• Journal of the Korean Chemical Society
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• v.55 no.4
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• pp.650-655
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• 2011

Three new peptide analogs 5a-c were obtained through coupling of 5-Amino benzimidazoles 2a-c with L-phenylalanine. For the purpose ${\alpha}$-amino group was blocked with phthalic anhydride and activation of ${\alpha}$-carboxy group of phenylalanine was carried out by preparing phthaloyl-L-phenylalanyl chloride 4. After developing a successful peptide linkage, the phthaloyl group was removed by treating 5a-c with hydrazine hydrate to get free peptides 6a-c, purified through a column of Amberlite (IR-4B). All of these compounds 2a-c and 5,6a-c have been characterized on the basis of their IR, 1H NMR and EIMS analyses. Antibacterial activity of these compounds is also been reported.

• Journal of the Korean Society of Combustion
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• v.21 no.2
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• pp.29-37
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• 2016

This study described the experimental investigations of combustion instability in a model gas turbine combustor. Strong coupling between pressure oscillations and unsteady heat release excites a self-sustained acoustic wave, which results in a loud and annoyed sound, and may also lead to a structural damage to the combustion system. In this study, in order to examine the combustion instability phenomenon of a dual swirling combustor configuration, the information of heat release and pressure fluctuation period with respect to the variation in both thermal power and combustor length was collected experimentally. As a result, the fundamental acoustic frequency turned out to increase with the increasing thermal power without respect to the combustor length. The frequency response to the combustor length was found to have two distinct regimes. In a higher power regime the frequency significantly decreases with the combustor length, as it is expected from the resonance of gas column. However, in a lower power regime it is almost insensitive to the combustor length. This insensitive response might be a result of the beating phenomenon between the interacting pilot and main flames with different periods.

• Structural Engineering and Mechanics
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• v.85 no.6
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• pp.825-835
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• 2023

The effective buckling length factor is an important parameter in the elastic buckling analysis of steel structures. The present article aims at developing a new method that allows the determination of the buckling factor values for frames. The novelty of the method is that it considers the interaction between the bracing and the elastic supports for asymmetrical frames in particular. The approach consists in isolating a critical column within the frame and evaluating the rotational and translational stiffness of its restraints to obtain the critical buckling load. This can be achieved by introducing, through a dimensionless parameter 𝜙_i, the effects of coupling between the axial loading and bending stiffness of the columns, on the classical stability functions. Subsequently, comparative, and parametric studies conducted on several frames are presented for assessing the influence of geometry, loading, bracing, and support conditions of the frame columns on the value of the effective buckling length factor K. The results show that the formulas recommended by different approaches can give rather inaccurate values of K, especially in the case of asymmetric frames. The expressions used refer solely to local stiffness distributions, and not to the overall behavior of the structure.

• Wind and Structures
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• v.39 no.1
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• pp.71-84
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• 2024

The wind-resistant performance of bridges is generally evaluated based on the strip assumption. For the arch rib of arch bridges, the situation is different due to the curve axis and the variable cross-sectional size. In the construction stage, the arch rib supported by a cable system exhibits flexible dynamic characteristics, and the wind-resistant performance attracts specially attention. To evaluate the wind-induced vibration of an arch rib with the maximum cantilever state, the finite element model was established to compute the structural dynamic characteristics. Then, a three-dimensional (3D) fluid-solid coupling analysis method was realized. After verifying the reliability of the method based on a square column, the wind-induced vibration of the arch rib was computed. The vortex-induced vibration (VIV) performance of the arch rib was focused and the flow field characteristics were discussed to explain the VIV phenomenon. The results show that the arch rib with the maximum cantilever state had the possibility of VIV at high wind speeds but the galloping was not observed. The lock-in wind speeds were larger than the results based on the strip assumption. Due to the vibration of arch rib, the frequency of shedding vortices along the arch axis trended to be uniform.

• Ocean and Polar Research
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• v.33 no.1
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• pp.21-34
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• 2011

We determined potential meso-scale benthic-pelagic ecosystem coupling in the north equatorial Pacific by comparing surface chl-a concentration with sediment bacterial abundance and adenosine triphosphate (ATP) concentration (indication of active biomass). Water and sediment samples were latitudinally collected between 5 and $11^{\circ}N$ along $131.5^{\circ}W$. Physical water properties of this area are characterized with three major currents: North Equatorial Current (NEC), North Equatorial Count Current (NECC), and South Equatorial Current (SEC). The divergence and convergence of the surface water occur at the boundaries where these currents anti-flow. This low latitude area ($5{\sim}7^{\circ}N$) appears to show high pelagic productivity (mean phytoplankton biomass=$1266.0\;mgC\;m^{-2}$) due to the supplement of high nutrients from nutrient-enriched deep-water via vertical mixing. But the high latitude area ($9{\sim}11^{\circ}N$) with the strong stratification exhibits low surface productivity (mean phytoplankton biomass=$603.1\;mgC\;m^{-2}$). Bacterial cell number (BCN) and ATP appeared to be the highest at the superficial layer and reduced with depth of sediment. Latitudinally, sediment BCN from low latitude ($5{\sim}7^{\circ}N$) was $9.8{\times}10^8\;cells\;cm^{-2}$, which appeared to be 3-times higher than that from high latitude ($9{\sim}11^{\circ}N$; $2.9{\times}10^8\;cells\;cm^{-2}$). Furthermore, sedimentary ATP at the low latitude ($56.2\;ng\;cm^{-2}$) appeared to be much higher than that of the high latitude ($3.3\;ng\;cm^{-2}$). According to regression analysis of these data, more than 85% of the spatial variation of benthic microbial biomass was significantly explained by the phytoplankton biomass in surface water. Therefore, the results of this study suggest that benthic productivity in this area is strongly coupled with pelagic productivity.

• Journal of Applied Biological Chemistry
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• v.57 no.4
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• pp.321-324
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• 2014

Fresh and chopped aerial parts of Oryza sativa were extracted in 80% aqueous mehthanol, and the concentrated extract was successively partitioned in n-hexane, ethyl acetate (EtOAc), n-butanol (n-BuOH), and $H_2O$ fractions. From the n-BuOH fraction, two compounds were isolated through repeated silica gel and ODS column chromatography (c.c.). Based on nuclear magnetic resonance (NMR), mass spectrometry and infrared spectroscopy spectroscopic data, the compounds were identified to be adenosine (1) and phlomuroside (2). Especially, the configuration of both the anomer hydroxyl groups was determined as ${\beta}$ from the coupling constants of the anomer protons (J =6.0 and 7.6 Hz) in the $^1H-NMR$ spectra. This is the first report for the isolation of these compounds from Oryza sativa L.

• Smart Structures and Systems
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• v.19 no.2
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• pp.181-194
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• 2017

In order to investigate the interface debonding defects detection mechanism between steel tube and concrete core of concrete-filled steel tubes (CFSTs), multi-physical fields coupling finite element models constituted of a surface mounted Piezoceramic Lead Zirconate Titanate (PZT) actuator, an embedded PZT sensor and a circular cross section of CFST column are established. The stress wave initiation and propagation induced by the PZT actuator under sinusoidal and sweep frequency excitations are simulated with a two dimensional (2D) plain strain analysis and the difference of stress wave fields close to the interface debonding defect and within the cross section of the CFST members without and with debonding defects are compared in time domain. The linearity and stability of the embedded PZT response under sinusoidal signals with different frequencies and amplitudes are validated. The relationship between the amplitudes of stress wave and the measurement distances in a healthy CFST cross section is also studied. Meanwhile, the responses of PZT sensor under both sinusoidal and sweep frequency excitations are compared and the influence of debonding defect depth and length on the output voltage is also illustrated. The results show the output voltage signal amplitude and head wave arriving time are affected significantly by debonding defects. Moreover, the measurement of PZT sensor is sensitive to the initiation of interface debonding defects. Furthermore, wavelet packet analysis on the voltage signal under sweep frequency excitations is carried out and a normalized wavelet packet energy index (NWPEI) is defined to identify the interfacial debonding. The value of NWPEI attenuates with the increase in the dimension of debonding defects. The results help understand the debonding defects detection mechanism for circular CFST members with PZT technique.

• Ocean and Polar Research
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• v.27 no.3
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• pp.341-349
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• 2005

Temporal variation of the natural planktonic community in the Southern Sea of Korea was investigated by using low floating enclosed bags (3.2m deep and 2,500 liter) in order to understand the effect of enriched nitrate on the planktonic community in the spring (March-April) of 2002. Prior to beginning the incubation, the bags were placed in two different concentrations of nitrate, which consisted of control (ambient water) and experimental mesocosms (final concentration of $12{\mu}M$). The nitrate concentration in the experimental mesocosms remained significantly higher than those in control mesocosms throughout the study period (ANOYA, p<0.001). Following the addition of nitrate, abundance and chi-a concentration of phytoplankton peaked on Day 1, when diatoms established the peak in the experimental mesocosms. Diatoms consisted mainly of Thalasxiosira decipiens, Pseudo-nitzschia pungem, Leptocylindrus danicu, Thalassionema nitzschioides, Chaetoceros pseudocrinitus and Actinoptychus senariu. However, the peak did not lead to the difference in abundance and composition of phytoplankton between control and experimental mesocosms during the study period. The dinoflagellates began to increase soon after the diatoms decreased in all mesocosms. Copepods, as a dominant group in the rnosozooplankton community, showed no immediate peak in relation to the nitrate addition, but only their own developmental process from the eggs to adult stage during the study period. The bottom-up control from enriched nitrate via phytoplankton to adult copepods was not distinguished in terms of the abundance of the planktonic community. This might stem from the relatively low nitrate availability of phytoplankton at no N-limited seawater and the weak coupling between rapidly sunken diatoms and copepods through the water column.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.05a
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• pp.135-140
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• 2006

In the experimental study of $N_2$ purge cold flow test of impinging(FOOF) injector for determining of instability region, the whistling sound which has a specific frequency is generated. The frequency of whistling is proportional to the gas flow velocity in part of the oxidizer orifice and due to the coupling of the vibrating gas column and the natural frequency of pipe-orifice shape, the discontinuous jumping phenomena arises. The whistling phenomena have no effect on the combustion instability. Compared the damping factor of 1T1L mode with the hot fire test, the instability region of $N_2$ purge cold flow test is very much like that. It means that flow instability by impinging or mixing of jet is the main reason of combustion instability of impinging injector(FOOF) in the hot firing test.

• Journal of Advanced Navigation Technology
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• v.21 no.6
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• pp.614-619
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• 2017

In this paper, we optimize the wireless power transmission (WPT) coil, and then compare the EM simulation and measurement using magnetic coupling at 6.78 MHz. As transmission efficiency is affected by various factors such as the shape of the system, the size of the coils, the coil structure is proposed to consist of a helical resonant for transmission and a spiral resonant for reception. The size of the coil and the distance between the coils are determined to minimize the volume problem, and the shape of the coil are confirmed by EM simulation. A WPT system is designed with 860mm diameter top plate and cylindrical structure of column spaced 600mm apart, and the characteristics are simulated and measured. The simulation shows that ${\mid}S_{21}{\mid}$ is -0.53 dB with the efficiency of 88%, and the measurement result is that ${\mid}S_{21}{\mid}$ is -0.71 dB with the efficiency of 85%.