• Journal of Energy Engineering
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• v.25 no.4
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• pp.53-61
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• 2016

Unburned Carbon(UBC) and NOx emissions from High-moisture coal and Dried coal were investigated in Drop Tube Furnace(DTF). When the same amount of the High-moisture coal and Dried coal were oxidized in DTF, the results show that UBC and NOx emissions of Dried coal case is higher than High-moisture coal case. As the moisture in coal decreases from 40% to 10%, the average gas temperature increases but the moisture concentration in DTF decreases. As the wall temperature increases from $900^{\circ}C$ to $1500^{\circ}C$, the UBC decreases and NOx emissions increases. Especially, the difference for UBC between High-moisture coal and Dried coal decreases with increasing wall temperature.

• Journal of the Korean Ceramic Society
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• v.45 no.7
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• pp.387-394
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• 2008

The Physical property changes of calcined clay by carburization were investigated studied. The carburization mechanism is the penetration of carbon which occurred during incomplete fuel combustion into crevice of clay structure. The experiments for elasticity and freeze-thaw resistance were conducted, and the results can be summarized as follows: Dynamic modulus of elasticity and also freeze-thaw resistance of calcined clay by carburization treatment increased more than 92% after testing 300 cycle, which was more improved than 88% of calcined clay. Therefore, it can decrease the possibility of winter-sowing, which is one the weakness of calcined clay. It is on the basis of the fact that the porosity of calcined clay by carburization treatment is about 12%, which indicates smaller pore spaces comparing with the 14% of porosity of calcined clay and those values were calculated by apparent porosity show and also supported by SEM images. Infrared emissivity of calcined clay by carburization treatment and calcined clay were respectively 0.92 and 0.9l at $80^{\circ}C$. However, those values were 0.91 and 0.88 at $200^{\circ}C$, which means infrared emissivity of calcined clay by carburization treatment shows 3.6% higher than the calcined clay. Moreover, within the wavelength range from 3 to $7\;{\mu}m$, while the calcined clay had low infrared emissivity, the calcined clay by carburization treatment had increased infrared emissivity. It is inferred that it was affected by carbon element that has high infrared absorptivity within this wavelength range.

• Journal of Hydrogen and New Energy
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• v.27 no.4
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• pp.412-420
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• 2016

Effect of $H_2S$ on reactivity of oxygen carrier was measured and discussed using fluidized bed reactor and SDN70 oxygen carrier. We could get 100% of fuel conversion and $CO_2$ selectivity even though $H_2S$ containing simulated syngas was used as fuel for reduction. Absorbed sulfur was released during oxidation and $N_2$ purge step after oxidation as $SO_2$ form. We could get 100% of fuel conversion and $CO_2$ selectivity during cyclic reduction-oxidation tests up to 10th cycle. However, only 6~7% of sulfur can be removed during oxidation and $N_2$ purge step and 93~94% of sulfur was accumulated in the oxygen carrier. Therefore we could conclude that total removal of sulfur was not possible. $SO_2$ emission during oxidation decreased as the number of cycle increased. Therefore we could expect that the reactivity of oxygen carrier will be decreased with time.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.9
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• pp.829-836
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• 2013

The combustion characteristics with variations in synthetic natural gas (SNG) compositions were studied in a lab-scale combustor. The objective of the current study is to investigate the flame stabilization, flame structure, and spectrometry in a non-premixed SNG flame with varying fuel compositions. For the analysis of light emission in SNG flames, we used a spectrometer. As experimental conditions, the fuel jet velocity at the nozzle exit $u_F$ was varied from 5 to 40 m/s and the coaxial air velocity $u_A$ was varies from 0 to 0.43 m/s. The experiments showed that the flame stability increased with the hydrogen component in SNG.

• Atmosphere
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• v.21 no.3
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• pp.301-309
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• 2011

In this study, we compared light-absorption properties of aerosols observed in East and South Asia from black carbon (BC) mass concentration, aerosol scattering (${\sigma}_s$) and absorption (${\sigma}_a$) coefficients measurements at four sites: Korea Climate Observatory-Gosan (KCO-G), Korea Climate Observatory-Anmyeon (KCO-A), Maldives Climate Observatory-Hanimaadhoo (MCO-H) and Nepal Climate Observatory-Pyramid (NCO-P). No significant seasonal variations of BC mass concentration, ${\sigma}_s$ and ${\sigma}_a$, despite of wet removal of aerosols by precipitation in summer, were observed in East Asia, whereas dramatic changes of light-absorbing aerosol properties were observed in South Asia between dry and wet monsoon periods. Although BC mass concentration in East Asia is generally higher than that observed in South Asia, BC mass concentration at MCO-H during winter dry monsoon is similar to that of East Asia. The observed solar absorption efficiency (${\alpha}$) at 550 nm, where ${\alpha}={\sigma}_a/({\sigma}_s+{\sigma}_a)$, at KCO-G and KCO-A is higher than that in MCO-H due to large portions of BC emission from fossil fuel combustion. Interestingly, ${\alpha}$ at NCO-P is 0.14, which is two times great than that in MCO-H and is about 40% higher than that in East Asia, though BC mass concentration at NCO-P is the lowest among four sites. Consistently, the highest elemental carbon to sulphate ratio is found at NCO-P.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.3
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• pp.42-49
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• 2014

The gasoline direct injection (GDI) system is considerably spreading in automotive market due to its advantages. Nevertheless, since GDI system emit higher particle matter (PM) due to its combustion characteristics, it is difficult to meet strengthened emission regulation in near future. For this reason, a combined GDI with MPI system, so-called, dual injection (DUI) system is being investigated as a supplemental measure for the GDI system. This paper focused on power and fuel consumption effect by injection mode strategy of DUI system in part load and idle engine operating condition. In this study, port fuel injectors are installed on 2.4 liters GDI production engine in order to realize DUI system. And, at each injection mode, DOE (design of experiment) method is used to optimize engine control parameters such as dual injection ratio, start of injection timing, end of injection timing, CAM position and so on. As a consequence, DUI mode shows slightly better or equivalent fuel efficiency compared to conventional GDI engine on 9 points fuel economy mode as well as MPI mode shows less fuel consumption than GDI mode during idle operation. Furthermore, DUI system shows improvement potential of maximum 2.0% fuel consumption and 1.1% performance compared to GDI system in WOT operating condition.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.4
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• pp.1-9
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• 2014

The vast stores of biomass available in the worldwide have the potential to displace significant amounts of petroleum fuels. Fast pyrolysis of biomass is one of several paths by which we can convert biomass to higher value products. The wood pyrolysis oil (WPO) has been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of WPO in a diesel engine requires modifications due to low energy density, high water contents, high acidity, high viscosity, and low cetane number of the WPO. One possible method by which the shortcomings may be circumvented is to co-fire WPO with other petroleum fuels. WPO has poor miscibility with light petroleum fuel oils; the most suitable candidates fuels for direct fuel mixing are methanol or ethanol. Early mixing with methanol or ethanol has the added benefit of significantly improving the storage and handling properties of the WPO. For separate injection co-firing, a WPO-ethanol blended fuel can be fired through diesel pilot injection in a dual-injection dieel engine. In this study, the performance and emission characteristics of a dual-injection diesel engine fuelled with diesel (pilot injection) and WPO-ethanol blend (main injection) were experimentally investigated. Results showed that although stable engine operation was possible with separate injection co-firing, the fuel conversion efficiency was slightly decreased due to high water contents of WPO compare to diesel combustion.

• Journal of Korean Society for Atmospheric Environment
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• v.34 no.1
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• pp.166-176
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• 2018

The n-alkanes which are stable compounds in the atmosphere are emitted by anthropogenic sources and biological sources. The goal of this study is to understand characteristics of n-alkane distributions in $PM_{2.5}$ of the Anmyeon Island which is one of background site in Korea. The concentration of n-alkanes in $PM_{2.5}$ was measured at Anmyeon Island for one year from June 2015 to May 2016. The average concentration of total n-alkanes (${\sum}$ n-alkanes) from C20 to C34 was $14.02{\pm}10.26ng\;m^{-3}$ and ranged from 1.77 to $47.65ng\;m^{-3}$. Various diagnostic parameters were used to identify the source. As a result, it is considered that Anmyeon Island had a large influence of biological sources during non-heating period, while the influence of anthropogenic emission during the heating period was significant. Principle Component Analysis (PCA) was performed and yielded three components that accounted for 93.6% of the total variance in n-alkanes. Factor 1, which accounted for 42.3% of the total variance, indicated anthropogenic source including fossil fuel and biomass combustion, while, Factor 3 was interpreted as the biological sources such as plant wax.

• Transactions of the Korean Society of Automotive Engineers
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• v.9 no.4
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• pp.77-84
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• 2001

Measurements of local CO, $CO_2$, $O_2$, $N_2$, $C_3$H$_{8}$, NOx concentrations and flame temperature are made for partially premixed flame with and without acoustic excitation. The CO, $CO_2$, $O_2$, $N_2$, and $C$_3$H_8$ concentrations are determined by thermal conductivity detection (Gas-chromatograph) and NOx concentrations are determined by chemiluminescent detection (NOx analyser). To measure local sample concentration, sampling probe was made by quartz with inlet diameter of 0.25mm. In the case of excitation, the visual shape of the flame is changed from laminar flame to turbulent-like flame. The flame length is also reduced, and the flame width becomes broad. In the observation of emission concentration without acoustic excitation, meanwhile, the $CO_2$ and NOx concentrations peak at flame front where the mixture meets with surrounding air, and the CO concentration is increasing at maximum position of CO2 concentration and peaks at the centerline of the burner. In the case of acoustic excitation, the $CO_2$ concentration is widely occurred at nozzle of the burner and is higher relative to unexcitation. The CO concentration is much reduced, but NOx concentration is more increasing. And flame temperature is higher relative to unexcitation. These are caused by enhancing of mixing with surrounding air due to excitation. However, in the case of acoustic excitation, the total NOx concentration is reduced because of the shortened flame length which affects residence time.e.

• Transactions of the Korean Society of Automotive Engineers
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• v.25 no.2
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• pp.157-166
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• 2017

The Fuel Cell Electric Vehicle(FCEV) is recently evolving into a new trend in the automobile industry due to its relatively higher efficiency and zero greenhouse gas(GHG) emission in the tailpipe, as compared to that of the conventional internal combustion engine vehicles. However, it is important to analyze the whole process of the hydrogen's life cycle(from extraction of feedstock to vehicle operation) in order to evaluate the environmental impact of introducing FCEV upon recognizing that the hydrogen fuel, which is used in the fuel cell stack, is not directly available from nature, but instead, it should be produced from naturally available resources. Among the various hydrogen production methods, ${\sim}54.1%^{8)}$ of marketed hydrogen in Korea is produced from naphtha cracking process in the petrochemical industry. Therefore, in this study, we performed a well-to-wheels(WTW) analysis on the hydrogen fuel cycle for the FCEV application by using the GREET program from the US Argonne National Laboratory with Korean specific data. As a result, the well-to-tank and well-to-wheel GHG emissions of the FCEV are calculated as 45,638-51,472 g $CO_2eq/GJ$ and 65.0-73.4 g $CO_2eq/km$, respectively