• Title/Summary/Keyword: Coin

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Electrochemical Characteristics of Surface Modified CTP Anode by H3PO4 Treatment (인산 처리된 표면 개질 음극 석탄계 피치의 전기화학적 특성)

  • Lee, Ho Yong;Lee, Jong Dae
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.415-420
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    • 2016
  • To enhance electrochemical performances of anode materials, the surface of coal tar pitch (CTP) was modified by incorporating heteroatoms through chemical treatment with phosphoric acid ($H_3PO_4$). The prepared anode materials with modified CTP was analyzed by XRD, FE-SEM and XPS. The electrochemical performances of modified CTP were investigated by constant current charge/discharge test, rate performance, cyclic voltammetry and impedance tests using the electrolyte of $LiPF_6$ dissolved in the mixed organic solvents (ethylene carbonate : dimethyl carbonate = 1 : 1 vol% + vinylene carbonate 3 wt%). The coin cell using modified CTP ($H_3PO_4/CTP$ = 3 : 100 in weight) has better initial capacity and initial efficiency (489 mAh/g, 82%) than those of other composition coin cells. Also, it was found that the capacity retention was 86% after 30 cycles and the rate capability was 87% at 2 C/0.1 C.

Conservation and Analysis of Goryeo-era Coins in Collection of the National Museum of Korea -Donggukjungbo, Dongguktongbo, Haedongtongbo, Haedongjungbo, Samhanjungbo- (국립중앙박물관 소장 고려시대 동전의 보존과 분석 -동국중보(東國重寶), 동국통보(東國通寶), 해동통보(海東通寶), 해동중보(海東重寶), 삼한중보(三韓重寶)-)

  • Jeon, Hyosoo;Kang, Hyungtae;Ahn, Jooyoung
    • Conservation Science in Museum
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    • v.9
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    • pp.17-29
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    • 2008
  • We conducted preservation treatment for 25 pieces of coins of Goryeo era in collection of the National Museum of Korea. Object coins are 5 kinds of 'Donggukjungbo', 'Dongguktongbo', 'Haedongtongbo', 'Haedongjungbo', 'Samhanjungbo'. As it is worried that if all chlorides able to make bad influence on reclics are removed, letter and chape of coin can be damaged, they were removed partially. To date, inscribed letter form of Dongguktongbo is known as more than 6 types, and as a result of interpreting X-ray photos, 3 types of inscribed letters were identified by this study. Bronze rust acquired in the process of removing rust on coins, origin of materials for coin was assumed through lead isotope ratio analysis. Latest tendency is that diverse scientific analyses are conducted based on bronze rust.

Electrochemical Properties of Carbon/Manganese Oxide Composite Air Cathode for Lithium-Air Batteries (리튬-공기전지용 탄소/망간산화물 복합구조 공기극의 전기화학적 특성)

  • Lee, Sun-Young;Cha, Eun-Hee;Mho, Sun-Il;Ju, Jeh-Beck;Cho, Won-Il
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.198-205
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    • 2012
  • Carbon-supported manganese oxide composite were fabricated as an air cathode material for Li-air batteries by hydrothermal method. The composite materials of carbon and manganese oxide were investigated by the implementation of X-ray diffraction, FE-SEM and BET surface area measurer. The manganese oxide synthesized at $170^{\circ}C$ for 12 h has a rod like shape morphology with 40-50 nm long in size. A Lithium-air battery with coin type, of which electrodes are composed of cathode composite materials synthesized $170^{\circ}C$-12 h and lithium metal anode, reveals its first discharge capacity of 3,852 mAh/g and four discharge-charge cycles.

Fabrication of Li2MnSiO4 Cathode Thin Films by RF Sputtering for Thin Film Li-ion Secondary Batteries and Their Electrochemical Properties (RF 스퍼터법을 이용한 Li2MnSiO4 리튬 이차전지 양극활물질 박막 제조 및 전기화학적 특성)

  • Chae, Suman;Shim, Joongpyo;Sun, Ho-Jung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.7
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    • pp.447-453
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    • 2017
  • In this study, $Li_2MnSiO_4$ cathode material and LiPON solid electrolyte were manufactured into thin films, and the possibility of their use in thin-film batteries was researched. When the RTP treatment was performed after $Li_2MnSiO_4$ cathode thin-film deposition on the SUS substrate by a sputtering method, a ${\beta}-Li_2MnSiO_4$ cathode thin film was successfully manufactured. The LiPON solid electrolyte was prepared by a reactive sputtering method using a $Li_3PO_4$ target and $N_2$ gas, and a homogeneous and flat thin film was deposited on a $Li_2MnSiO_4$ cathode thin film. In order to evaluate the electrochemical properties of the $Li_2MnSiO_4$ cathode thin films, coin cells using only a liquid electrolyte were prepared and the charge/discharge test was conducted. As a result, the amorphous thin film of RTP treated at $600^{\circ}C$ showed the highest initial discharge capacity of about $60{\mu}Ah/cm^2$. In cases of coin cells using liquid/solid double electrolyte, the discharge capacities of the $Li_2MnSiO_4$ cathode thin films were comparable to those without solid LiPON electrolyte. It was revealed that $Li_2MnSiO_4$ cathode thin films with LiPON solid electrolyte were applicable in thin film batteries.

Characterization and preparation titanate nanotubes for Li-ion secondary battery (Li 이차전지용 티타네이트 나노튜브 제조 및 특성평가)

  • Oh, Hyo-Jin;Lee, Nam-Hee;Yoon, Cho-Rong;Jung, Sang-Chul;Kim, Sun-Jae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.510-510
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    • 2007
  • Titanate nanotube(TNT)는 높은 비표면적과 우수한 물리화학적 특성을 가지고 있어 광촉매, 수소 저장재료, 태양전지용 전극재료 등에 적용되고 있다. 또한, 티타네이트 나노튜브는 전자 이동이 원활한 구조적 특징을 가지고 있어 리듐 이차전지용 호스트 재료로서 많은 연구가 진행 중이다. 이에 본 연구에서는 저온균일침전법으로 제조한 루틸상 $TiO_2$ 분말에 Lithium chloride를 1~10wt%를 동시에 첨가한 후 10M의 sodium hydroxide 수용액 내에서 수열합성하여 리튬이 도핑된 티타네이트 나노튜브를 제조하였다. 제조된 분말의 입자형상 및 크기는 전자주사 현미경을 이용하여 관찰하였으며, X-선 회절분석을 이용하여 리튬 첨가에 따른 결정상 변화를 관찰하였다. 또한 리튬이 도핑된 티타네이트 나노튜브의 전기화학적 특성 평가를 위해 양극 활물질 : 도전제 : 바인더를 75 : 20 : 5의 비율로 혼합한 후 coin cell을 제조하였고, potentiostat를 이용하여 용량 측정 및 cycle 특성을 실시하였다. 수열 합성법에 의해 형성된 입자는 직경 10nm, 길이 수 ${\mu}m$로 관찰되었으며, X-선 회절 시험 결과 LiO와 같은 이차상은 발견되지 않았다. 측정된 coin cell의 용량은 240mAh/g을 나타내었으나, 싸이클 특성이 빠르게 저하됨을 확인할 수 있었다.

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Development of Thin Film Electrode by Thermal CVD and Its Anode Characteristics for Lithium Battery (Thermal CVD법을 이용한 박막전극의 개발 및 리튬이차전지의 음극특성)

  • Lee, Young-Ho;Kim, Seong-Il;Doh, Chil-Hoon;Jin, Bong-Soo;Min, Bok-Ki;Kim, Hyun-Soo;Moon, Seong-In;Yun, Mun-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.378-379
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    • 2006
  • The carbon thin film was developed by the CVD method using the carbon source of toluene with the stream of argon gas at $800{\sim}1100^{\circ}C$ for 1 hour. Developed carbon thin films have the material loading of 0.27 mg($800^{\circ}C$), 0.80 mg($900^{\circ}C$), 2.3 mg($1000^{\circ}C$), and 2.9 mg($1100^{\circ}C$) for the disk of 15 mm diameter on single side. The characteristics of carbon thin film as the anode of thin film battery were evaluated using Li|C coin cell. Li|C($1100^{\circ}C$) coin cell has the first specific discharge and charge capacity of 953 mAh/g and 374 mAh/g, respectively, resulting the first Ah efficiency of 39.3 %. Capacity retention of the 5th cycle was 93.2 % indicating good cycleability. The carbon thin film prepared by CVD shows good specific capacity and cycleability, but low Ah efficiency.

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Esophageal Foreign Bodies : Experiences of 235 cases for 12 years (식도이물;12년간 235례의 경험)

  • Choi, Geon;Ko, Tae-Ok;Song, Jong-Seok;Chae, Sung-Won;Jung, Kwang-Yoon;Choi, Jong-Ouck
    • Korean Journal of Bronchoesophagology
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    • v.3 no.1
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    • pp.115-121
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    • 1997
  • We have clinico-statically analysed the 235 cases of esophageal foreign body during the period the past 12 years from March InS to December 1996 at the Department of Otolaryngology-Head and Neck Surgery, Korea University College of Medicine, Guro Hospital. The results were as follow : 1) Coin was the most frequent foreign body in the esophagus(172 cases : 73.2%). Bone was the next frequent foreign body (21 cases 8.8%). 2) In sex distribution, 124 cases(52.8%) of patients were the female and 111 cases(47.2%) were the male, so the sex ratio was 1:1.12. 3) In the age distribution, 134 cases(56.9%) were under 5 years of age, coin was the most frequent materials in this age group(111 cases 47.2%). 4) The most common symptom was vomiting(136 cases : 57.9%). The next common symptom was dysphagia and odynophagia was 41 cases(17.4%) 5) The most prevalent site of lodgement was the first narrowing(181 cases : 77.0%), the third narrowing(31 cases : 13.2%) and the second narrowing of esophagus(23 cases 9.8%) in order. 6) In duration of lodgement, 207 cases(88.1%) were lodged for one day. 7) The foreign bodies of esophagus were removed successfully by esophagoscopic procedure under local or general anesthesia. There were 3 cases of complication, one case of esophageal bleeding and two cases of esophageal rupture.

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Automatic Exposure Control Performance Evaluation of Digital Radiographic Imaging System by Manufacturer Using Coins (동전을 이용한 제조사 별 디지털 방사선 영상 시스템의 자동노출제어 성능 평가)

  • Lim, Se-Hun;Seoung, Youl-Hun
    • Journal of radiological science and technology
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    • v.45 no.1
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    • pp.1-9
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    • 2022
  • In this study, we proposed an image quality control for an automatic exposure control (AEC) of digital radiographic imaging system and tried to analyze the performance of the AEC by various manufacturer. The subjects of the experiment were analyzed for the AEC image quality evaluation using digital radiation generators from four manufacturer such as PHILIPS, GE Healthcare, SAMSUNG Healthcare, DK Medical Solution. We used as materials for the implementation of the image quality evaluation by coins (500 won, KOMSCO, Korea). This study evaluated the performance evaluation of the AEC as image quality and exposure dose (Milliampere-seconds; mAs). The image quality evaluation was tried visual assessment by two radiologic technologists and contrast to noise (CNR) by ImageJ. The exposure dose investigated mAs on digital radiation generators. The radiographic coin images acquired 360 images based on change in the control factors of the AEC, which were kVp, the consistency of field configuration and dominant zone, sensitivity and density. As a result, there was a significant difference in the AEC performance between manufacturer. The CNR by the AEC for each manufacturer showed a difference of up to about 1.9 times. The exposed tube current by the AEC for each manufacturer showed a difference of up to about 5.8 times. It is expected that our proposed evaluation method using coins could be applied as the AEC performance evaluation method in the future.

A Study on the Quantitative Evaluation of Initial Coin Offering (ICO) Using Unstructured Data (비정형 데이터를 이용한 ICO(Initial Coin Offering) 정량적 평가 방법에 대한 연구)

  • Lee, Han Sol;Ahn, Sangho;Kang, Juyoung
    • Smart Media Journal
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    • v.11 no.5
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    • pp.63-74
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    • 2022
  • Initial public offering (IPO) has a legal framework for investor protection, and because there are various quantitative evaluation factors, objective analysis is possible, and various studies have been conducted. In addition, crowdfunding also has several devices to prevent indiscriminate funding as the legal system for investor protection. On the other hand, the blockchain-based cryptocurrency white paper (ICO), which has recently been in the spotlight, has ambiguous legal means and standards to protect investors and lacks quantitative evaluation methods to evaluate ICOs objectively. Therefore, this study collects online-published ICO white papers to detect fraud in ICOs, performs ICO fraud predictions based on BERT, a text embedding technique, and compares them with existing Random Forest machine learning techniques, and shows the possibility on fraud detection. Finally, this study is expected to contribute to the study of ICO fraud detection based on quantitative methods by presenting the possibility of using a quantitative approach using unstructured data to identify frauds in ICOs.

A Study on Blockchain-Based Mass NFT Content Minting

  • Byong-Kwon Lee
    • Journal of the Korea Society of Computer and Information
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    • v.28 no.5
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    • pp.49-56
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    • 2023
  • Currently, e-commerce is changing from a digital twin to a metaverse world. The metaverse world is an intermediate form between virtual and real worlds and is operated as a coin-based meta-commerce. In this meta-commerce world, blockchain-based NFT coins are used when trading items (contents). In this study, we studied how to issue a large number of NFT coins (certification) rather than issuing a single type of NFT. The research method was designed to produce content layer-based and automatically create the desired quantity using a mass NFT index and automatic generation method. In this study, a layer overlap method (background, body, etc.) was used with a Phyton-based program for mass minting. As a result, it can be used as a blockchain-based certificate that can prove a group of many people. In addition, the content created with the NFT index was registered on the NFT sales site to confirm its utilization and value.