• 제목/요약/키워드: Cole-Cole

검색결과 149건 처리시간 0.027초

WO$_3$를 첨가한 SrTiO$_3$ 세라믹스의 전기적 성질에 관한 연구 (Study on the electrical properties WO$_3$-doped SrTiO$_3$ ceramics)

  • 유인규;김효태;변재동;김윤호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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    • pp.9-13
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    • 1995
  • The effect of WO$_3$ addition and sintering condition on the electrical properties of SrTiO$_3$ceramic have been investigated. Resistivity and capacitance of grains and grain boundaries were obtained by applying impedance spectroscopy. From the result it could be concluded that the temperature dependance of capacitance of WO$_3$doped specimens were influenced directly by the variation of grain boundary capacitance. It was also found that the dispersion frequency increased as the degree of reduction of the specimen increased. The dispersion frequency characteristics showed discernably that the resistivity of the specimen varied with WO$_3$ content. The dielectric properties were influenced directly by the reduction of the specimens. The dielectric constant of grain boundaries of BL capacitor could be obtained by Cole-Cole plot and was influeneced by the amount of WO$_3$ added.

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에틸렌-비닐알콜 공중합체와 나일론 블렌드의 유변학 및 형태학 (Rheology and Morphology of Ethylene-Vinyl Alcohol Copolymers/Nylons Blends)

  • 김창기;김병규;정한모;허정도
    • 유변학
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    • 제1권1호
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    • pp.20-28
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    • 1989
  • 비닐 알코올의 함량이 62(EVOH-62) 및 71(EVOH-71) mole%인 에틸렌 비닐알코올 공중합체와 나일론(나일론-6, 나일론-6/12 및 나일론-12)과의 블렌드를 이축압출기에서 제 조하였으며 이들블렌드의 형택학 및 유변학적 성질을 SEM, TEM 및 RDS로 측정하였다. EVOH-61/나일론-6 및 EVOH-7/나일론-6 블렌드는 나일론의 조성이 많은 영역에서는 균 일상을 EVOH 조성이 많은 영역에서는 미세한 상분리(약 0.2$\mu$)를 나타내었다. 한편 EVOH-71/나일론-6/12 및 EVOH-71/나일론-12 블렌드는 상분리가 뚜렸하였으며 EVOH조 성이 많은 영역에서는 피브릴화가 나타났다. 낮은 진동주파수 영역에서 점도 대 조성곡선은 전반적으로 양의 편차를 보였으나 Cole-Cole plot은 나일론-6과의 블렌드가 나일론-6/12나 나일론-12와의 블렌드에 배해 유변학적인 측면에서보다 상용성이 우수함을보였다.

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단백질 알부민 수용액의 광대역 초음파 스펙트로스코피 (Wide-Band Ultrasonic Spectroscopy in Albumin Aqueous Solution)

  • 김정구;배종림
    • 대한방사선기술학회지:방사선기술과학
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    • 제30권2호
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    • pp.161-165
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    • 2007
  • 알부민 수용액(pH 7)에 대한 초음파 흡수 메카니즘을 규명하기 위해 주파수 $0.2{\sim}1,000\;MHz$에 걸쳐 흡수특성측정을 하였다. 관측된 단백질 알부민 수용액의 흡수스펙트럼은 David-Cole함수의 거울상으로 가정한 완화시간의 분포함수와 일치하였다. 이 분포함수는 BSA분자의 수화평형에 의한 것이고 수화평형에 의해 넓은 주파수영역에 걸쳐 완화현상이 일어난다.

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고온인가에 따른 에폭시 복합체의 열화 및 유전특성평가 (Estimation of Degradation and Dielectric Properties for Epoxy Composites doe to Applying High Temperature)

  • 왕종배;이준웅;김재환
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
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    • pp.175-178
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    • 1995
  • Distribution of relaxation time is presented in the Cole-Cole arc diagram with frequency parameter. In the case of estimation of activation energy for main chains, maximum loss frequencies of ${\alpha}$ peaks, f$\sub$m/(${\alpha}$) display curved change according to the WLF type with variations of temperature. Structural change by the filling of filler and degradation by the thermal aging can be estimated from the WLF factors, C$_1$and C$_2$in Log f$\sub$m/-1/T curves which reflect the variations of free volume and thermal expansivity of composites.

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온도에 따른 유기발광소자의 임피던스 분석 (Impedance spectrosocpy depending on temperature in Organic Light-Emitting Diodes)

  • 안준호;정동회;장경욱;송민종;이성일;이준웅;김태완
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.543-546
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    • 2004
  • Bias and frequency-dependent impedance is a technique for the investigation of complex conductivity. At low frequency, complex impedance is dominated by resistive component, and at high frequency by capacitive component. We are going to present the results of the bias and frequency-dependent complex impedance in the device structure of $ITO/Alq_3/Al$ in the temperature range between 10K and 300k. And we will show to change radius of Cole-Cole plot. It will be decrease resistance by temperature. Also equivalent electrical circuit and dielectric relaxation can be accomplished by using the complex impedance analysis.

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초고주파 소자 실장을 위한 유전체를 이용하는 본딩와이어 기생 효과 감소 방법 (Reduction of the bondwire parasitic effect using dielectric materials for microwave device packaging)

  • 김성진;윤상기;이해영
    • 전자공학회논문지D
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    • 제34D권2호
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    • pp.1-9
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    • 1997
  • For the reduction of parasitic inductance and matching of bonding wire in the package of microwave devices, we propose multiple bonding wires buried in a dielectric material of FR-4 composite. This structure is analyzed using the method of moments (MoM) and compared with the common bondwires and ribbon interconnections. The FR-4 composite is modelled by the cole-cole model which can consider the loss and the variation of the permittivity in a frequency. At 20 GHz, the parasitic reactance is reduced by 90%, 80%, 60% compared to those of a single bonding wire in air, double bonding wires in air and ribbon interconnection in air, respectively. Also, the new bondwire shows very good matching of 60.ohm characteristic impedance and has 15dB, 10dB, 5dB improvement of the return loss and 2.5dB, 0.7dB, 0.2dB improvement of the insertion loss compared to the common interconnections. This technique can minimize the parasitic effect of bondwires in microwave device packaging.

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초고주파소자의 저가 플라스틱 실장을 위한 접지된 본딩와이어의 기생특성 해석 (Parasitics analysis of a grounded bondwire for low-cost plastic packaging of microwave devices)

  • 윤상기;이해영
    • 전자공학회논문지D
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    • 제34D권2호
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    • pp.21-26
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    • 1997
  • The dielectric effects on the parasitics of bondwires buried in slightly-lossy dielectric materials hav been investigated over a wide frequency range using the method of moments with incorporation of ohmic and dielectric losses. The FR-4 composite is widely used as a basis material for PCB and plastic packages, because of it sinherent electricl and chemical stbility and low cost. The cole-cole model, which is representative complex permittivity model of epoxy polymers, has been applied to consider the dielectric effects in the MoM calculation. The prasitic impedance of a grounded bondwire in FR-4 composite is greatly increased due to the dielectric loading effect enhanced by the radiation at high frequencies. These calculation results will be helpful for designing and packaging of high-frequency low-cost IC's.

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알킬벤젠술폰산나트륨을 함유하는 폴리프로필렌의 유변학적 성질 및 함유물의 용출 성분 (Rheological Properties of polypropylene Containing Sodium Alkylbenzenesulfonate and the elution Property of the Ingredient)

  • 박승구
    • 유변학
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    • 제3권2호
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    • pp.175-185
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    • 1991
  • Sodium octylbenzenesulfonate(SOBS)와 sodium dodecylbenzenesulfonate(SDBS)를 폴리프로필렌(PP) 용융액에 각각 균일하게 서로 다른 함량으로 섞어 넣은 후에 용융압착법 으로 PP 필름을 제조하였다. 저장 점성도(η') 저장탄성률(G') 및 손실 탄성률(G")을 진 동식 레오미터를 사용하여 170~195$^{\circ}C$에서 측정하였다. 실험온도 범위내에서 첨가제를 함유 한 PP와 순PPrks에 Cole-Cole 플롯(G'에 대한 G"의 log-log 플롯)에는 차이가 없었다. 그러나 광범위한 전단속도에서 SOBS의 첨가량이 8%를 넘어서면서 η'과 G'은 증가하였 다. 이러한 현상은 PP 중에서의 첨가제의 응집효과로 설명되었으며 이것은 SOBS와 SDBS 를 함유하는 PP 필름의 시차 주사열량법 및 주사전자 현미경 관찰결과로 확인되었다. SDBS를 8% 미만 함유하는 PP로부터 섬유의 용융방사가 가능하였으나 SDBS3% 이상 함 유PP 방사섬유는 연신 과정중에 섬유의 절단이 이따금 일어났다. PP 기질내에 있어서의 SDBS의 뜨거운 물에대한 견뢰성을 SDBS와 C. I. Basic blue 41사이의 이온결합 형성 거동 에 바탕을 두어 가시분광법에 의하여 검토하였다.

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Simple Technique for Measurement of Complex Permittivity and Detection of Small Permittivity Change Using Partially Open Cavity

  • Park, Sangbok;Chung, Young-Seek;Cheon, Changyul
    • Journal of Electrical Engineering and Technology
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    • 제9권1호
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    • pp.268-272
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    • 2014
  • This letter presents a measurement methodology of the complex permittivity of liquid using a partially open cavity in narrow band. The partially open cavity (POC) can measure dielectric small changes caused by the temperature variation of the liquid inside the cavity as well. Using the resonance frequency and unloaded quality factor of the proposed POC, the complex permittivity is evaluated. The apertures on the walls of the cavity are designed to circulate the liquid inside to outside of the POC and located at the corner area of the cavity to minimize the disturbance of field distribution at the dominant mode. The results measured by the proposed POC were compared with those by the conventional open-ended probe and Cole-Cole equation. The POC showed better performance in measuring small dielectric constant changes than the open-ended probe.

Rheological properties of branched polycarbonate prepared by an ultrasound-assisted intensive mixer

  • Kim, Hyung-Su;Lee, Hoo-Seok;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제19권1호
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    • pp.1-5
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    • 2007
  • By combining ultrasonic energy which is essential for the chain scission of polymer molecules and a multifunctional agent (MFA) having double bonds at its ends, we were able to modify the molecular structure of polycarbonate (PC) from linear to a branched structure during melt processing. The three double bonds in chain ends of MFA were expected to act as sites for trapping macroradicals of PC during the course of ultrasound-assisted mixing process. The transformation of molecular structure of PC was confirmed by the measurements of rheological properties of the modified PC. After the ultrasonic irradiation of PC together with MFA, increase in complex viscosities and shear-thinning behavior were observed. The Cole-Cole plot and measurement of extensional viscosities revealed the characteristic features of branched structure with well-defined extensional behavior which is comparable to that of a commercial branched PC.