• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2004.10a
• /
• pp.211-214
• /
• 2004

In the present study, the effect of SIDT (Strain Induced Dynamic Transformation) on the microstructure of medium carbon steels was investigated to develop spheroidized annealing-free steel wire rods. When $0.45\%C$ steels were hot-deformed under the conditions of heavy reduction at low temperatures, a microstructure quite different from conventional ferrite-pearlite structure was obtained. It was considered that this ferrite-cementite microstructure was obtained because very small retained austenite grains existing between fine SIDT ferrites prefer to transform to cementite and ferrite instead of pearlite during cooling. Through the present study, $0.45\%C$ steels containing ferrite-cementite (FC) structure instead of ferrite-pearlite structure was obtained in as-rolled state by introducing SIDT. The specimen containing the FC structure was much softer than that containing conventional ferrite-pearlite structure. Therefore, it is concluded that deforming medium carbon steels under the conditions of SIDT is a very powerful method to obtain soft steel wire rods which could be cold-forged without softening heat-treatment

• Proceedings of the KWS Conference
• /
• 2009.11a
• /
• pp.68-68
• /
• 2009

Recently, resistance spot welding using Inverter DC is applied to improve the weldability of high strength steel for the auto-body fabrication. In this study, inverter DC spot welding machine, which is developed in the domestic, was evaluated weldability of the galvanized and cold rolled dual-phase steel(tensile strength : 590MPa). The welding conditions (welding time, current and force) were decided by tensile-shear test, and welding strength and nugget size were analyzed by statistical analysis methods which involved dynamic resistance and indentation. The results of the statistical analysis was utilized for real-time estimation of the invisible nugget size and tensile strength. Moreover, it can be achieved without the conventional destructive testing of welds.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.21 no.2
• /
• pp.151-156
• /
• 1985

In this paper, the plane stress fracture toughness of cold rolled 4.5mm thick SS41 steel plate was investigated for various crack ratios respectively in case of base metal, normalized and annealed heat-treated specimens using the method of J-integral. The specimen geometry used was double edge tension (DET) specimen. The experiments were performed on an Instron machine and all the crack lengths were measured by travelling microscope. The plane stress fracture toughness obtained by the method of Rice equation was J sub(1C)=22.8kgf/mm for the base metal, j sub(1C)-24.7kgf/mm for the normalized specimen and J sub(1C)=26.9 kgf/mm for the annealed. The J-integral computed at the limit load was found unsuitable for fracture toughness determination, because of large variation depending on the crack ratio.

• Journal of Ocean Engineering and Technology
• /
• v.27 no.2
• /
• pp.33-38
• /
• 2013

In the past, a very popular method for reducing the corrosion on zinc involved the use of chemical conversion layer coatings based on $Cr^{+6}$. However, there is an important problem with using chromium salts as a result of restrictive environmental protection legislation. This study investigated the optimum condition for galvanized steel using an organic/inorganic solution with a Ti composition. In the case of a fixed heat treatment time, the corrosion resistance values of LR-0727(1) and LR-0727(2) were improved as the heat treatment temperature increased, and the optimum minimum temperature decreased with the heat treatment time. At the optimum heat treatment condition of two coating solutions, the heat treatment time of the LR-0727(1) solution was shorter than LR-0727(2) for the same heat treatment temperature. LR-0727(1) coated specimens did not show desquamation, and all of the specimens showed a good adhesive property. In contrast, in the case of the LR-0727(2) coated specimens, desquamation arose. Therefore, the adhesive property of LR-0727(1) was superior to that of LR-0727(2). The pencil hardness had a 3H average for all of the coating solutions and heat treatment conditions. In the case of a corrosion resistance test with boiling water, the coated specimens of LR-0727(1) were discolored, but LR-0727(2) was not. Finally, LR-0727(1) was more moisture proof than LR-0727(2).

• Journal of the Korean institute of surface engineering
• /
• v.49 no.2
• /
• pp.202-210
• /
• 2016

This study was intended to investigate the effect of the amount of magnesium addition and heat treatment in the Al-Mg coating film in order to improve corrosion resistance of aluminum coating. Al-Mg alloy films were deposited on cold rolled steel by physical vapor deposition sputtering method. Heat treatment was fulfilled in an nitrogen atmosphere at the temperature of $400^{\circ}C$ for 10 min. The morphology was observed by SEM, component and phase of the deposited films were investigated by using GDLS and XRD, respectively. The corrosion behaviors of Al-Mg films were estimated by exposing salt spray test at 5 wt.% NaCl solution and measuring polarization curves in deaerated 3 wt.% NaCl solution. With the increase of magnesium content, the morphology of the deposited Al-Mg films changed from columnar to featureless structure and particle size was became fine. The x-ray diffraction data for deposited Al-Mg films showed only pure Al peaks. However, Al-Mg alloy peaks such as $Al_3Mg_2$ and $Al_{12}Mg_{17}$ were formed after heat treatment. All the sputtered Al-Mg films obviously showed good corrosion resistance compared with aluminum and zinc films. And corrosion resistance of Al-Mg film was increased after heat treatment.

• Journal of the Korean institute of surface engineering
• /
• v.45 no.3
• /
• pp.106-110
• /
• 2012

Oblique angle deposition (OAD) is a physical vapor deposition where incident vapor flux arrives at non-normal angles. It has been known that tilting the substrate changes the properties of the film, which is thought to be a result of morphological change of the film. In this study, OAD has been applied to prepare single and multilayer TiN films by cathodic arc deposition. TiN films have been deposited on cold-rolled steel sheets and stainless steel sheet. The deposition angle as well as substrate temperature and substrate bias was changed to investigate their effects on the properties of TiN films. TiN films were analyzed by color difference meter, scanning electron microscopy, nanoindenter and x-ray diffraction. The color of TiN films was not much changed according to the deposition conditions. The slanted and zigzag structures were observed from the single and multilayer films. The relation between substrate tilting angle (${\alpha}$) and the growth column angle (${\beta}$) followed the equation of $tan{\alpha}=2tan{\beta}$. The indentation hardness of TiN films deposited by OAD was low compared with the ones prepared at normal angle. However, it has been found that $H^3/E^2$ ratio of 3-layer TiN films prepared at OAD condition was a little higher than the ones prepared at normal angle, which can confirm the robustness of prepared films.

• Journal of Korean Society of Steel Construction
• /
• v.16 no.1 s.68
• /
• pp.33-42
• /
• 2004

Making use of SN steel in the building structure should be a prerequisite to adopt the design strength of said steel. As a preceding study, the material properties of STKN400B/490B tubes and SPAP235/325 and SPAR295 square pipes manufactured using SN400B/490B plates were evaluated. Compared with the yield and ultimate strengths of SN400B/490B plates, those of STKN400B/490B tubes increase. Nonetheless, the yield and ultimate strengths of STKN400B/490B tubes satisfied the design codes of STKN400B/490B tubes even though the tubes were fabricated via roll bending or press forming. On the other hand, the yield and ultimate strengths at the edges of SPAP235/325 square pipes did not satisfy the design codes based on the values at the sides. The maximum tensile and compressive residual stresses at the SN490B tube were equal to and 40% of the yield strength of the SN490B plate, respectively, In the case of the SPAP325 square pipe, both the maximum tensile and compressive residual stresses were 80% of the yield strength of the SN490B plate. The axial compressive loaded column test results snowed that the buckling strengths were not very different regardless of the mode of fabrication of STKN490B tunes. i.e., through roll bending or press forming. On the other hand, the buckling strength of the SPAP325 square pipe was higher than that of the built-up square pipe.

• Korean Chemical Engineering Research
• /
• v.56 no.3
• /
• pp.327-334
• /
• 2018

Water-repellent coating solutions were prepared by sol-gel method using tetraethoxysilane (TEOS) and methyltrimethoxysilane (MTMS) as precursors. The solutions were spin-coated on a cold-rolled steel sheet and thermally cured to prepare a non-fluorine water-repellent coating films. The effects of molar ratios of MTMS/TEOS, water concentration and ammonia concentration on the hydrophobic properties of the coating films were studied. The contact angle of water on coating films prepared by varying the molar ratio of MTMS/TEOS to 1~20 showed a maximum value of $108^{\circ}$ when the MTMS/TEOS molar ratio was 10. With increasing water content, the coating films showed the larger contact angles and the better the water repellency. As the amount of ammonia added was increased, the contact angles of coating films were increased, showing the better the water repellency. It is considered that the larger the amount of ammonia added, the larger the size of the silica particles generated, which increases the surface roughness of the silica particles, thereby increasing the water repellency.

• Proceedings of the Korean Society of Marine Engineers Conference
• /
• 2005.11a
• /
• pp.192-193
• /
• 2005

Magnesium thin films were prepared on cold-rolled steel substrates by RF(Radio Frequency) magnetron sputtering technique.$^{1)}$ The crystal orientation and monitoring of the deposited films were investigated by using XRD(X-ray Diffraction) and EIS(Electrochemical Impedance Spectroscopy), respectively. The corrosion rates of Mg thin films deposited with different argon gas pressure and substrate bias voltage were monitored by AC impedance method under a cyclic wet-dry condition, which was conducted by exposure to alternate conditions of 1h immersion in 3%NaCl solution and 5h drying at 60% RH and 25$^{\circ}C$. The result of corrosion rate of Mg thin films deposited at various Ar gas pressures and substrate bias voltage under wet-dry cyclic exposure in chloride-containing solutions was showed the following conclusions. At the region I during the onset of the wet cycle, corrosion rate showed relatively low value. The increase in the Corrosion rate of region II is due to the increase in the chloride concentration. Corrosion rate of region III during the onset of the cycle zero and salt crystals remain on the metal surface.$^{2)}$

• Journal of Advanced Marine Engineering and Technology
• /
• v.20 no.5
• /
• pp.103-113
• /
• 1996

The properties of the deposited film depend on the deposition condition and these, in turn depend critically on the morphology and crystal orientation of the films. Therefore, it is important to clarify the nucleation occurrence and growth stage of the morphology and orientation of the film affected by deposition parameters, e.g. the gas pressure and bias voltage etc. In this work, magnesium thin flims were prepared on cold-rolled steel substrates by a thermo-eletron activation ion plating technique. The influence of nitrogen gas pressure and substrate bias voltage on their crystal orientation and morphology of the coated films were investigated by scanning electron microscopy (SEM) and X-ray diffraction, respectively. The diffraction peaks of magnesium film became less sharp and broadened with the increase of nitrogen gas pressure. With an increase in nitrogen gas pressure, flim morphology changed from colum nar to granular structure, and surface crystal grain-size decreased. The morphology of films depended not only on gas pressure but also on bias voltage, i.e., the effect of increasing bias voltage was similar to that of decreasing gas pressure. The effect of crystal orientation and morphology of magnesium films on corrosion behaviors was estimated by measuring anodic polarization curves in deaerated 3%NaCl solution. Magnesium, in general, has not a good corrosion resistance in all environments. However, these magnesium films prepared by changing nitrogen gas pressure showed good corrosion resistance. Among the films, magnesium films which exhibited granular structure had the highest corrosion resistance. The above phenomena can be explained by applying the effects of adsorption, occlusion and ion sputter of nitrogen gas.