• Title/Summary/Keyword: Cobalt Zinc

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Effect of Cobalt Oxide Addition on Electrical Properties of Praseodymium-based Zinc Oxide Varistors (프라세오디뮴계 산화아연 바리스터의 전기적 특성에 코발트 산화물 첨가의 영향)

  • Nahm, Choon-Woo;Park, Jong-Ah;Yoo, Dae-Hoon;Suh, Hyoung-Kwon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.10
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    • pp.896-901
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    • 2005
  • The microstructure and electrical properties of praseodymium-based zinc oxide varistors were investigated at various cobalt oxide contents in the range of $0.5{\~}5.0 mol\%$. The ceramic density increased in the range of $5.25{\~}5.55 g/cm^3$ with increasing cobalt oxide content. The varistor doped with cobalt oxide of $1.0 mol\%$ exhibited the highest nonlinearity, with 66.6 in nonlinear exponent and 1.2 $\mu$A in leakage current. The donor concentration, density of interface states, and tamer height were in the range of $(1.06{\~}1.69){\times}10^{18}/cm^3$, $(3.11 {\~}3.56){\times}10^{12}/cm^2$, and 0.80${\~}$1.07 eV, respectively.

Studies on Adhesion Properties between Zinc-Coated Steel Cord and Adhesion Promoter-Containing Rubber Compound (아연 코팅된 스틸코드와 접착증진제가 적용된 고무 Compound와의 접착특성 연구)

  • Ko, Sang Min;Choi, Hee Seok;Son, Woo Jung;Kang, Sin Jung
    • Journal of Adhesion and Interface
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    • v.15 no.2
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    • pp.49-56
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    • 2014
  • In this study, properties of adhesion between adhesion promoter-containing rubber compound and zinc coated steel cord was investigated. Cobalt salt, resorcinol formaldehyde resin (RF resin) and hexamethoxymethylmelamine (HMMM) were used to adhesion promoter. Since cobalt salts accelerate sulphidation rate of zinc at zinc coated steel cord surface, pullout force of rubber compound applying cobalt salts was increased compared to that of rubber compound without applying cobalt salts. Pullout force and rubber coverage of rubber compounds applying all adhesion promoters were superior because strong interlocking between rubber matrix increased modulus due to applying RF resin and HMMM and grown zinc sulfides at zinc coated steel cord surface.

Decomposition Mechanism of Waste Hard Metals using by ZDP (Zinc Decomposition Process) (ZDP(Zinc Decomposition Process)를 이용한 폐 초경합금의 분해기구)

  • Pee, Jae-Hwan;Kim, Yoo-Jin;Sung, Nam-Eui;Hwang, Kwang-Taek;Cho, Woo-Seok;Kim, Kyeong-Ja
    • Journal of the Korean Ceramic Society
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    • v.48 no.2
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    • pp.173-177
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    • 2011
  • Decomposition promoting factors and decomposition mechanism in the zinc decomposition process of waste hard metals which are composed mostly of tungsten carbide and cobalt were evaluated. Zinc volatility amount was suppressed and zinc valatilization pressure was produced in the reaction graphite crucible inside an electric furnace for ZDP. Reaction was done for 2 h at $650^{\circ}C$, which 100 % decomposed the waste hard metals that were over 30 mm thick. As for the separation-decomposition of waste hard metals, zinc melted alloy formed a liquid composed of a mixture of ${\gamma}-{\beta}1$ phase from the cobalt binder layer (reaction interface). The volume of reacted zone was expanded and the waste hard metal layer was decomposed-separated horizontally from the hard metal. Zinc used in the ZDP process was almost completely removed-collected by decantation and volatilization-collection process at $1000^{\circ}C$.

Zinc, Copper and Cobalt Concentrations in Blood During Inflammation of the Mammary Gland in Dairy Cows

  • Naresh, R.;Dwivedi, S.K.;Dey, S.;Swarup, D.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.4
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    • pp.564-566
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    • 2001
  • A study was undertaken to record the utilization of some micro-elements during inflammation of the mammary gland. Two groups of twenty five animals each suffering from subclinical and clinical mastitis were selected for the study. All the animals were maintained on identical diets. Blood zinc level in cows with subclinical mastitis ($5.66{\pm}0.52$) was significantly (p<0.05) lower than that of healthy cows ($8.46{\pm}1.10ppm$). No significant difference was, however, recorded in blood copper and cobalt levels between healthy and mastitic cows.

Effect of Al Addition on the Reaction Behavior of Pure Cobalt with Molten Zinc (용융 아연과 WC-Co 코팅층 내 코발트의 반응거동에 미치는 아연욕 중의 Al 첨가 영향)

  • Seong, Byeong-Geun;Kim, Kyoo-Young;Kwon, Sung-Hee;Lee, Kee-Ahn
    • Journal of the Korean institute of surface engineering
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    • v.40 no.1
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    • pp.23-31
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    • 2007
  • The objective of this study is to investigate the effect of Al addition on the reaction behavior of cobalt with molten zinc. Pure cobalt specimen was immersion tested in the three kinds of molten zinc (pure, 0.12%Al added and 0.24%Al added) baths at $460^{\circ}C,\;490^{\circ}C\;and\;520^{\circ}C$. For the understanding of degradation processes, specimens were analyzed with scanning electron microscope (SEM) and energy dispersive spectrum (EDS), and electrochemical stripping method. When 0.12% and 0.24% Al was added in molten zinc baths, three intermetallic compounds layers of ${\gamma},\;{\gamma}_1,\;and\;{\gamma}_2$ were formed on the Co matrix and ${\beta}_1$ layer was not formed between the Co matrix and the ${\gamma}$ layer. Particles of CoAl intermetallic compound were formed at the interface between the ${\gamma}_2$ layer and zinc melt and they did not adhere to the Co-Zn intermetallic layer. Weight loss of the Co specimen increased as Al content in the molten zinc increased and the relationship of weight loss vs. immersion time followed parabolic rate law. Rate controlling process for the reaction rate of Co with Al added molten zinc was analyzed as the diffusion process of Al atom through a boundary layer between the ${\gamma}_2$ layer and the Al added zinc melt.

Distribution of Heavy Metals in Sediments, Seawater and Oysters (Crassostrea gigas) in the Jinhae Bay (진해만의 퇴적물, 해수 및 참굴 내의 중금속 분포)

  • 이인숙;김은정
    • The Korean Journal of Ecology
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    • v.23 no.1
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    • pp.59-64
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    • 2000
  • Heavy metal concentrations in surface sediments, seawater and oysters (Crassostrea gigas) were determined to assess heavy metal contamination in the Jinhae Bay. The ranges of cadmium, cobalt, copper, nickel, lead and zinc concentration in surface sediments were 0.1∼2.4, 12.6∼14.4, 25.3∼ 92.3, 32.4∼ 93.5, 24. 1∼81.2, 124∼477 ㎍/g, respectively. The concentrations of cadmium, copper, lead and zinc which were influenced by industrial activity were the highest in the inside of Masan Bay. Dissolved concentrations of cadmium, cobalt, copper, nickel, lead and zinc in seawater were <0.010∼0.043, 0.008∼0.120, 0.31∼0.90, 0.25∼3.10, 0.010∼0.142, 0.27∼9.04 ㎍/L, respectively. The concentrations of cadmium, cobalt, copper, nickel, lead and zinc in seawater were also the highest inside of Masan Bay, suggesting that Masan Bay is the major source of heavy metal input to the Jinhae Bay. Bioconcentration factors (BCF) of zinc, copper, cadmium, lead, cobalt and nickel in C. gigas were 647373, 280861, 145069, 44559, 13524, 2745, respectively, showing C gigas is a stronger accumulator than other bivalves.

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Effect of a Copper, Selenium and Cobalt Soluble Glass Bolus Given to Grazing Yaks

  • Liu, Zongping
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.9
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    • pp.1433-1437
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    • 2007
  • Two field trials were carried out to evaluate the performance of a soluble glass copper, cobalt and selenium bolus for maintaining adequate levels of the three trace elements in yaks. Forty yaks were used in trial 1 and 60 yaks were used in trial 2. In each trial two commercial soluble glass boluses were administered to half of the yaks. Blood samples were taken from the jugular vein at day 0, 30, 60, 90 in trial 1 and at day 0, 45, 75 and 105 in trial 2. The samples were analysed for copper status (serum caeruloplasmin activity and copper concentration), cobalt status (serum vitamin $B_{12}$ concentration and cobalt concentration), selenium status (erythrocyte glutathione peroxidase activity and selenium concentration) and serum zinc concentration. The erythrocyte glutathione peroxidase activities, serum caeruloplasmin activities and serum vitamin $B_{12}$ concentrations for trial 1 and 2 were all significantly increased for the bolused yaks (p<0.001 or p<0.01) on all sampling days. The bolused yaks had a significantly higher selenium and copper status in serum than the control yaks on all sampling days in trial 1 and 2 (p<0.05 or p<0.01). There were no significant differences in zinc and cobalt concentrations between the bolused yaks and the controls.

The Effect of Cobalt Oxide Addition on Electrical and Dielectic Stability of Zinc Oxide Varistors (코발트 산화물 첨가가 산화아연 바리스터의 전기적, 유전적 안정성에 미치는 영향)

  • Nahm Choon-Woo;Yoo Dae-Hoon
    • Korean Journal of Materials Research
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    • v.15 no.11
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    • pp.722-729
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    • 2005
  • The electrical and dielectric stability of zinc oxide-based varistors were investigated with the cobalt oxide contents in the range of $0.5\~5.0 mo\l%$. As cobalt oxide contents increased, the ceramic density increased in the range of $5.25\~5.55g/cm^3$ and the varistor voltage decreased in the range of $235.3\~86.0V$. The varistor with on addition of cobalt oxide $1.0 mol\%$ exhibited good nonlinearity. in which the nonlinear exponent is 66.6 and the leakage current is $1.2{\mu}A$. Furthermore, the varistors exhibited the highest electrical and dielectric stability, with $\%{\Delta}V_{1mA}=-1.9\%,\;\%{\Delta}{\alpha}=-10.5\%,\;\%{\Delta}I_L=+275.0\%,\;and\;\%{\Delta}tna{\delta}=+55.6\%$, under DC accelerated aging $0.95V_{1mA}/150^{\circ}C/24h$.

Characterization of the enzymatic property of thermostable carboxypeptidase Taq by addition of metal ions and replacement of active center metal (금속이온 첨가와 활성중심 금속의 치환에 따른 내열성 카르복시펩 티다제 Taq의 효소적 특성 변화에 관한 연구)

  • Lee, Sang-Hyeon;Ha, Jong-Myung;Ha, Bae-Jin
    • Journal of Life Science
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    • v.12 no.6
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    • pp.682-687
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    • 2002
  • We analyzed improvement on the enzyme activity of CPase Taq by addition of various metal ions. The enzyme activity was increased more then four times by 1 mM cobalt ion and almost three times by 1 mM calcium ion. However, the active center metal zinc ion did not affect the enzyme activity. In order to investigate whether the active center metal affects the enzyme activity, zinc ion which is occupied the active center of the enzyme was replaced by cobalt ion which activates the enzyme activity very effectively. Since the cobalt ion in the active center of the cobalt-substituted CPase Taq did not affect the enzyme activity, it could act as the natal metal ion in the active center of the enzyme.

Liquid Phase Deposition of Transition Metal Ferrite Thin Films: Synthesis and Magnetic Properties

  • Caruntu Gabriel;O'Connor Charles J.
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.703-709
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    • 2006
  • We report on the synthesis of highly uniform, single phase zinc and cobalt thin films prepared by the Liquid Phase Deposition (LPD) method. X-Ray diffraction, TGA and EDX measurements support the assumption that the as deposited films are constituted by a mixture of crystallized FeOOH and amorphous M(OH)$_2$ (M=Co, Zn) which is converted upon heat treatment in air at 600?C into the corresponding zinc ferrites. The films with adjustable chemical compositions are identified with a crystal structure as spinel-type and present a spherical or rod-like microstructure, depending on the both the nature and concentration of the divalent transition metal ions. Zinc ferrite thin films present a superparamagnetic behavior above blocking temperatures which decrease with increasing the Zn content and are ferromagnetic at 5 K with coercivities ranging between 797.8 and 948.5 Oe, whereas the cobalt ferrite films are ferromagnetic at room temperature with magnetic characteristics strongly dependent on the chemical composition.