• 제목/요약/키워드: Codoping

검색결과 34건 처리시간 0.02초

The Effects of Codoping of Be and Mg on Incorporation of Mn in GaAs

  • Yu, Fucheng;Gao, Cunxu;Parchinskiy, P.B.;Chandra, Sekar.P.V.;Kim, Do-Jin;Kim, Chang-Soo;Kim, Hyo-Jin;Ihm, Young-Eon
    • 한국재료학회지
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    • 제18권8호
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    • pp.444-449
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    • 2008
  • Samples of GaMnAs, GaMnAs codoped with Be, and GaMnAs simultaneously codoped with Be and Mg were grown via low-temperature molecular beam epitaxy (LT-MBE). Be codoping is shown to take the Ga sites into the lattice efficiently and to increase the conductivity of GaMnAs. Additionally, it shifts the semiconducting behavior of GaMnAs to metallic while the Mn concentration in the GaMnAs solid solution is reduced. However, with simultaneous codoping of GaMnAs with Be and Mg, the Mn concentration increases dramatically several times over that in a GaMnAs sample alone. Mg and Be are shown to eject Mn from the Ga sites to form MnAs and MnGa precipitates.

박막 EL소자의 광방사에 있어서 등전자 불순물의 효과 (EFFECTS OF ISOELECTRONIC IMPURITIES ON THE LIGHT EMISSION OF THE THIN-FILM ELECTROLUMINESCENCT DEVICES)

  • 박연수;곽민기;김현근;손상호;이상윤;이상걸
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 1994년도 추계 학술발표 강연 및 논문 개요집
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    • pp.79-80
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    • 1994
  • A systematic study on isoelectronic impurities in thin-film eletroluminescent devices (TFELD) has been made on the basis of the experimental analysis aimed at a survey for the blue-emitting materials. Codoping effects of isoelectronic impurities, such as oxygen(O), tellurium(Te), and lithium(Li), on the emissive characteristics of ZnS:Ce$^{3+}$ and ZnS:Tm$^{3+}$TFELD have been investigated by means of the X-ray diffraction studies, the Auger electron spectroscopy, the cathodoluminescent spectra, and the electroluminescent spectra. Experiment results reveal that oxygen codoping gives rise to an increase of the luminance, due to a suppression of the nonradiative energy transfer via sulfur vacancies Te codoping in ZnS:Ce$^{3+}$ TFELD result in a large change in the crystal field around Ce$^{3+}$ ions. Li codoping in ZnS:Tm$^{3+}$ TFELD causes the luminance to increase slightly, due to a lowering in the symmetry of Tm$^{3+}$ions. Likewise, the experimental results suggest strongly that an Auger-type enegy loss via lattece defects such an sulfur vacancies acts as a non-emissive in TFELD.ve in TFELD.

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Realization of p-type ZnO Thin Films Using Codoping N and Al by RF Magnetron Sputtering

  • Jin, Hu-Jie;So, Byung-Moon;Park, Bok-Kee;Park, Choon-Bae
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.107-108
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    • 2006
  • ZnO is a promising material for UV or blue LEDs p-Type ZnO thin films which are imperative for the p-n junction of LEDs are difficult to achieve because of strong compensation of intrinsic defects such as zinc interstitial and oxygen vacancy. The method of codoping group three elements and group five elements is effective for the realization of p-type ZnO films. In this study, We codoped N and Al m ZnO thin films by RF magnetron sputtering and annealed the films in sputtering chamber. Some films showed p-type conductivity m Seeback effect measurement.

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Room-temperature Magnetotransport in Degenerately Doped GaAs:(Mn,Be) by Virtue of the Embedded Ferromagnetic Clusters

  • Yu, Fu-Cheng;Kim, Do-Jin;Kim, Hyo-Jin;Ihm, Young-Eon
    • Journal of Magnetics
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    • 제10권3호
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    • pp.103-107
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    • 2005
  • Magnetotransport is a prerequisite to realization of electronic operation of spintronic devices and it would be more useful if realized at room temperature. The effects of Be codoping on GaMnAs on magnetotransport were investigated. Mn flux was varied for growth of precipitated GaMnAs layers under a Be flux for degenerate doping via low-temperature molecular beam epitaxy. Magnetotransport as well as ferromagnetism at room temperature were realized in the precipitated GaAs:(Mn,Be) layers. Codoping of Be was shown to promote formation of MnGa clusters, and annealing process further stabilized the cluster phases. The room-temperature magnetic properties of the layers originate from the ferromagnetic clusters of MnGa and MnAs embedded in GaAs. The degenerately doped metallic GaAs matrix allowed the visualization of the magnetotransport through anomalous Hall effect.

Eu이 이온주입된 undoped와 Mg-doped GaN의 분광 특성 연구 (Optical characterization on undoped and Mg-doped GaN implanted with Eu)

  • 이소원;문주영;이석주
    • 한국진공학회지
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    • 제17권4호
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    • pp.346-352
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    • 2008
  • Eu을 이온주입한 GaN 시료에 대하여 Eu의 site들에 대한 연구와 Mg을 같이 도핑하였을 때의 효과를 분석하였다. 빨간색 광원으로 주목받는 620nm 근처의 Eu의 $^5D_0\;{\rightarrow}\;^7F_2$ 전이에 대하여 photoluminescence (PL) 와 PL 여기 분광법을 이용하여 GaN 내에서 Eu 이온이 자리하는 이미 알려진 2 개의 site 이외에도 2 종류의 site들이 있음을 확인하였다. 이들 중 한 site는 Mg의 codoping에 의하여 PL 크기가 약 1.6배 증가하였다. 이는 GaN의 밴드갭보다 작은 trap에 의해 에너지를 전달받는 Er이나 Nd보다 Mg의 도핑에 의한 효과가 매우 작은 것이다. GaN:Eu에서는 Mg과 관련된 trap을 통하지 않고 GaN에서 직접 Eu으로 에너지를 전달하기 때문으로 생각된다.

Yb3+ Er3+ ions 동시도핑에 의한 TiO2 분말의 열적 안정성 증가효과와 upconversion 특성 연구 (Thermal stabilizing effect of Yb3+ Er3+ codoping into TiO2 powder prepared by sol-gel method and its upconversion characteristic)

  • 은종원;오동근;김광진;홍태의;정성민;최봉근;심광보
    • 한국결정성장학회지
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    • 제20권4호
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    • pp.173-177
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    • 2010
  • Sol-gel method로 합성한 anatase상의 $TiO_2$와 Yb와 Er을 codoping한 $TiO_2:Yb^{3+},\;Er^{3+}$ 파우더의 열적안정성과 이에 따른 광촉매 특성의 변화를 비교하였다. XRD 분석을 통하여 $TiO_2$ 결정성 및 상변화에 $Yb^{3+},\;Er^{3+}$ ions이 미치는 영향을 온도에 따라 비교하였으며 anatase $TiO_2$와 rutile $TiO_2$의 광학적 성질을 UV-Vis을 통하여 비교하였다. UV-Vis 분석결과 anatase $TiO_2:Yb^{3+},\;Er^{3+}$ ions도핑에 의하여 $TiO_2$의 밴드갭이 미세하게 감소함을 확인하였고 이를 통해 광촉매 작용을 향상시킬 수 있음을 확인하였다. $Yb^{3+}$ 이온과 $Er^{3+}$ 이온이 도핑된 $TiO_2:Yb^{3+},\;Er^{3+}$ 파우더를 980 nm에서 PL 분석하여 녹색 및 적색 형광을 하는 up-converting 형광특성을 분석하였다.

Effects of Codoping with Fluorine on the Properties of ZnO Thin Films

  • Heo, Young-Woo;Norton, D.P.
    • 한국세라믹학회지
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    • 제43권11호
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    • pp.738-742
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    • 2006
  • We report on the effects of co-doping with fluorine on properties of ZnO thin films grown by pulsed-laser deposition. The transport characteristics of Ag-F and Li-F codoped ZnO films were determined by Hall-effect measurements at room temperature. Ag-F codoped ZnO films showed n-type semiconducting behaviors. An ambiguous carrier type was observed in Li-F codoped ZnO films grown at a temperature of 500$^{\circ}C$ with the oxygen pressures of 20 and 200 mTorr. The qualities of the codoped ZnO films were studied by X-ray diffraction, atomic force microscopy, X-ray photoemission spectroscopy, and photoluminescence.

The Phase Transition and Thermochromic Characteristics of W/Mg-codoped Monoclinic VO2 Nanoparticle and Its Composite Film

  • Park, Heesun;Kim, Jongmin;Jung, Young Hee;Kim, Yeong Il
    • 대한화학회지
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    • 제61권2호
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    • pp.57-64
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    • 2017
  • Monoclinic $VO_2(M)$ nanoparticles codoped with 1.5 at. % W and 2.9 at. % Mg were synthesized by the hydrothermal treatment and post-thermal transformation method of $V_2O_5-H_2C_2O_4-H_2O$ with $Na_2WO_4$ and $Mg(NO_3)_2$. The composite thin film of the W/Mg-codoped $VO_2(M)$ with a commercial acrylic block copolymer was also prepared on PET substrate by wet-coating method. The reversible phase transition characteristics of the codoped $VO_2(M)$ nanoparticles and the composite film were investigated from DSC, resistivity and Vis-NIR transmittance measurements compared with the undoped and Wdoped $VO_2(M)$ samples. Mg-codoping into W-doped $VO_2(M)$ nanoparticles synergistically enhanced the transition characteristics by increasing the sharpness of transition while the transition temperature ($T_c$) lowered by W-doping was maintained. The codoped composite film showed the prominently enhanced NIR switching efficiency compared to only W-doped $VO_2(M)$ film with a lowered $T_c$.