive conservatism in the ABB/CE's. A correlation is introduced to account for the actual variation of the CETOP-D inlet flow factor within the core operating limits. This technique was applied to the core operating range of the YongGwang Units 3&4 Cycle 1, which results in the increase of 2% in the DNB overpower margin at the normal operating condition, compared with that from the ABB/CE method.

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A Numerical Study on the Generation and Propagation of Intake Noise in the Reciprocating Engine (엔진 흡기계의 소음발생 및 전파에 관한 수치연구)

  • 김용석;이덕주
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1996.10a
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    • pp.65-70
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    • 1996
  • 엔진소음을 소음특성에 따라 분류하면 공력소음(Aerodynamic Noise), 연소소음(Combustion Noise), 기계적인 소음(Mechanical Noise)으로 나눌 수 있으며 소음원의 종류에 따라 분류하면 배기계소음(Exhaust System Noise)으로 나눌 수 있으며 소음원의 종류에 따라 분류하면 배기계소음(Exhaust System Noise), 흡기계소음(Intake System Noise), 냉각계소음(Cooling System Noise), 엔진표면소음(Engine System Noise)등으로 분류할 수 있다. 이러한 여러소음중 엔진 내부의 유동에 의한 흡배기계통으로의 소음방출은 자동차 실 내외 소음의 중요한 문제로 대두되는데, 이를 줄이기 위해 그 동안 소음기 등의 서브시스템의 형태와 그 위치조정에 관한 연구가 수행되어 왔다. 그러나 이것이 비용 또는 성능에 영향을 미치므로 본질적인 소음원을 규명해 내는 것이 필요하게 되었다. 흡배기계의 소음은 엔진의 흡입, 배기행 정시 피스톤의 운동에 의해 팽창 및 압축파 형태의 압력파(pressure wave)로 발생하게 되고, 밸브근방에서는 유동의 박리(separation)에 의해 발생하게 된다. 소음기 등의 서브시스템에서도 유동의 박리에 의해 발생하게 되며 특히 배기행정시 발생하는 압력파는 비선형영역에 있게된다. 흡기소음은 배기에 비해 그 크기가 작아서 그동안 등한시 되어왔으나 이것이 소비자의 불평요인으로 작용하므로써 이에 대한 연구도 활발히 수행되어야 한다. Bender, Bramer[1]는 흡배기계 소음의 외부 방사에 관하여 전반적으로 기술하였고 Sierens등[2]은 흡기계에서 1차원 MOC(Method of Characteristics)방법으로 비정상 유동해석을 하고 실험결과와 비교하였다. J.S.Lamancusa 등[3]은 흡기 소음원을 실험을 통해 예측하였고, 흡기소음도 비선형 거동을 보인다고 밝혔다. Yositaka Nishio 등[4]은 새로운 흡기실험장치를 고안하여 공명기(resonator)의 위치 변화에 의한 저소음 흡기계를 설계 초기단계에서부터 적용하려 하였다. 일반적으로 흡배기계의 복잡한 형상 때문에 대부분 실험을 통해 문제를 해결하려 하였고, 수치해석은 피스톤의 운동을 배제한 단순화한 흡배기계의 정상상태 유동해석이 주를 이루어왔다. Taghaui and Dupont 등[5]은 KIVA코드를 사용하여 흡기포트와 연소실 그리고 밸브의 움직임을 동시에 고려한 수치해석을 도입하였다. 하지만 이들이 밸브의 운동을 고려하기 위해 사용한 이동격자는 격자점은 시간에 따라 변화하지만 그 격자의 수가 일정하게 유지되어 있어서 밸브의 완전개폐를 해석할 수가 없다. 강희정[6]은 단일 실린더와 단일 배기밸브를 갖는 문제로 단순화하여 피스톤과 밸브의 움직임을 고려하므로써 배기행정 후 소음이 어떻게 전파해 나가는가를 연구하였다. 본 연구에서도 최소밸브간격과 최대밸브간격 사이에서만 계산이 가능하나 흡기의 경우는 밸브가 닫힐 때 생기는 압력파가 중요하므로 실린더와 밸브사이에 벽면조건을 주어 밸브의 개폐를 모사하였다.

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Effects of Drying Method on N-Nitrosamine Formation in Squid during Its Drying (오징어의 건조방법이 N-Nitrosamine의 생성에 미치는 영향)

  • 성낙주;이수정;신정혜;김정균
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.4
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    • pp.614-619
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    • 1997
  • To examine effects of drying methods on the formation of N-nitrosamine(NA) in squid during its drying. Three different types of dried products, which were made by sun, hot-air and traditional drying of squid after removal of intestines, were utilized. NA was analyzed by a gas chromatography-thermal energy analyzer. The contents of nitrate and nitrite nitrogen in dried products were in the range of 0 to 5.2mg/kg and 0 to 2.7mg/kg, respectively. The contents of TMAO and betain nitrogen in squid during its drying decreased, while those of TMA and DMA nitrogen increased. The contents in dried products were 27.8~29.2mg% and 10.4~12.3mg/kg, respectively. N-Nitrosodimethylamine (NDMA) was only detected in squid during its drying, recovery from raw sample and its dried pro- ducts spiked with 10$\mu\textrm{g}$/kg for NDPA was 81.0~ 100.0%. NDMA in raw samples was found to be below 0.05$\mu\textrm{g}$/kg. The levels of NDMA in squid increased remarkably during its drying and those in dried products were ranged from 2.7 to 42.7$\mu\textrm{g}$/kg. The effects of drying methods in squid were found to be quite different. the levels of NDMA in traditionally dried products were 11~16 and 3~4 times higher than those in sun dried and hot-air dried products, respectively It is believed that high levels of NDMA were detected in traditionally dried products because NDMA was formed from reaction between various amines and nitrogen oxide produced by combustion of briquet during drying of squid.

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A Study of Estimation of Greenhouse Gas Emission and Reduction by Municipal Solid Waste (MSW) Management (D시 생활폐기물 관리 방법과 온실가스 배출량과 감축량 산정 연구)

  • Yun, Hyunmyeong;Chang, Yun;Jang, Yong-Chul
    • Journal of Korea Society of Waste Management
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    • v.35 no.7
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    • pp.606-615
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    • 2018
  • Over the past two decades, the options for solid waste management have been changing from land disposal to recycling, waste-to-energy, and incineration due to growing attention for resource and energy recovery. In addition, the reduction of greenhouse gas (GHG) emission has become an issue of concern in the waste sector because such gases often released into the atmosphere during the waste management processes (e.g., biodegradation in landfills and combustion by incineration) can contribute to climate change. In this study, the emission and reduction rates of GHGs by the municipal solid waste (MSW) management options in D city have been studied for the years 1996-2016. The emissions and reduction rates were calculated according to the Intergovernmental Panel on Climate Change guidelines and the EU Prognos method, respectively. A dramatic decrease in the waste landfilled was observed between 1996 and 2004, after which its amount has been relatively constant. Waste recycling and incineration have been increased over the decades, leading to a peak in the GHG emissions from landfills of approximately $63,323tCO_2\;eq/yr$ in 2005, while the lowest value of $35,962tCO_2\;eq/yr$ was observed in 2016. In 2016, the estimated emission rate of GHGs from incineration was $59,199tCO_2\;eq/yr$. The reduction rate by material recycling was the highest ($-164,487tCO_2\;eq/yr$) in 2016, followed by the rates by heat recovery with incineration ($-59,242tCO_2\;eq/yr$) and landfill gas recovery ($-23,922tCO_2\;eq/yr$). Moreover, the cumulative GHG reduction rate between 1996 and 2016 was $-3.46MtCO_2\;eq$, implying a very positive impact on future $CO_2$ reduction achieved by waste recycling as well as heat recovery of incineration and landfill gas recovery. This study clearly demonstrates that improved MSW management systems are positive for GHGs reduction and energy savings. These results could help the waste management decision-makers supporting the MSW recycling and energy recovery policies as well as the climate change mitigation efforts at local government level.

Measuring the Non-market Value of the Introduction of Electric Vehicles to National Parks Against Climate Change (기후변화의 대응수단으로서 국립공원 내 전기자동차 도입의 비시장적 가치 추정에 관한 탐색적 연구)

  • Kim, Sang-Tae;Min, Woong-Ki;Kim, Nam-Jo
    • Review of Culture and Economy
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    • v.17 no.2
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    • pp.81-102
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    • 2014
  • As carbon dioxide, the main greenhouse gas, is generally emitted by vehicles, the development and distribution of electric cars is important for the sustainability of environmentally-friendly tourism, especially in national parks. National parks in Korea, however, still see the use of traditional vehicles powered by internal combustion engines in the handling of visitors and the transportation of goods and staff. Such engines being the cause of environmental problems such as exhaust emission and noise pollution, the introduction of electric cars in national parks is needed. This study aims to analyze the economic value of electric cars in national parks as well as contribute to the development of the Green Transportation model in tourism destinations. The study used a logit model to estimate the willingness to pay for the introduction of electric cars in national parks. Adults over the age of twenty, with gender and age apportioned equally, were surveyed using questionnaires that included dichotomous as well as demographic questions. The findings show that the amount an individual is willing to pay for the purpose of environmental conservation is 3,948 won, while the value the national parks would derive from the use of electric cars is 56,138,130,000 won. The introduction of electric cars in national parks is expected to offer both direct and indirect benefits while helping to improving the environment of the national parks by eliminating exhaust emission and noise. This introduction would also be a response to climate change that can be taken by society as a whole.

Ag-Loaded LaSrCoFeO3 Perovskite Nano-Fibrous Web for Effective Soot Oxidation (Ag 담지된 LaSrCoFeO3 섬유상 perovskite 촉매의 탄소 입자상 물질의 산화반응)

  • Lee, Chanmin;Jeon, Yukwon;Hwang, Ho Jung;Ji, Yunseong;Kwon, Ohchan;Jeon, Ok Sung;Shul, Yong-Gun
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.584-588
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    • 2019
  • The catalytic combustion of particulate matter (PM) is one of the key technologies to meet emission standards of diesel engine system. Therefore, we herein suggest Ag loaded $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ perovskite web catalyst. They were produced by the electrospinning method. FE-SEM, EDS mapping, XRD, XPS were studied to investigate the crystal and morphological structures of loaded Ag particles and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ perovskite web catalyst. Following the catalytic soot oxidation, we found that the Ag loaded $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ perovskiteweb catalyst showed the higher catalytic activities (e.g., $T_{50}=490^{\circ}C$) than the only $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ perovskite web catalyst (e.g., $T_{50}=586^{\circ}C$). Thus, this finding suggests that Ag loaded $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ perovskite web catalyst can be a promising candidate for enhancing the soot oxidation.

A Study on the Uniform Mixing of Ammonia-Air with the Change of Ammonia Supply Device Shape in a De-NOx System (탈질설비에서 암모니아 혼합기의 형상에 따른 암모니아-공기 균일 혼합에 관한 연구)

  • Ha, Ji Soo
    • Journal of the Korean Institute of Gas
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    • v.23 no.3
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    • pp.20-26
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    • 2019
  • Selective catalytic reduction(SCR) method is widely used among various methods for reducing nitrogen oxides in combustion devices of coal power plant. In the present study, the computational fluid dynamic analysis was accomplished to derive the optimal shape of ammonia-dilution air mixing device in a ammonia injection grid. The distribution characteristics of flow and $NH_3$ concentration had been elucidated for the reference shape of ammonia mixing device(Case 1). In the mixing device of Case 1, it could be seen that $NH_3$ distribution was shifted to the wall opposite to the inlet of the ammonia injection pipe. For the improvement of $NH_3$ distribution, the case(Case 2) with closing one upper injection hole and 4 side injection holes, the case(Case 3) with installing horizontal plate at the upper of ammonia injection pipe, the case(Case 4) with installing horizontal plate and horizontal arc plate at he upper of ammonia injection pipe were investigated by analyzing flow and $NH_3$ concentration distributions. From the present study, it was found that the % RMS of $NH_3$ for Case 4 was 4.92%, which was the smallest value among four cases, and the range of $R_{NH3}$ also has the optimally uniform distribution, -10.82~8.34%.