• Title/Summary/Keyword: Coefficient of Bonding

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5-Bromo-Ph4-BTPhen Ligand for Selective Removal of Strontium and Cobalt From Water

  • Jang, Jiseon;Harwood, Laurence M.;Cowell, Joe;Afsar, Ashfaq;Lee, Dae Sung
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2018.05a
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    • pp.183-183
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    • 2018
  • In this study, 5-bromo-2,9-bis(5,6-diphenyl-1,2,4-triazin-3-yl)-1,10-phenanthroline (5-bromo-Ph4-BTPhen) was synthesized and evaluated for its ability to remove major radionuclides ($Cs^+$, $Sr^{2+}$, and $Co^{2+}$). The synthesized ligand removed both $Sr^{2+}$ and $Co^{2+}$ from $1mg\;L^{-1}$ aqueous solutions with extraction efficiencies of up to 99% at neutral and alkaline pH. The $Sr^{2+}$ and $Co^{2+}$ removal efficiencies decreased as a consequence of the higher bonding strengths of competing metal ions to the N-donor atoms in the cavity of the ligand; competing divalent ions affected the $Sr^{2+}$ and $Co^{2+}$ removal efficiencies more than monovalent ions.

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Study on the Functionalization of Waste EPDM and PP Blend

  • Chung, Kyungho;Kim, Jinhee
    • Elastomers and Composites
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    • v.50 no.4
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    • pp.245-250
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    • 2015
  • Recycling of ethylene-propylene-diene terpolymer (EPDM) scrap was tried by blending with polypropylene (PP). EPDM scrap powder was prepared by shear pulverization process at high temperature, which may lead to selective chain scission induced by difference in the critical elastic coefficient. On the other hand, EPDM scrap powder was prepared by adding a selected reclaiming agent during shear pulverization process at high temperature. Terpene as a bonding agent was then introduced to improve adhesion property. PP, used as a matrix for manufacturing thermoplastic elastomer, was modified by the incorporation of dicumyl peroxide and maleic anhydride. The functionalized EPDM and modified PP were blended and cured dynamically at $190^{\circ}C$. The blend materials prepared in this study showed the comparable results to those of conventional TPE in terms of tensile and flow properties. Also, the odor component of recycled EPDM was analyzed using GC-MS.

Joining of Ceramic and Metal using Active Metal Brazing (활성금속 브레이징을 사용한 세라믹과 금속의 접합)

  • Kee, Se-Ho;Xu, Zengfeng;Jung, Jae-Pil;Kim, Won-Joong
    • Journal of the Microelectronics and Packaging Society
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    • v.18 no.3
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    • pp.1-7
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    • 2011
  • Active brazing of ceramic to metal is reviewed in this paper. As one of the key aspect in joint techniques, active brazing has been developed to simplify the manufacturing procedure of brazed joints between ceramic and metal. The active filler metal includes Ag-Cu-Ti series, Cu-Ti series, Co-Ti series and so on. The active filler metal which supplies the chemical bonds between ceramic and metal, enhances the wetting of filler metal on ceramic surface and eliminates the need for metallization treatments. The residual stress caused by difference of coefficient of thermal expansion between ceramic and metal, holds a direct influence on the bonding strength and even results in a fracture. Good joints of ceramic to metal promote the miniaturization and simplicity of electronic components with multifunction.

Strength Evaluation of Adhesively Bonded Single-Lap Joints by Ultrasonic Signal Analysis (초음파신호해석을 이용한 단순겹치기 접착이음의 강도평가)

  • Oh Seung-Kyu;Jang Chul-Sub;Han Jun-Young;Lee Won
    • Journal of Welding and Joining
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    • v.22 no.5
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    • pp.32-37
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    • 2004
  • Application of bonding by adhesives can be found in many industries, particularly in advanced technological domains such as aeronautical and space, automobile and electronics industries. Periodic inspection with conventional ultrasonic NDE techniques is capable of indicating the presence and possible location of crack. Continuous ultrasonic attenuation monitoring has potential to supply information. This article discusses the use of pulse-echo ultrasonic testing for the inspection of adhesive bonds between metal sheets. The method is based on the measurement of the reflection coefficient at the metal/adhesive interface. By means of a control experiment it is shown that Quantitative Nondestructive Evaluation in Adhesive Joints are evaluated together with Ultrasonic Testing and Fracture Testing.

The Development and Performance Evaluation of the Air-preheating Heat Exchanger for Ultra-high Temperature Applications (초고온융 공기예열식 열교환기의 개발 및 성능 평가)

  • 박용환
    • Journal of the Korean Society of Safety
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    • v.14 no.4
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    • pp.78-84
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    • 1999
  • A compact air-preheating type heat exchanger was developed and tested for the ultra-high temperature heat recovery applications. For the direct use of exhaust gases up to $1200^{\circ}C$, the heat exchanger adopted a ceramic core with high strength and low thermal expansion coefficient less than $1{\times}10^{-6}^{\circ}C^{-1}$. The ceramic core was fabricated by special extrusion and bonding techniques. To minimize thermal stresses in the core, spring-loaded sealing mechanism was designed and successfully installed. 1-pass air flow scheme was adopted for the compactness and cost-savings. The pressure test for the ceramic core showed no failure under 35 kPa and less than 3% leak under 7 kPa. Flue gas simulation system was developed to investigate the performance of the heat exchanger. The test results showed normal operations of the heat exchanger up to $1200^{\circ}C$ of exhaust gases and relatively high heat recovery efficiencies of 31~39% depending upon exhaust gas temperatures..

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Surface Characterization and Dyeing Property of PET Film Treated with Hydrazine Hydrate in Methanol (Hydrazine/Methanol 처리에 의한 PET film의 표면특성과 염색성)

  • 성우경;조현혹;김경환
    • Textile Coloration and Finishing
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    • v.1 no.1
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    • pp.26-34
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    • 1989
  • The selective chemical degradation or etching of PET based on an organic amine attack on the ester group. The techniques involves the chemical removal of loss ordered amorphous regions or crystalline regions, which are essentially unaffected by the degradative etchant. Thus, most of previous studies have limited to consideration which has been given to structural changes taking place. Therefore, this study was carried out to investigate surface characterization, dyeing properties of PET film hydrazinolyzed with hydrazine hydrate in methanol. PET film was treated with 30% hydrazine hydrate in methanol at $30^\circ{C}$ for various time intervals. The total surface tension of treated PET increased, the dispersion force decreased and the hydrogen bonding force increased. The equilibrium dye adsorption, dyeing rate and apparent diffusion coefficient of acid dyes increased, and the apparent activation energies of diffusion decreased.

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An Experimental Study on the Bond Strength of the Metal Sprayed Coating According to the Shape and Size of the Attachment (어태치먼트의 형상 및 크기가 금속용사 방식피막의 부착강도에 미치는 영향에 관한 실험적 연구)

  • Park, Seungi-Gi;Park, Jin-Ho;Ryu, Hua-Sung;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.109-110
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    • 2016
  • The recent introduction of Metal spraying method apply to construction and civil steel structure is increasing. In applying the metal spraying lining process of construction and civil steel structure to secure the adhesion strength between the metal thermal spray coating and the steel structure and the highest priority requirements are required bond strength test reliable measurement accordingly. In this study, by calculating the deposition intensity and the standard deviation, coefficient of variation corresponding to the bonding area, unlike the shape of the attachment we compared the results.

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Investigation on Adhesive Properties depending on the Environmental Variation of the Steel Plate Adhesive Strengthening Method by the Epoxy Resin (에폭시 수지 접착 강판보강공법의 환경 변화에 따른 부착 특성 검토)

  • Han, Cheon-Goo;Byun, Hang-Yong;Park, Yong-Kyu
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.3
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    • pp.107-113
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    • 2007
  • This study is to investigate adhesive properties depending on the temperature, humidity, and freeze-thraw of the Steel plate adhesive strengthening method by the epoxy resin. The results are summarized as following. For the temperature variation, the debonding failure appear only after 1 cycle of temperature varoation because the coefficient of thermal expansion of the epoxy resin is comparatively large, and the bonding strength is decreased. The deformation properties and ultrasonic pulse velocity on each materials are similar until 4 cycles on the dry and moisture test. As the freeze-thraw test, the epoxy resin is degraded easily subjected to freeze-thaw cycle, comparatively easy, so the debonding failure may occur in short term because of the freeze-thaw repeatition.p

Evaluation of Performance on Repair Materials for Creek Concrete Structures (콘크리트 복개구조물용 보수재료의 성능 평가)

  • Lee, Chang-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.6 no.1
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    • pp.205-212
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    • 2002
  • The deterioration rate of concrete structures in urban area is accelerated due to rapid urbanization and environmental pollution. Repair materials and methods newly introduced in Korea should be investigated whether they are appropriate for the urban environment in Korea. The creek concrete structures are exposed in severe environmental condition than others. Based on these background in mind, the study is focused on evaluation of performance on repair materials used to rehabilitate creek concrete structures. To evaluate the performance of repair materials, four kinds of repair materials were selected based on polymer emulsion. This experimental study was conducted on fundamental performance such as setting time, compressive strength, bending strength, bonding strength, thermal expansion coefficient, and durability performance such as chloride diffusion, carbonation, chemical attack, and steel corrosion rate. On the basis of this study, the optimal repair material which is proper to the environment condition can be selected and service life of creek concrete structures can be extended. As a result, the life cycle cost can be reduced and the waste of material resources will be cut down.

Metal/ceramic Interface Mechanical Property Analysis (금속/세라믹 계면 물성 분석)

  • Kim, Song-Hee;Kang, Hyung-Suk
    • Journal of Industrial Technology
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    • v.24 no.A
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    • pp.9-15
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    • 2004
  • The flexural strength from 3-point bend test and fatigue properties were measured to evaluate mechanical properties of metal/ceramic interface of the multilayer ceramic package produced through tape casting. From the results, the specimens with three electrode layers showed the highest strength. The temperature distribution with time during thermal cycle and thermal stresses with the change of electrode's shape have been estimated by mathematical modelling. Specimen affected by thermal shock, produced microcracks by the difference of thermal expansion coefficient. The results of tensile test and fatigue test showed the rupture at pin. The fact that the pin brazed specimens were always fractured at the pin proved the good bonding condition between pin and electrode.

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