• Explosives and Blasting
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• v.21 no.2
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• pp.21-30
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• 2003

Currently, the shotcrete used as basic support in the tunnel excavation, has the advantages of maintaining high-level strength in condition of early shooting with thin thickness based on the excavation characteristics of rock mass. Therefore supreme equipment and materials were developed and the great strides have continued. Also, the development of measurement technology and the rocks behaviors of undergound are evaluated in detail and the designs of strength and thickness are made. The reinforcement materials development of new material is carried on. Most of the coal fly ash produced in Korea fire power plant is fly ash and bottom mash. Fly ash has been producing to be applied in many fields such as cement, aggregate, construction, civil, agriculture and fisheries. Also a lot of experiments are actively on the way. Therefore in this experiment, in order to use the fly ash mixed with concrete as a material of shotcrete, the experiment was performed in the best content to reduce the compression strength and the shooting rebound ratio of the excavated surface to use fly ash as a substitute material of concrete. As a result, when 15%.wt substitution was made to the fly ash, about 10% of compression strength and 6% of rebound ratio was reduced.

• Journal of the Korean Ceramic Society
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• v.39 no.12
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• pp.1164-1170
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• 2002

The effect of fly ash addition to the kaolin block has been investigated. The addition affected the firing temperature and physical properties such as water absorption and compressive strength. The starting materials were from korea natural resources and the fly ash were from the power plant using coal as fuel, containing free carbon of 8∼9 wt%. The starting natural materials were mixed with 5 different proportions of fly ash, pressed and then sintered at 1050, 1100, 1150 and 1200${\circ}C$. With sintering temperature, water absorption decreased and compressive strength increased. When specimens were sintered at the temperature lower than 1100${\circ}C$, water absorption increased and strength decreased with fly ash content. In contrast, when sintering was done at the temperature higher than 1150${\circ}C$, water absorption increased with fly ash content similarly but strength was improved.

• Clean Technology
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• v.19 no.4
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• pp.453-458
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• 2013

Fly ash has capacity to oxidize or adsorb mercury in a flue gas. Mercury oxidation and adsorption efficiencies of fly ash vary depending on the properties of fly ash. This study was designed to understand reaction characteristics of mercury with fly ash components. The fly ash components were tested to determine their oxidation and adsorption capabilities for elemental mercury and oxidized mercury. A sample was synthesized with fly ash components and tested. The test results were compared with those of the fly ash sample obtained from a coal-fired power plant. $Fe_2O_3$, CuO and carbon black showed higher oxidation or adsorption efficiency for elemental mercury while CaO, MgO, CuO and carbon black showed higher adsorption efficiency for mercury chloride. In addition, the synthesized sample showed comparable mercury oxidation and adsorption efficiencies to the fly ash sample.

• Resources Recycling
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• v.26 no.6
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• pp.10-19
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• 2017

It is studied the effect of crystal structure of domestic High-Ca limestones using absorbent for desulfurization on the grinding characteristics and dissolution rates in wet flue gas desulfurization process of domestic coal fired power plant. It compared the crystal structure, grinding work index and dissolution rates with 4 Limestones from Jecheon-Danyang with different crystal structure, and we found that grinding work index differ in crystal size and crystal structure of limestones : The lower the value of the grinding work index is, the higher the dissolution rates of limestones. Confirmed that we have important indicators of grinding characteristics for crystal structure with CaO content of limestones.

• Plant Journal
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• v.15 no.3
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• pp.35-41
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• 2019

In this study, we investigated the effect of the generation of NOx and CO by adjusting the overfire air supply position and ratio using the boiler that was converted from coal burning to wood pellet boiler. When the amount of the overfire air is relatively increased, the amount of NOx is slightly decreased but CO is sharply decreased when burning at low excess air ratio (1.10) that is due to a small fuel particle size. However, NOx slightly increased when burning at high excess air ratio (1.33) due to the large fuel size, but CO was hardly affected. Also, When the amount of overfire air was same, The more supply position was concentrated to upper portion of the main combustor, the more NOx and CO was lowered. And in case of the excess air ratio was high, the generation of NOx and CO I can see that it keeps the level irrelevant to the amount of air for the second stage combustion.

• Journal of the Korean GEO-environmental Society
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• v.11 no.6
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• pp.77-83
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• 2010

In this study, we tried to determine any detrimental effects on water quality when bottom ash obtained from a coal-fired power plant intended to be used as a fill material in construction sites. Physical-chemical properties of bottom ash were determined using proximate analysis, elemental analysis, XRD, and XRF. Classification of bottom ash as a waste material and soil contamination due to the use of bottom ash were performed by Korea waste standard leaching test and soil toxicity test, respectively. Results of leaching tests were compared to the regulations for water quality and groundwater quality and no harmful effects on water quality were found. Most of heavy metals in leachate were below detection limits but trace amount of $Cr^{6+}$ was found. However, concentration of $Cr^{6+}$ was below the regulation criteria. Column leaching tests indicated that concentrations of Pb and Zn were slightly higher than regulations but below regulations within 1 PVE, but concentrations of sulfate were 10 times higher than regulation and thus, the required time to reach regulation was almost 8 PVE.

• Journal of Energy Engineering
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• v.28 no.1
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• pp.1-9
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• 2019

In the flue gas desulfurization process of the coal-fired power plant, the grinding efficiencies of the limestone as the sorbent for desulfurization were compared after BWI and HGI measurements. As a result, the grinding index of the domestic desulfurization limestone were linear inversely proportional relationship with decreasing BWI was observed with increasing HGI. There was a difference in grinding efficiency depending on the chemical composition and crystal structure. Therefore, it is considered that when grinding ability of limestone is measured, the grinding property of the sample can be confirmed even by using HGI which can be measured more easily than BWI which is difficult to measure and takes a long time. The desulfurization efficiency can be improved by selective utilization of limestone depending on the crushing characteristics.

• Environmental and Resource Economics Review
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• v.31 no.3
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• pp.343-365
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• 2022

This paper tries to identify the effect of reducing PM2.5 concentration of the First Seasonal Management Policy implemented by Korean government by using statistical method. In particular, this paper tests the hypothesis that this policy effect may differ by region (west-coast, south-coast, and east-coast). To this end, this paper analyzed only pure policy effects by removing temporal abnormalities such as COVID-19, warm winter temperature during the policy implementation period (December 2019 to March 2020) by using the difference-in-difference method (DID). As a result of the analysis, this policy had the effect of reducing PM2.5, but the effect is not homogenous by region. In particular, PM2.5 reducing effect is the largest in west-coast region and south-coast region folllows, but its effect is not statistically significant in the east-cost region. In conclusion, this paper drew implications that the current Seasonal mamangement policy which is implemented regardless of the regional difference needs to be changed.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.5
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• pp.501-512
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• 2016

The study evaluated methods to measure condensable fine particles in flue gases and measured particulate matter by fuel and material to get precise concentrations and quantities. As a result of the method evaluation, it is required to improve test methods for measuring Condensable Particulate Matter (CPM) emitted after the conventional Filterable Particulate Matter (FPM) measurement process. Relative Standard Deviation (RSD) based on the evaluated analysis process showed that RSD percentages of FPM and CPM were around 27.0~139.5%. As errors in the process of CPM measurement and analysis can be caused while separating and dehydrating organic and inorganic materials from condensed liquid samples, transporting samples, and titrating ammonium hydroxide in the sample, it is required to comply with the exact test procedures. As for characteristics of FPM and CPM concentrations, CPM had about 1.6~63 times higher concentrations than FPM, and CPM caused huge increase in PM mass concentrations. Also, emission concentrations and quantities varied according to the characteristics of each fuel, the size of emitting facilities, operational conditions of emitters, etc. PM in the flue gases mostly consisted of CPM (61~99%), and the result of organic/inorganic component analysis revealed that organic dusts accounted for 30~88%. High-efficiency prevention facilities also had high concentrations of CPM due to large amounts of $NO_x$, and the more fuels, the more inorganic dusts. As a result of comparison between emission coefficients by fuel and the EPA AP-42, FPM had lower result values compared to that in the US materials, and CPM had higher values than FPM. For the emission coefficients of the total PM (FPM+CPM) by industry, that of thermal power stations (bituminous coal) was 71.64 g/ton, and cement manufacturing facility (blended fuels) 18.90 g/ton. In order to estimate emission quantities and coefficients proper to the circumstances of air pollutant-emitting facilities in Korea, measurement data need to be calculated in stages by facility condition according to the CPM measurement method in the study. About 80% of PM in flue gases are CPM, and a half of which are organic dusts that are mostly unknown yet. For effective management and control of PM in flue gases, it is necessary to identify the current conditions through quantitative and qualitative analysis of harmful organic substances, and have more interest in and conduct studies on unknown materials' measurements and behaviors.

• Applied Chemistry for Engineering
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• v.28 no.6
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• pp.607-618
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• 2017

Harmful air pollutants are exhausted from the various industrial facilities including the coal-fired thermal power plants and these substances affects on the human health as well as the nature environment. In particular, nitrogen oxides ($NO_x$) and sulfur dioxide ($SO_2$) are known to be causative substances to form fine particles ($PM_{2.5}$), which are also deleterious to human health. The integrated system composed of selective catalytic reduction (SCR) and wet flue gas desulfurization (WFGD) have been widely applied in order to control $NO_x$ and $SO_2$ emissions, resulting in high investment and operational costs, maintenance problems, and technical limitations. Recently, new technologies for the simultaneous removal of $NO_x$ and $SO_2$ from the flue gas, such as absorption, advanced oxidation processes (AOPs), non-thermal plasma (NTP), and electron beam (EB), are investigated in order to replace current integrated systems. The proposed technologies are based on the oxidation of $NO_x$ and $SO_2$ to $HNO_3$ and $H_2SO_4$ by using strong aqueous oxidants or oxidative radicals, the absorption of $HNO_3$ and $H_2SO_4$ into water at the gas-liquid interface, and the neutralization with additive reagents. In this paper, we summarize the technical improvements of each simultaneous abatement processes and the future prospect of technologies for demonstrating large-scaled applications.