• 공업화학
• /
• 제9권1호
• /
• pp.13-19
• /
• 1998

Pyromellitic dianhydride(PMDA)와 methylenedianiline(MDA)을 기본으로 하고 이에 meta-phenylendiamine(MPD), para-phenylendiamine(PPD), 2,4,6-trimethyl-1,3-phenylenediamine(TriMeMPD)을 첨가하여 열적 이미드화법으로 서로 다른 화학적 구조를 갖는 폴리이미드 공중합체막을 합성하여 제조된 막들의 물성치들을 측정하고, 산소와 질소의 투과 특성을 막의 물성과 관련시켜 정성적으로 고찰하였다. PMDA-MDA막을 기준으로 PPD, MPD의 첨가는 막의 밀도를 증가시켰고, 이에 따라 막의 자유용적과 d-spacing 값의 감소를 나타내어 산소, 질소의 투과량을 감소시켰으며, TriMeMPD의 첨가는 반대의 경향을 나타내었다. 따라서 d-spacing값과 자유용적은 질소, 산소의 투과특성과 정성적 상관성을 가짐을 알 수 있었다. 모든 막에서 압력에 상관없이 투과 계수는 거의 일정한 값을 나타내었고, 막의 기체 투과계수가 증가하면 산소/질소의 이상분리인자는 감소하였다. 온도가 증가하면 투과량도 증가하였으며 이상분리인자는 감소하였으며, 질소 투과량의 상승비가 산소보다 더 크게 나타났다.

• 콘크리트학회논문집
• /
• 제19권2호
• /
• pp.163-169
• /
• 2007

본 연구에서는 불포화 폴리에스터수지를 이용하여 적절한 투수성과 압축강도 및 내구성을 갖는 투수 콘크리트를 개발하고자 하였다. 투수 콘크리트 개발을 위해 사용된 재료로는 단입도 굵은골재와 결합재로서 불포화 폴리에스터수지 그리고 채움재로서 탄산칼슘을 이용하였다. 배합 방법은 굵은골재 최대치수, 결합재 비율, F/B 비율 등을 변화시키며 KS 규격에 준하여 각각의 배합에 따른 투수계수, 압축강도를 평가하였다. 그 결과, 투수계수는 약 $3.5{\times}10^{-1}cm/sec$, 공극률은 약 34%, 압축강도는 11 MPa로 나타나, 우수유출저감시설의 기준을 만족하는 것으로 나타났다.

• 한국농공학회논문집
• /
• 제49권4호
• /
• pp.51-59
• /
• 2007

Recently, concrete has been made porous and used for sound absorption, water permeation, vegetation and water purification according to void characteristics. Many studies are carried out on the utilization of sewage sludge, fly ash and waste concrete to reduce the environmental load. This study was performed to evaluate the void, strength, relationship between void and strength, permeability and chemical resistance properties of porous polymer concrete for pavement with different fillers. An unsaturated polyester resin was used as a binder, crushed stone and natural sand were used as an aggregate and bottom ash, fly ash and blast furnace slag were used as fillers. The mix proportions were determined to satisfy the requirement for the permeability coefficient, $1{\times}10^{-2}$ cm/s for general permeable cement concrete pavement in Korea. The void ratios of porous polymer concrete with fillers were in the range of $18{\sim}23%$. The compressive strength and flexural load of porous polymer concrete with fillers were in the range of $19{\sim}22$ MPa and $18{\sim}24$ KN, respectively. The permeability coefficients of porous polymer concrete with fillers were in the range of $5.5{\times}10^{-1}{\sim}9.7{\times}10^{-2}$ cm/s. At the sulfuric acid resistance, the weight reduction ratios of porous polymer concrete immersed during 8-week in 5% $H_{2}SO_{4}$ were in the range of $1.08{\sim}3.56%$.

• 한국농공학회논문집
• /
• 제55권3호
• /
• pp.9-12
• /
• 2013

The pavement is generally used on the highways, local loads, roads for bicycle riding and neighborhood living facility such as parking lot, plaza, park and sports facilities. However, the pavement material that is usually used on the most of roads is impermeable asphalt-concrete and cement-concrete. If the pavement material is impermeable, many problems can be happened on the drainage facilities in the rainy season. Additionally, a lot of rainwater on the pavement surface cannot permeate to the underground and flows to the sewage ditch, stream and river, etc. If a lot of rainwater flows at once, the floods can be out along the streams and rivers. So, underground water can be exhausted. Micro organisms cannot live in the underground. Recently, many studies has been conducted to exploit the permeable concrete that has high performance permeability. However, it is required to develop the permeable concrete which has high strength and durability. In this study, permeable and strength tests were performed to investigate the permeable characteristics of porous concrete according to fine aggregate content and substitution ratio of blast furnace slag. In this test, crushed stones with 10~20 mm and sand with 5~10 mm were used as a coarse aggregate and a fine aggregate respectively. The substitution ratio of blast furnace slag to cement weight is 0 %, 15 %, and 30 %. The ratio of fine aggregate to total aggregate is 0 %, 18 %, and 35 %. As a result, permeability coefficient was decreased according to fine aggregate ratio of total aggregate. Compressive strength was also decreased according to substitution ratio of blast furnace slag.

• 한국막학회:학술대회논문집
• /
• 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
• /
• pp.33-38
• /
• 2004

Molecular modeling of gas permeation through zeolite membranes with/without intercrystalline region was carried out. Molecular dynamics (MD) and Monte Carlo (MC) simulations were performed to estimate the diffusion coefficient and adsorption parameters respectively, and our proposed combined method of molecular simulation techniques with a permeation theory (CMP) was used to estimate gas permeability. The calculated permeability of gases (Ar, He, Ne, $N_2$, $0_2$, $CH_4$) at 301 K for the single crystal membrane model was about one order of magnitude larger than the experiential values, although the dependence on the molecular weight of the permeating species agreed with experiments. On the other hand, the estimated permeability using the diffusivity and adsorption parameters of the intercrystalline region model was in good agreement with the experiments. The consistency between experiments and the estimated values means the importance of considering the intercrystalline region and the validity of CMP method to predict the performance of zeolite membranes.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
• /
• pp.443-448
• /
• 1999

Tests have been carried out on four concrete containing different levels of silica fume to measure their permeability coefficient using water and oxygen, chloride ion. The total cementitious content was 351kg/㎥, and the water/cementitious materials ratio was 0.55. The results show that a dramatic reduction in permeability of concrete containing silica fume occurs due to formation of a discontinuous macro-pore system which inhibits flow. Porosity estimates from mercury-intrusion porosimetry are used to develop an explanations for the water and air permeability reduction. And, results of the rapid permeability test showed that the resistance of concrete to the penetration of chloride ions increases significantly as a contents of silica-fume is increased. The current intensity passing through the concrete containing silica fume is presented from 664C to 2166C.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2001년도 춘계학술대회논문집D
• /
• pp.648-653
• /
• 2001

This study represents the numerical analysis of natural convection of a microenvironments with a air permeability in the clothing air-layer. The clothing air layer of shoulder and arm was used for numerical analysis model. As a numerical analysis method, we adopted a finite volume method for two-dimensional laminar flow, and analyzed the flow and thermal characteristics of velocity, temperature and concentration in the air layer between body and clothing. As a temperature boundary conditions, we considered that a body skin has a high temperature with $34^{\circ}C$ the environmental temperatures are $5,\;15\;and\;25^{\circ}C$ for various permeability coefficients. The distributions of concentration, temperature and velocity were showed that two large cells were. formed at horizontal and vertical air layer, respectively. As the temperature difference between body skin and environment decrease, the heat transfer was decreased rapidly.

• 한국지반환경공학회 논문집
• /
• 제3권3호
• /
• pp.15-25
• /
• 2002

투수계수는 연약점토의 기본 공학 특성 중 하나로서, 투수계수 값은 점토의 압밀과정뿐만 아니라 토양 내 오염물질의 이동에도 관계된다. 일반적으로 압밀이 진행되는 동안 간극비의 감소로 인해 점토의 투수계수 값은 감소하게 된다. Kozeny와 Carman 이후의 많은 연구자들이 다음의 관계로 간극비와 투수계수의 관계를 제안하였다. (1) log e - log k(1+e), (2) e - log k, (3) log e - log k. 본 연구에서는 대표적 국내 해성점토인 김해점토와 군산점토에 대하여 일정변형률(CRS) 압밀시험 수행하였다. 시험결과로부터 위의 관계식들은 군산점토와 김해점토에 모두 적용 가능한 것으로 나타났으며, 김해점토의 경우 경험적 관계식인 $C_k=0.5e_o$를 잘 만족하고 있으나 군산점토의 경우는 그렇지 않은 것으로 나타났다.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2005년도 지반공학 공동 학술발표회
• /
• pp.188-197
• /
• 2005

Square patterned jet grouting technique is the soil improvement method that shakes the special end monitor left and right like as tail fin and mixing the soil and cement paste after cutting the soil in square shape by injecting the cement paste from installed two nozzles. The structure shape by jet grouting technique can be constructed in various shapes and sizes like as square, circle, and sector form designed by an engineer. Also, it can be constructed without waste material and reduced a construction time of work economically. In this study, the applicability of Square Jet Grouting to reduce permeability is estimated by FEM analysis and in-situ test in many cases which are various coefficient of permeability and breadth of grouting structure.

• 한국농공학회논문집
• /
• 제57권6호
• /
• pp.107-115
• /
• 2015

The objective of the this study is to find the breakage index and changes in permeability of Bottom ash from thermoelectric power plants in Korea. Bottom ash was crushed by compaction according to compaction energy from 0 to $1661.4\;kN/m^2$. The particle size distribution was estimated by sieve analysis. The various breakage indexes were used for analyzing the change in particle size distribution and effect of compaction energy. In the result, breakage indexes were increased as compaction energy and initial upper 4.75 mm diameter ratio, but values and tendencies of breakage indexes appeared in different as calculation method of breakage indexes. The coefficient of permeability was decreased with particle breakage, but decreasing ratio of permeability was very small. Bottom ash has a higher permeability than the weathered soil and it is considered high usability as a permeable materials.