• 한국세라믹학회지
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• 제37권8호
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• pp.781-786
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• 2000

An Er-doped sulfide fiber was drawn, and its spectroscopic properties were analyzed. Compositions of a 1000 ppmwt Er3+-doped core and an undoped clad were Ge30-Ga1-Asg-S61 and Ge30-As8-S62, in at.%, respectively. Refractive index of the core composition was approximately 0.01 high than that of the clad. In order to enhance the mechanical stability as well as to prevent infiltration of impurity ions such as OH-, an UV-curable polymer was used for the coating. The optical loss of a fiber formed directly from a polymer coated core rod without cladding was ∼15 dB/m at 1.06$\mu\textrm{m}$. In the case of a fiber with core/clad structure, the optical loss was so high that the stimulated emission of erbium fluorescence was not evident. It is believed that presence of inhomogeneous core/clad interface and crystalline aggregates precipitated in the clad region were responsible for the high optical loss. On the other hand, fluorescence characteristics of Er3+ embedded in the core region were more or loss deteriorate compared to fiber preform, which is attributed to the redistribution of the Er ions along with the partial crystallization of the core glass during the fiberization process.

• 공업화학
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• 제23권6호
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• pp.554-560
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• 2012

전자 통신 산업이 발달하면서 도전성 재료의 사용이 증가하게 되었다. 그에 따라 주로 사용되어오던 귀금속들을 대신할 저렴한 재료들이 필요하게 되었다. 그 중 구리는 귀금속에 비해 값이 저렴하고, 유사한 열 전기적 특성을 가졌지만 대기 중에서 쉽게 산화가 되는 문제점이 있다. 산화를 방지하기 위해서는 제조공정이 복잡해져 사용에 제한이 되어왔다. 구리의 산화 방지를 위한 방법 중 하나로 산화에 강한 금속을 Core-Shell 구조로 도금시켜 고유의 특성을 유지하며 산화를 방지하는 방법이 있다. 본 연구에서는 무전해 도금법으로 구리분말에 주석(Sn) 도금을 했고, 도금에 영향을 주는 인자들에 대해서 연구했다. XRD, FE-SEM, FIB, 4-Point Probe 등의 분석결과 구리 표면에 치밀한 주석피막이 도금되었고, 대기 중에서 산화가 되지 않았다. 분석결과를 바탕으로 최적의 도금 조건을 도출했고, 추가적으로, 도전성 필러 응용 가능성에 대한 실험을 했다. 합성된 분말을 pellet 형태로 압분 성형한 후 저온 열처리 전과 후의 변화를 분석했다. 그 결과 저온 치밀화를 통해 용융된 주석이 구리 입자들을 상호연결 시켰고, 전기 전도가 향상되었다.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.83-84
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• 2006

In aqueous phase, we directly prepared conducting and photoluminescent nano-structured particles by oxidation polymerization. Thiophene(PT) was initiated by $FeCl_{3}/H_{2}O_{2}$ (catalyst/oxidant) combination system. And, polydispersed core-shell poly(styrene/thiophene) and polyaniline(PANI)-coated multi core-shell polystyrene latex particles were successfully prepared by oxidative and radical polymerization. The resulting latex particles have fine improved luminescence and conductive efficiency and dispersion state due to the PT and PANI shell. Hyper functionalized nanoparticle would be expected to increase the processibility in various electrical and electro-optical fields.

• 한국세라믹학회지
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• 제37권2호
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• pp.117-121
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• 2000

Er-doped sodiumborosilicate glass films for waveguides amplifier were fabricated by Aerosol Flame Deposition(AFD) method. Al2O3 was added to sodium borosilicate glass films to suppress the formation of crystalline phase and control the refractive index. the formation of crystalline phase was suppressed above Al2O3 of 6 wt%. As the amount of Al2O3 increased from 2 to 12 wt% the refractive index of glass films increased lineary from 1.4595 up to 1.4710. After the core of 77SiO2-15B2O3-8Na2O＋6 wt%Al2O3＋8wt%Er2O3 was coated on the buffer layer of 77SiO2-15B2O3-8Na2O＋6 wt%Al2O3, the core was etched by reactive ion etching. The absorption spectrum of 3 cm waveguide amplifier showed two peaks of 1530 and 1550 nm.

• Journal of Advanced Marine Engineering and Technology
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• 제22권5호
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• pp.588-594
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• 1998

Heat transfer characteristics of distance between impinging surface and a plane jet were experi-mentally investigated. The local heat transfer coefficients were measured by a thermochromic liq-uid crystal(TLC) The jet Reynolds number studied was varied over the range from 10,000310 to 30,000310 the nozzle-to-plate distance (H/B) from 4 to 10. It was observed that the Nusselt number increases with Reynolds number the occurrence of the secondary peak in the Nusselt number is within the potential core region the potential core of the jet flow can reach the impinging surface so that the wall jet can a transition from laminar to turbulent flow resulting in a sudden increase in the heat transfer rate.

• Macromolecular Research
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• 제16권5호
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• pp.399-403
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• 2008

Monodisperse, micron-sized, hybrid particles having a core-shell structure were prepared by coating the surface of poly(methyl methacrylate)(PMMA) microspheres with silica and by copolymerizing acrylamide (AAm) to supply the hydrogen bonding effect by means of the amide groups. Tetraethoxysilane (TEOS) was then slowly dropped onto the medium under certain conditions. Because of the hydrogen bonding between the amide of the PMMA particles and the hydroxyl group of the hydrolyzed silanol, a silica shell was generated on the PMMA core particles. The morphology of the hybrid particles was investigated with transmission (TEM) and scanning (SEM) electron microscopy as a function of the medium conditions and the amount of TEOS. Improved thermal properties were observed by TGA analysis.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1167-1168
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• 2006

In this study, the pure iron powder was treated with aqueous phosphoric acid to produce phosphate insulating layer on the surface. After drying the powder, it was compacted in a mold with a diameter of 20mm at 800MPa. The powder compacts were then heat treated at $500^{\circ}C$ for 1 hour. The results showed that insulated iron powder was obtained with uniform phosphate layer by chemical reaction. With increased amount of phosphate layer, the core loss and density of compacts were decreased. It was also found that the addition of ethyl alcohol during insulating reaction resulted in improved core loss value.

• Bulletin of the Korean Chemical Society
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• 제33권11호
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• pp.3576-3580
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• 2012

Larva-like GaS nanostructures synthesized by the thermal evaporation of Ga metals and S powders were coated with $SiO_2$ by the sputtering technique. Transmission electron microscopy and X-ray diffraction analyses revealed that the cores and shells of the GaS-core/$SiO_2$-shell larva-like nanostructures were single crystal wurtzite-type hexagonal structured-GaS and amorphous $SiO_2$, respectively. Photoluminescence (PL) measurements at room temperature showed that the passivation of the larva-like GaS nanostructures was successfully achieved with $SiO_2$ without nearly harming the major emission from the wires. However, subsequent thermal annealing treatment was found to be undesirable owing to the degradation of their emission in intensity.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.342-349
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• 2018

Polystyrene (PS) was coated on carbonyl iron (CI) particles via dispersion polymerization to produce core-shell structured CI/PS particles and adopted as magnetorheological (MR) material. Two MR fluids were prepared by dispersing CI/PS and CI particles in silicone oil. Their MR and tribological properties were investigated using a rheometer and a reciprocating friction and wear tester, respectively. Experimental data showed that tribological properties of MR fluid based on CI/PS particles are significantly enhanced compared to those of CI based MR fluid. Sedimentation problem of CI/PS MR fluid was also expected to be improved due to relatively lower density of CI/PS particles.

• 한국재료학회지
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• 제32권12호
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• pp.538-544
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• 2022

In existing ceramic mold manufacturing processes, inorganic binder systems (Si-Na, two-component system) are applied to ensure the effective firing strength of the ceramic mold and core. These inorganic binder systems makes it possible to manufacture a ceramic mold and core with high dimensional stability and effective strength. However, as in general sand casting processes, when molten metal is injected at room temperature, there is a limit to the production of thin or complex castings due to reduced fluidity caused by the rapid cooling of the molten metal. In addition, because sodium silicate generated through the vitrification reaction of the inorganic binder is converted into a liquid phase at a temperature of 1,000 ℃. or higher, it is somewhat difficult to manufacture parts through high-temperature casting. Therefore, in this study, a high-strength ceramic mold and core test piece with effective strength at high temperature was produced by applying a Si-Na-Ti three-component inorganic binder. The starting particles were coated with binary and ternary inorganic binders and mixed with an organic binder to prepare a molded body, and then heat-treated at 1,000/1,350/1,500 ℃ to prepare a fired body. In the sample where the two-component inorganic binder was applied, the glass was liquefied at a temperature of 1,000 ℃ or higher, and the strength decreased. However, the firing strength of the ceramic mold sample containing the three-component inorganic binder was improved, and it was confirmed that it was possible to manufacture a ceramic mold and core via high temperature casting.