• 한국건축시공학회지
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• 제19권5호
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• pp.391-399
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• 2019

본 연구는 국내에 새롭게 도입하고자 시운전중인 석탄가스화복합발전(IGCC)에서 발생하는 석탄가스화 용융슬래그(CGS)를 국내의 부족한 골재자원으로 재활용 가능성을 검토하였다. 즉, 부족한 골재자원확보를 위해 IGCC에서 발생하는 CGS를 빈배합 모르타르인 콘크리트 2차제품용 잔골재로 활용하고자 국내 건설산업에서 가장 많이 사용되고 있는 석산의 부순 잔골재로 양호한 품질의 CSa 및 굵은 입자로 표준입도를 벗어난 CSb와 해사인 SS를 혼합한 혼합잔골재에 CGS를 0~100 % 범위에서 치환하는 것을 검토하였다. 연구결과, CSa 혹은 CSb+SS에 CGS를 25~50% 정도 치환할 경우 골재의 입도측면 및 시멘트 모르타르의 유동성 및 압축강도 측면에서 양호한 결과가 얻어져 활용가능함을 확인할 수 있었다.

• 한국건축시공학회지
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• 제21권6호
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• pp.551-562
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• 2021

본 연구에서는 IGCC에서 발생하는 부산물인 CGS를 콘크리트용 혼합 잔골재로써 효율적으로 활용하는 방안을 제시하기 위하여 플라이애시 치환 매스 콘크리트의 수화열 저감 효과를 확보하기 위한 방안으로 CGS 기반 혼합 잔골재와 플라이애시 치환에 따른 수화열 저감 특성 분석 및 해석을 실시 하고자 한다. 따라서, 매스 콘크리트의 수화열 저감을 위하여 활용되는 플라이애시 기반 저발열 결합재에 CGS를 잔골재로 치환하여 최적의 조합으로 FA 30% 및 CGS를 잔골재로 50% 치환할 경우 저발열 결합재 FA를 단일 치환한 경우보다 복합상승 효과에 따라 수화열 저감 성능이 더 크게 나타났다. 따라서 산업부산물인 CGS 골재 조합에 플라이애시를 복합 치환한 분체-골재조합 재료 시스템은 매스 콘크리트 수화열 저감 공법의 효율적인 대안으로서 활용이 기대된다.

• 한국연소학회지
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• 제17권1호
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• pp.1-11
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• 2012

A slag building simplified model was developed to determine wall heat flux of a Shell 300 MW coal gasifier. In the model 4 layers(particulate, sintered, molten slag, solidified slag) were considered and mass conservation and energy balance were used to obtain each slag layer's thickness and surface temperature. Thermo-chemical and fluid charateristics of the gasifier were studied with and without considering the slag model using commercial CFD code FLUENT. Consideration of the slag layer did not affect syn-gas mole fractions. However, the slag layer caused to increase the exit gas temperature by about 50 K.

• 한국수소및신에너지학회논문집
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• 제22권6호
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• pp.913-924
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• 2011

A steady-state analysis has been conducted to predict the behavior of the slag layer in the entrained-flow slagging coal gasifier. The analysis takes into consideration the composition dependent slag properties such as density, viscosity, heat capacity, thermal conductivity, and temperature of critical viscosity. The amount of added flux to the design coal and the variation of syngas temperature inside the gasifier have been adopted as calculation parameters. The predicted results are the local thickness of the molten and the solid slag layers, and the slag viscosity and the velocity distribution across the molten slag layer along the gasifier wall near the slag tap.

• 한국수소및신에너지학회논문집
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• 제22권3호
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• pp.386-401
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• 2011

Mathematical models for various steps in coal gasification reactions were developed and applied to investigate the effects of operation parameters on dynamic behavior of gasification process. Chemical reactions considered in these models were pyrolysis, volatile combustion, water shift reaction, steam-methane reformation, and char gasification. Kinetics of heterogeneous reactions between char and gaseous agents was based on Random pore model. Momentum balance and Stokes' law were used to estimate the residence time of solid particles (char) in an up-flow reactor. The effects of operation parameters on syngas composition, reaction temperature, carbon conversion were verified. Parameters considered here for this purpose were $O_2$-to-coal mass ratio, pressure of reactor, composition of coal, diameter of char particle. On the basis of these parametric studies some quantitative parameter-response relationships were established from both dynamic and steady-state point of view. Without depending on steady state approximation, the present model can describe both transient and long-time limit behavior of the gasification system and accordingly serve as a proto-type dynamic simulator of coal gasification process. Incorporation of heat transfer through heterogenous boundaries, slag formation and steam generation is under progress and additional refinement of mathematical models to reflect the actual design of commercial gasifiers will be made in the near futureK.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.131.1-131.1
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• 2010

This study was conducted for engineering optimization for the gasification process which is the key factor for success of Taean IGCC gasification plant which has been driven forward under the government support in order to expand to supply new and renewable energy and diminish the burden of the responsibility for the reduction of the green house gas emission. The gasification process consists of coal milling and drying, pressurization and feeding, gasification, quenching and HP syngas cooling, slag removal system, dry flyash removal system, wet scrubbing system, and primary water treatment system. The configuration optimization is essential for the high efficiency and the cost saving. For this purpose, it was designed to have syngas cooler to recover the sensible heat as much as possible from the hot syngas produced from the gasifier which is the dry-feeding and entrained bed slagging type and also applied with the oxygen combustion and the first stage cylindrical upward gas flow. The pressure condition inside of the gasifier is around 40~45Mpg and the temperature condition is up to $1500{\sim}1700^{\circ}C$. It was designed for about 70% out of fly ash to be drained out throughout the quenching water in the bottom part of the gasifier as a type of molten slag flowing down on the membrane wall and finally become a byproduct over the slag removal system. The flyash removal system to capture solid particulates is applied with HPHT ceramic candle filter to stand up against the high pressure and temperature. When it comes to the residual tiny particles after the flyash removal system, wet scurbbing system is applied to finally clean up the solids. The washed-up syngas through the wet scrubber will keep around $130{\sim}135^{\circ}C$, 40~42Mpg and 250 ppmv of hydrochloric acid(HCl) and hydrofluoric acid(HF) at maximum and it is turned over to the gas treatment system for removing toxic gases out of the syngas to comply with the conditions requested from the gas turbine. The result of this study will be utilized to the detailed engineering, procurement and manufacturing of equipments, and construction for the Taean IGCC plant and furthermore it is the baseline technology applicable for the poly-generation such as coal gasification(SNG) and liquefaction(CTL) to reinforce national energy security and create new business models.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
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• pp.93-96
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• 2015

Commercial coal gasifiers typically use entrained flow type reactors, but have unique features in terms of reactor shape, gasifying agent, coal feeding type, ash/slag discharge, and reaction stages. The MHI gasifier is characterized as air-blow dry-feed entrained reactor, which incorporates a short combustion stage at the bottom and a tall gasification stage above. This study investigates the flow and reaction characteristics inside a MHI gasifier by using computational fluid dynamics (CFD) in order to understand its design and operation features. For its pilot-scale system at 200 ton/day capacity, the distribution of coal and air supply between the two reaction stages was varied. It was found that the syngas composition and carbon conversion rate were not significantly influenced by the changes in the distribution of coal and air supply. However, the temperature, velocity and flow pattern changed sensitively to the changes in the distribution of coal and air supply. The results suggest that one key factor to determine the operational ranges of coal and air supply would be the temperature and flow pattern along the narrower wall between the two reaction stages.

• 한국수소및신에너지학회논문집
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• 제22권5호
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• pp.686-698
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• 2011

Mathematical models for char-slag interaction and near-wall particle segregation developed by Montagnaro et. al. were applied to predict various aspects of coal gasification in an up-flow entrained gasifier of commercial scale. For this purpose, some computer simulations were performed using gPROMS as the numerical solver. Typical design parameters and operating conditions of the commercial gasifiers were used as input values for the simulation. Development of a densely dispersed phase of solid carbon was found to have a critical effect on both carbon conversion and ash flow behavior. In general, such a slow-moving phase was turned out to enhance carbon conversion by lengthening the residence time of char or soot particles. Furthermore, it was also found that guiding the transfer of char or soot into the closer part of the wall to coal burner is favorable in terms of gasification efficiency and vitrified ash collection. Finally, to a certain degree densely dispersed phase of carbon showed an yield-enhancing effect of syngas.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.147-148
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• 2012

The syngas produced from coal gasification is cooled down for gas cleaning by a syngas cooler that produces steam. Due to the presence of fly slag in the syngas, erosion, slagging and corrosion especially in the upper part of the syngas cooler may cause major operational problems. This study investigates the flow, heat transfer and particle behaviors in the syngas cooler of a 300MWe IGCC plant by using computational fluid dynamics. For various operational loads and geometry, the gas and particle flows directly impinged on the wall opposite to the syngas inlet, which may lead to erosion of the membrane wall. In the evaporate channels inside the syngas cololr, the particle flows were concentrated more on the outer channel where slagging becomes more serious. The heat transfer to the wall was mainly by convection which was larger on the side wall below the inlet level.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2022년도 봄 학술논문 발표대회
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• pp.192-193
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• 2022

In this study, concrete durability was reviewed before CGS, a by-product generated from IGCC, was used as a fine aggregate for concrete. The characteristics of concrete and effect on carbonization according to the type of pre-mixed cement and the CGS substitution rate were analyzed. As a result of the analysis, the depth of carbonation according to the pre-mixed cement types increased by up to 52%, and the carbonation resistance tended to be similar overall when CGS was used as a fine aggregate.