• Environmental Engineering Research
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• v.20 no.3
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• pp.223-229
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• 2015

The application of coagulation for feed water pretreatment prior to microfiltration (MF) process has been widely adopted to alleviate fouling due to particles and organic matters in feed water. However, the efficiency of coagulation pretreatment for MF is sensitive to its operation conditions such as pH and coagulant dose. Moreover, the optimum coagulation condition for MF process is different from that for rapid sand filtration in conventional drinking water treatment. In this study, the use of response surface methodology (RSM) was attempted to determine coagulation conditions optimized for pretreatment of MF. The center-united experimental design was used to quantify the effects of coagulant dose and pH on the control of fouling control as well as the removal organic matters. A MF membrane (SDI Samsung, Korea) made of polyvinylidene fluoride (PVDF) was used for the filtration experiments. Poly aluminum chloride (PAC) was used as the coagulant and a series of jar tests were conducted under various conditions. The flux was $90L/m^2-h$ and the fouling rate were calculated in each condition. As a result of this study, an empirical model was derived to explore the optimized conditions for coagulant dose and pH for minimization of the fouling rate. This model also allowed the prediction of the efficiency of the coagulation efficiency. The experimental results were in good agreement with the predictions, suggesting that RSM has potential as a practical method for modeling the coagulation pretreatment for MF.

• Environmental Engineering Research
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• v.15 no.2
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• pp.63-70
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• 2010

In this study, the response surface method and experimental design were applied as an alternative to conventional methods for the optimization of coagulation tests. A central composite design, with 4 axial points, 4 factorial points and 5 replicates at the center point were used to build a model for predicting and optimizing the coagulation process. Mathematical model equations were derived by computer simulation programming with a least squares method using the Minitab 15 software. In these equations, the removal efficiencies of turbidity and total organic carbon (TOC) were expressed as second-order functions of two factors, such as alum dose and coagulation pH. Statistical checks (ANOVA table, $R^2$ and $R^2_{adj}$ value, model lack of fit test, and p value) indicated that the model was adequate for representing the experimental data. The p values showed that the quadratic effects of alum dose and coagulation pH were highly significant. In other words, these two factors had an important impact on the turbidity and TOC of treated water. To gain a better understanding of the two variables for optimal coagulation performance, the model was presented as both 3-D response surface and 2-D contour graphs. As a compromise for the simultaneously removal of maximum amounts of 92.5% turbidity and 39.5% TOC, the optimum conditions were found with 44 mg/L alum at pH 7.6. The predicted response from the model showed close agreement with the experimental data ($R^2$ values of 90.63% and 91.43% for turbidity removal and TOC removal, respectively), which demonstrates the effectiveness of this approach in achieving good predictions, while minimizing the number of experiments required.

• Journal of Korean Society of Water and Wastewater
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• v.31 no.2
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• pp.161-168
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• 2017

Microfiltration (MF) and Ultrafiltration (UF) membrane processes capable of producing highly purified water have been extensively applied as a pretreatment process in the wastewater reuse field with the improvement of membrane properties and resistance, development of operating protocols, and improvement of technologies of backwashing and physicochemical cleaning, and improvement of scale and antifoulants. However, despite of the development of membrane production and process technologies, fouling still remains unresolved. This study confirmed that foulants such as polysaccharides, proteins and humic substances existed in final treated effluent (secondary effluent) by fluorescence excitation emission matrix (FEEM) and fourier transform infrared spectroscopy (FTIR) analysis. In addition, when constructing ozone oxidation and coagulation processes as a hybrid process, the removal efficiency was 5.8%, 6.9%, 5.9%, and 28.2% higher than that of the single process using coagulation in turbidity, color, dissolved organic carbon (DOC), and UV254, respectively. The reversible and irreversible resistances in applying the hybrid process consisting of ozone oxidation and coagulation processes were lower than those in applying ozone oxidation and coagulation processes separately in UF membrane process. Therefore, it is considered possible to apply ozonation/coagulation as a pretreatment process for stable wastewater reuse by and then contributing to the reduction of fouling when calculating the optimal conditions for ozone oxidation and coagulation and then to applying them to membrane processes.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.30 no.3
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• pp.74-83
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• 1998

The phenomenon of decrease in sizing efficiency when the stock temperature is increased is well recognized as summer sizing, and this is believed to be caused by uneven distribution of sizing agents on paper surface most often incurred by coagulation of sizing agents. When unevenly sized paper is used as coating base stock, nonuniform consolidation of the coating layer may result, which, in turn, causes uneven distribution of binder on coating surface. This causes nonuniform ink absorption to produce print mottle. In this study the effects of simple or polymeric electrolytes, storage temperature and time on the coagulation of cationic dispersed rosin size were investigated using a turbidity measurement method which was verified to correlate well with the particle size of rosin emulsion or its coagulates. Handsheets sized with rosin dispersions coagulated under various conditions were prepared and their sizing degree and coated paper properties including gloss and ink density were examined. The relationship between the sizing nonuniformity of coated papers and its ink absorption property was evaluated. Turbidity of rosin emulsion increased as the storage temperature and time were increased. Addition of simple or polymeric electrolytes caused reduction in $zeta$ -potential of the rosin dispersion and accelerated the coagulation tendency substantially. Reversion of the $zeta$ -potential of rosin dispersion, however, did not occur when coagulation was induced with simple electrolytes. On the other hand, addition of an anionic polyelectrolyte reversed the $zeta$ -potential of the flocculated rosin dispersion. This indicated that electrical double layer compaction and bridging flocculation were coagulation mechanisms for simple and polymeric electrolytes, respectively. Sizing degree decreased as coagulation of rosin was increased. Paper gloss, ink gloss and ink density were increased when sizing degree of base stock was increased most probably due to prevention of base paper swelling and increased binder migration to coating surface. This suggested that uneven printing ink density occurred when uneven sizing development was induced by coagulation of rosin particles.

• Korean Journal of Veterinary Service
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• v.45 no.1
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• pp.55-61
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• 2022

In veterinary medicine, a variety of disease are known to cause coagulation abnormalities. Identification of these coagulation abnormalities have been relied on traditional coagulation assays(platelet concentration, aPTT, PT, D-dimer, fibrinogen) which take only a small part of the coagulation pathways rather than global hemostatic capacity. Among of the hypercoagulable diseases, cardiovascular disease, such as mitral valvular disease, was not regarded as the cause of the hypercoagulability. The value of a thromboelastography (TEG) as an early predictor of coagulopathy, especially hypercoagulability, has been founded. It was associated with decreased R and K values, and increased MA and α angle. The objective of this study was to compare thromboelastography results and those of traditional coagulation tests between twenty adult dogs with mitral insufficiency (MVI group) and eleven adult healthy dogs (Healthy group). As a results, MA values in the patients with mitral insufficiency (68.8±7.8 mm) were significantly higher than the normal patients (60.4±4.8 mm) (P value<0.05). Although a little report has been reported in veterinary medicine, platelet activation seems to be related with hypercoagulability in MVI patients in human medicine. The result of this report can support this pathophysiology in veterinary medicine. In addition to traditional coagulation assay, global assessment of coagulopathy using TEG, especially ability to detect hypercoagulability, may be useful for customized treatment in MVI patients. To achieve this, further study is needed to define pathophysiology and effect of medication.

• Journal of Environmental Health Sciences
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• v.17 no.1
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• pp.67-73
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• 1991

In this study are investigated to the optimal coagulation conditions and magnetite which was used as coagulation-aids. To accomplish this study, analysis of water quality, removing tubidity and SS from wastewater were measured with jar-tester. The results were obtained that waste water requires 10g magnetite, 100mg aluminum sulfate, and pH valuse was 6~9.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.4
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• pp.473-479
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• 2005

Applying enhanced coagulation is not uncommon not only to improve water quality but also to obtain economical advantages in water treatment. In this study, the economical evaluation was investigated with considering dosage of coagulant, produced sludges and usage of activated carbon with two different water sources. To simulate the granular activated carbon(GAC) adsorber mini-column test was adapted. Even if there were some variation according to the source waters, the life time of GAC was extended 60 to 110days with adding 2.5 to 3 times of coagulant in enhanced coagulation. With assumption of changing GAC adsorber at 50% of breakthrough the total treatment cost can be reduced to range from 25% to 44% with adapting the enhanced coagulation. The obtained value can not be generalized because the value can be varied by water quality and cost of the GAC or coagulant. However, the evaluation can be basis starting point to find optimum operation methods for the drinking water treatment which has plan to adapt GAC adsorber.

• Journal of environmental and Sanitary engineering
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• v.16 no.2
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• pp.1-8
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• 2001

The water treatment by electrochemical method was performed to increase the yield of production. Continuous plug flow reactor was operated to treat poultry and domestic wastewaters. Experimental results were compared with experimental results of the wastewater treatment by chemical coagulation, they were increased over 10% in the removal efficiency of COD and the production rate of sludge was reduced by 30%. Ozone utilized to degrade or change the organic chemical structures, which removal efficiency increased to 20% in the electro-coagulation reactor. Economic evaluation was performed to estimate total cost of electro-coagulation reactor in comparison with that of chemical coagulation method. The total cost to treat 1000 ton/day of domestic wastewater was reduced by 50%.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.4
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• pp.303-312
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• 1998

To obtain the solution to the time-dependent particle size distribution of an aerosol undergoing gravitational coagulation, the moment method was used which converts the non linear integro-differential equation to a set of ordinary differential equations. A semi-numerical solution was obtained using this method. Subsequently, an analytic solution was given by approximating the collision kernel into a form suitable for the analysis. The results show that during gravitational coagulation, the geometric standard deviation increases and the geometric mean radius decreases as time increases.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.715-718
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• 2001

This study uses traditional alum coagulation and sedimentation process to treat CMP wastewater from cleaning after polishing. The primary goal is to successfully recycle both solid fines and water for semiconductor manufacturing. Results indicated that CMP wastewater may be successfully treated to recover clean water and fine particles by alum coagulation. The optimum operating conditions for coagulation are as fellowing: alum dosage of 10 ppm, pH at 5, rapid mixing speed at 800 rpm, 5 min rapid mixing time, and long slow mixing time. The treated water with low turbidity and an average residual aluminum ion concentration of 0.23 ppm may be considered for reuse. The settled sludge after alum coagulation contains mainly SiO$_2$particle with a minor content of aluminum (1.7 wt%) may be considered as raw materials for glass and ceramic industry.