• Resources Recycling
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• v.27 no.3
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• pp.93-99
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• 2018

Effective extraction of platinum group elements by dissolving waste platinum scrap from the display industry and solvent extraction, was studied. The extracted platinum solution was prepared as a precursor solution for diesel automotive exhaust gas purification catalyst and its catalytic activity was tested. The behavior of aqueous species of platinum was investigated through solution chemistry and based on the existence and behavior of these chemical species, the possibility of extraction and separation was established. By dissolving waste scrap by electrochemical method, the dissolution time of scrap was shortened and the extraction efficiency was increased. Through separation and removal of rhodium component, solvent extraction by TBP, and stripping by hydrochloric acid, Pt-Chloride-$H_2O$ solution was prepared. And then, an platinum amine complex solution through amination reaction with this solution as a raw material was prepared. The possibility of producing high-value platinum compounds from platinum group waste scrap was investigated by preparing platinum amine complex solution and then examining the catalytic activity with this amine precursor on the combustion reaction of carbon black.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2008.04a
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• pp.131-134
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• 2008

In this study, the lower detonation limits(LDL) and the upper detonation limits(UDL) of the flammable substances predicted with the appropriate use of the heat of combustion and the stoichiometric coefficient. The values calculated by the proposed equations were a good agreement with literature data within a few percent. From a given results, It is to be hoped that this methodology will contribute to the estimation of the detonation limits of for other flammable substances.

• Fire Science and Engineering
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• v.26 no.3
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• pp.40-48
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• 2012

Fire patterns have been used to determine the origin and cause of fires in every setting imaginable. However, it is very difficult to identify fire patterns and causes from the fire-damaged remains of a devastated structure. If someone was killed by the fire, it is possible to identify fire patterns by analyzing the Hb-CO concentration in charred bodies of deceased as well as the pace of the fire. For example, a low level of Hb-CO concentration in the charred bodies indicate a rapid fire with accelerants and the death was caused by severe heat and thick toxic fumes. However, a high level of Hb-CO concentration in the charred bodies demonstrates that the fire was slow and/or there was a flameless form of combustion. Thus, it is possible to identify fire patterns through analyzing the level of Hb-CO concentration on the dead from the fire. In this study, the Hb-CO concentration in the charred bodies was from 3 % at the case of gas burning oneself to death to 93 % at the death caused by smoldering fire.

• Transactions of the Korean Society of Automotive Engineers
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• v.9 no.4
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• pp.77-84
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• 2001

Measurements of local CO, $CO_2$, $O_2$, $N_2$, $C_3$H$_{8}$, NOx concentrations and flame temperature are made for partially premixed flame with and without acoustic excitation. The CO, $CO_2$, $O_2$, $N_2$, and $C$_3$H_8$ concentrations are determined by thermal conductivity detection (Gas-chromatograph) and NOx concentrations are determined by chemiluminescent detection (NOx analyser). To measure local sample concentration, sampling probe was made by quartz with inlet diameter of 0.25mm. In the case of excitation, the visual shape of the flame is changed from laminar flame to turbulent-like flame. The flame length is also reduced, and the flame width becomes broad. In the observation of emission concentration without acoustic excitation, meanwhile, the $CO_2$ and NOx concentrations peak at flame front where the mixture meets with surrounding air, and the CO concentration is increasing at maximum position of CO2 concentration and peaks at the centerline of the burner. In the case of acoustic excitation, the $CO_2$ concentration is widely occurred at nozzle of the burner and is higher relative to unexcitation. The CO concentration is much reduced, but NOx concentration is more increasing. And flame temperature is higher relative to unexcitation. These are caused by enhancing of mixing with surrounding air due to excitation. However, in the case of acoustic excitation, the total NOx concentration is reduced because of the shortened flame length which affects residence time.e.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.121.2-121.2
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• 2011

석탄가스화복합발전과 연계하여 사용할 수 있는 $CO_2$분리법으로 연소 전 탈탄소화는 연료가 연소되기 전에 $CO_2$를 회수하는 방법으로 현재 여러가지 분리법이 사용되고 있다. 본 연구에서는 가스 하이드레이트의 다양한 응용 분야 중 이산화탄소 격리분야에서 합성가스로부터 $CO_2$롤 효과적으로 분리/회수하기 위하여 가스 고형화법에 관한 연구를 진행하였다. 가스 하이드레이트 형성과정에서의 반응 특성을 살펴보기 위하여 순수계와 촉진제 첨가계(TBAB, TBAF, THF)에 대하여 반응시간에 따른 가스소모량 및 기상의 $CO_2$ 조성 변화를 측정하였다. 그 결과 하이드레이트 상에 고농도의 $CO_2$가 포집되는 것을 확인 할 수 있었다. 순수계와 THF 첨가계의 경우 가스 소모량이 다른 계에 비하여 높게 나타났다. 이는 순수계의 경우 구조-I의 큰 동공과 작은 동공에 모두 기체가 점유되기 때문이며, THF 첨가계의 경우 구조-II의 큰 동공에만 기체가 점유되지만 THF의 첨가로 인해 전환율이 증가되기 때문이다. 반면, TBAF와 TBAB 첨가계의 경우에는 상재적으로 낮은 가스 소모량을 보였다. 기체 소모량이 큰 경우 최종 기상의 $CO_2$ 조성이 낮게 나타났다. 그리고 모든 실험조건에서 1시간 이내에 하이드레이트 형성반응이 종결되는 것을 확인할 수 있었다. 또한, 촉진제 첨가에 의한 하이드레이트의 구조적인 변화를 확인하기 위하여 Raman 분광법과 $^1H$-NMR을 이용하여 혼합가스 하이드레이트를 분석하였다. 본 실험으로 얻어진 결과는 가스 고형화법을 이용한 합성가스 분리 공정 설계 및 개발에 중요한 기초자료가 될 것으로 사료된다.

• Fire Science and Engineering
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• v.30 no.3
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• pp.48-54
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• 2016

Pilotis are support columns that lift a building above the ground. Thus, they can elevate the lowest floor to the secondfloor level and, in Korea, are used to leav a parking area below multifamily housing. However, if there is a fire in the piloti area, the cars and main entrance door are wrapped in flames. Due to the inflammability of the materials, the combustion of the cars and insulation at the ceiling of the pilotis, having a high heat release rate, can quickly destroy the front entrance of the building and spread heat, flames and a poisonous gas to the stairs and elevator pit. Therefore, the fire can quickly spread to the whole building, putting the lives of the residents in danger. This study was an in-depth accidental case study of the "Uijeongbu Fire Accident" that killed 5 residents and injured 139 others. The study identified the relationships between the fire at the piloti structure of multifamily housing and the vulnerability of this structure and its inherent weaknesses.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.34 no.1
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• pp.65-73
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• 2006

The high temperature occurs due to the combustion gas from engine in unmanned aerial vehicles (UAV). The high temperature may cause serious damages in UAV structure. The Functionally Graded Material (FGM) is chosen as a candidate material of the engine duct structure. A functionally graded material (FGM) is a two- component mixture composed by compositional gradient materials from one material to the other. In contrast, traditional composite materials are homogeneous mixtures, and involve compositions between the desirable properties of the component materials. Since significant proportions of an FGM contain the pure form of each material, the need for compromise is eliminated. The properties of both components can be fully utilized. Thermal stress analysis of FGM layers (20, 40, 60, 80 and 100) is performed in this paper. In addition, the creep behavior of FGM applied in duct structure of an engine is analyzed for better understanding of FGM characteristics.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.6
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• pp.539-546
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• 2002

The physicochemical properties of solid wastes generated from seven highway service areas, four branch offices, and one construction site were analyzed in concert with air pollutants including heavy metals emitted from near-by small-scale incinerators. The amount of solid wastes generated from highway areas has been increasing with recent increases in the number of highways and passengers. Twelve incinerators examined in this study generally had capacity smaller than 100 kg/hr, most of which were equipped with cyclone for dust removal. It was seen that the concentrations of the gas-phase air pollutants (e.g., SO$_2$, NO$_{x}$, HCl and H$_2$S) were above the acceptable emission standards except one or two sites. CO concentrations at all incinerators were also higher due to incomplete combustion. In addition, particulate matters showed concentration six times higher at their maximum. The results of heavy metal analysis showed that the concentrations of Cu, Cd, and Ni satisfied the emission standards. whereas Pb at one site and Zn at five sites exceeded the standards. Cr measurement results indicated that 9 of 12 incinerators had higher values than the standard; especially one branch office showed nine times higher than normal concentration. In order to satisfy more stringent emission standards in the near future, it is necessary to install air pollution control system and to develop an intensified management plan.n.

• Journal of Energy Engineering
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• v.18 no.4
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• pp.239-246
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• 2009

A fundamental investigation has been conducted on the combustion of single particle of a sub-bituminous coal char burning at different temperatures and residence times. The lab-scale test setup consisted of a drop tube furnace where gas temperatures varied from $900^{\circ}C$ to $1400^{\circ}C$. A calibrated two color pyrometer, mounted on the top of the furnace, provided temperature profiles of luminous particle during a char oxidation. An amount of char mass reacted during the reaction is measured with thermogravimetry analyzer by using an ash tracer method. As a result, mass and area reactivity as well as reaction rate coefficients are determined for the char burning at atmospheric pressure condition.

• Fire Science and Engineering
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• v.19 no.3 s.59
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• pp.58-63
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• 2005

Experimental measurements of flames and the product properties were performed for small kerosene pool fires. which is widely used as a fire source of laboratory scale experiments with scaling modeling. The flame length and flickering frequency were investigated for the flame structures, and compared with the theory. Three measurement methods were introduced to clarify the smoke characteristics, i.e. various gas concentrations, smoke density and thermophoretic sampling with transmission electron microscopy (TEM). The yield of carbon dioxide and the consumption of oxygen were proportional to the heat release rate of pool fires, but there is no trend on carbon monoxide emission. Smoke density of turbulent flames was exponentially increased with the heat release rate. The morphology of the soot particle was investigated to address the degree of soot maturing. The results show that the similar smoke morphology between an inverse jet flame and a pool fire exists despite of different combustion controlling mechanisms.