• Analytical Science and Technology
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• v.33 no.1
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• pp.11-22
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• 2020

When extracting semi-volatile components of herbal medicines using hot water vapor, some substances may react with water vapor or oxygen, and some volatile substances may be lost, when using an organic solvent extraction method has the disadvantage that it may contain a non-volatile material and residual organic solvent. In addition, it is inefficient to separate semi-volatile substances from herbal medicines into each single component and conduct biological activity research for each component to determine the effective ingredient, and some components may be lost in the separation process. In this study, semi-volatile substances evaporated under two pressure-reduced conditions in Chinese herbal medicines such as Cnidii Rhizoma, Aucklandiae Radix and Amomum Fructus were separated by cooling with liquid nitrogen. Those were analyzed by gas chromatography-mass spectrometry (GC-MS) to identify the components, and this method may be used to study biological activities at the cellular level. The substances separated under reduced pressure, essential oil obtained by simultaneous distillation extraction (SDE) method and substances by using solid phase micro-extraction (SPME) from Cnidii Rhizoma, Aucklandiae Radix and Amomum Fructus were analyzed by GC-MS. In the case of Cnidii Rhizoma and Aucklandiae Radix, there were some differences among the essential oil components obtained by SDE and those identified by low temperature capture (CT) and SPME method, these were believed to be produced by some volatiles reacting with water or oxygen at the boiling point temperature of water.

• Journal of the korean society of oceanography
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• v.37 no.1
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• pp.27-34
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• 2002

We measured the alkenone concentration of bulk sediments from a piston core collected from the Ulleung Basin in the East Sea in order to reconstruct past sea surface temperatures (SST). Sediment ages are well constrained by AMS $^{14}C$ dates of the planktonic foraminifera Globigerina bulloides. Coretop alkenone SST calibration with modern surface temperatures and sediment trap dat (Hong et al., 1996) indicate that the SST estimated from alkenones most likely represent the temperatures of late fall. Downcore variations in the alkenone saturation index indicate that between 19 and 15 kyr BP the surface waters were about $3^{\circ}C$ warmer than today. Between 15 and 11 kyr BP, the temperatures were about $3^{\circ}C$ lower than today. A rapid SST increase of about $3^{\circ}C$ occurred at approximately 10 kyr BP. After considering the factors which might influence the SST reconstruction from the $U^{k'}_{37}$ values, we conclude that the alkenone temperature estimates are reliable. The reason for glacial warming in the East Sea is not clear, although there is a possibility that it could be caused by shift in the season of maximum alkenone production from summer during the last glaciation to late fall during the Holocene. Cooling between 15 and 11 kyr BP may be due to inflow of cold water into the East Sea such as via the Oyashio Current or ice-melt water. Warming at the early Holocene could be due to inflow of the Tsushima Current into the East Sea through the Korea Strait.

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.6
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• pp.734-745
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• 2011

In this article, we reviewed the monitoring status of hazardous VOC in ambinet air in Korea and some developed countries such as USA, Japan, and UK. In many countries, two types of VOC monitoring stations are being operated, i.e., for hazardous VOC and photochemical VOC. Each country has different target VOC but all includes benzene. Korea, Japan, and UK have a national ambient air quality standard for benzene, but no national standard has been established in the USA. For sampling of the hazardous VOC, the adsorbent method is adopted in Korea and UK, while the canister method is used in the USA. Both of adsorbent and canister methods are used in Japan. USA and UK have only non-automatic method to measure the hazardous VOC, and the individual samples are being sent to their national laboratories for integrated analysis. On the other hand, Korea and Japan have automatic and nonautomatic methods to measure the hazardous VOC. Local governments or regional environmental agencies in Korea and Japan have the authorization for the sampling and analysis of VOC. According to a field study to evaluate the performance of automatic VOC monitoring system, controlling the moisture in the air sample was identified as the most important problem. However, careful attention must be given to using a moisture removing device such as Nafyon dryer, because of unexpected artifacts formation. In order to have reliable data, it is highly recommended not only to use internal standards, but to use appropriate hydrophobic adsorbents as a cold trap in any automatic on-line VOC monitoring system.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.18 no.6
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• pp.1462-1468
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• 2014

Xe gas is moved to target from GPM. It is used to feasible nuclear reaction from proton of 30MeV cyclotron being investigated by the Xe-124 gas target system. This system is divided into four parts. The hardware system was constructed by solidworks 3-D CAD and Helium supply is to cool the Havor foil. The Cooling water has the job of cooling down the temperature when Xe gas is being investigated in the target. Temperature and pressure gauges are attached to be checked easily. GPM has the part that prepares to transport Xe gas. There are storage vessel that stores Xe gas, the cold trap that filters humidity and impurity and lastly storage vessel that temporarily stores Xe gas. HCS using the helium is to clean and cool for each part. These parts are configured with SIEMENS PLC and PcVue monitoring program for more comfortable and easy maintenance.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2014.05a
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• pp.496-499
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• 2014

Xe Gas is moved to Target from GPM. It is Used to feasible nuclear reaction from proton of 30MeV Cyclotron being investigated by the Xe-124 Gas target System. This system is divided into four parts. Hardware was constructed by solidworks and Helium Supply is to cool the Havor Foil. Water has the job of cooling down the temperature when Xe Gas is being investigated in the target. Temperature and pressure gauges are attached to be checked easily. GPM(Gas Process Manifold) has the part that prepares to transport Xe Gas. There are Storage Vessel that stores Xe Gas, the cold trap that filters humidity and impurity and lastly storage vessel that temporarily stores Xe Gas. HCS(Helium Circulation System) using the Helium to cleaning and cooling. these parts are used to SIEMENS PLC and Pcvue Program. Because It is more comfortable and easy maintenance.