• Advances in Energy Research
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• v.8 no.4
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• pp.265-273
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• 2022

In this study, a product gas yield and carbon conversion were measured during the coal pyrolysis. The pyrolysis process occurred under two different atmospheres such as subcritical (45 bar, 10℃) and supercritical CO₂ condition (80 bar, 35℃). Under the same pressure (80 bar), the atmosphere temperature increased from 35℃ to 45℃ to further examine temperature effect on the pyrolysis at supercritical CO₂ condition. For all three cases, a power input supplied to heating wire placed below coal bed was controlled to make coal bed temperature constant. The phase change of CO₂ atmosphere and subsequent pyrolysis behaviors of coal bed were observed using high-resolution camcorder. The pressure and temperature in the reactor were controlled by a CO₂ pump and heater. Then, the coal bed was heated by wire heater to proceed the pyrolysis under supercritical CO₂ condition.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.35-40
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• 2003

Immense quantities of coal combustion by-products are produced every year, and only a small fraction of them are currently utilized. The purpose of this study is to investigate reused techniques of coal to highly economic growth and expansion of country base industry. So, in this study, artificial aggregate was developed to recycle coal ash by non-sintering technique and crush method. And characteristic of developed artificial aggregate was examined. Also, noise barriers using developed artificial aggregate was made by link of development of ECO-construction product and is preparing sound absorption and transmission loss experiment. Result of study was showed that artificial aggregate was more proper to use a noise barriers and this is expected to satisfy sound absorption standard in this study. So, if shape and color considering surround and design technology is studied continuously, it can be expected to make ECO-precast product as well as maximize waste recycling.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.275-280
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• 2001

Recycling of coal combustion by-product(Ash) are becoming more improtant in the utilization business as a result of the increased use of NOx reduction technologies at coal-fired power plants. current disposal methods of these by-products create not only a loss of profit for the power industry, but also environmental concerns that breed negative public opinion. Since inherent characteristics make these by-product suitable for building materials, several types of artificial aggregates and construction bricks are manufactured and tested to verify the engineering properties.

• Journal of the Korean Society of Combustion
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• v.14 no.2
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• pp.1-9
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• 2009

New way to effectively capture $CO_2$ in coal fired power plant is the combustion of coal using oxy-fuel technology. Combustion characteristics of Minco sub-bituminous coal at oxy-fuel conditions using TGA and drop tube furnace (DTF) were included activation energy about the char burnout, volatile yield and combustion efficiency of raw coal, the porosity of pyrolyzed char and fusion temperature of by-product ash. TGA result shows that the effect of $CO_2$ on combustion kinetics reduces activation energy by approximately 7 kJ/mol at air oxygen level(21% $O_2$) and decreases the burning time by approximately 16%. The results from DTF indicated similar combustion efficiency under $O_2/CO_2$ and $O_2/N_2$ atmospheres for equivalent $O_2$ concentration whereas high combustion efficiency under $O_2/N_2$ than $O_2/CO_2$ was obtained for high temperature of more than $1,100^{\circ}C$. Overall coal burning rate under $O_2/CO_2$ is decreased due to the lower rate of oxygen diffusion into coal surface through the $CO_2$ rich boundary layer. By-product ash produced under $O_2/CO_2$ and $O_2/N_2$ was similar IDT in irrelevant to $O_2$ concentration and atmospheres gas during the coal combustion.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.621-627
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• 2001

Recycling of coal combustion by-product(Ash) are becoming more important in the utilization business as a result of the increased use of NOx reduction technologies at coal-fired power plants. current disposal methods of these by-products create not only a loss of profit for the power industry, but also environmental concerns that breed negative public opinion. Since inherent characteristics make these by-product suitable for building materials, several types of artificial aggregates and construction bricks are manufactured and tested to verify the engineering properties.

• Journal of the Korea Institute of Building Construction
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• v.9 no.3
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• pp.73-78
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• 2009

Coal ash is a by-product of the combustion of pulverized coal, and much of this is dumped in landfills. The disposal of coal ash is one of the major issues for environmental problems. In this paper, the effects of the kinds and replacement ratio of coal ash on the durabilities of concrete mixtures are investigated. Fine aggregate was replaced with coal ash(fly ash and bottom ash) in five different ratios, of 0%, 10%, 20%, 35%, and 50% by volume. Test results indicated that the compressive strength increased with the increase in fly ash percentage. The loss of compressive strength of bottom ash concrete mixes after immersion in sulphuric acid solution was less than in the control mix(BA0). In addition, the carbonation depth of fly ash concrete mixes was lower than the control mix(FA0).

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.1015-1020
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• 2002

Recycling of coal combustion by-product(Ash) are becoming more improtant in the utilization business as a result of the increased use of NOx reduction technologies at coal-fired power plants. Current disposal methods of these by-products create not only a loss of profit for the power industry, but also environmental concerns that breed negative public opinion. This research made Precast block for environment-friendly secondary product and compare strength special quality of this block with existent common use brick and analyze application possibility in situ with a reserve experiment that measure strength property and manufacture method to handle coal ash produced in Bo-ryung thermoelectric power plant.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.621-627
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• 2016

Low-priced hydrogen is required in petrochemical industry for producing low-sulfur oil, and upgrading low-grade crude oil since environmental regulations have been reinforced. Steel industry can produce hydrogen from by-product gases such as Blast Furnace Gas (BFG), Coke Oven Gas (COG), and Linze Donawitz Gas (LDG) with water gas shift (WGS) reaction by catalysis. In this study, we optimized conditions for WGS reaction with commercial catalysts by BFG and LDG. In particular, the influence on activity of gas-hourly-space-velocity, and $H_2O/CO$ ratios at different temperatures were investigated. As a result, 99.9%, and 97% CO conversion were showed with BFG, and LDG respectively under $350^{\circ}C$ High Temperature Shift (HTS), $200^{\circ}C$ Low Temperature Shift (LTS), 3.0 of $H_2O/CO$, and $1500h^{-1}$ of GHSV. Furthermore, 99.9% CO conversion lasted for 250 hours with BFG as feed gas.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.11a
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• pp.159-160
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• 2017

Recently, researches on controlled low strength materials using coal ashes have been actively conducted in Korea. Controlled Low Strength Material by using a large amount of Coal Ashes, which is a by-product of the industry, will solve the environmental problems caused by coal ash as well as economic formulation. In this paper, the compressive strength and flow of the CLSM binder were investigated in order to select the optimum mixing ratio.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.293-298
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• 2002

Recycling of coal combustion by-product(Ash) are becoming more improtant in the utilization business as a result of the increased use of NOx reduction technologies at coal-fired power plants. current disposal methods of these by-products create not only a loss of profit for the power industry, but also environmental concerns that breed negative public opinion. This research made concrete crecast block using coal ash artificial aggregate for environmental-friendly products and compared strength special quality of this block with existent common use brick and analyzed application possibility in situ with a reserve experiment that measured strength property and manufactured method to handle coal ash produced in Bo-ryung thermoelectric power plant.