• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 2011년도 임시총회 및 하계학술연구발표회
• /
• pp.161-162
• /
• 2011

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 1998년도 추계학술발표강연 및 논문개요집
• /
• pp.137-137
• /
• 1998

• 한국전기전자재료학회논문지
• /
• 제13권11호
• /
• pp.908-913
• /
• 2000

CoSi$_2$/p+/n diodes(bilayer diodes) were fabricated by using epitaxial CoSi$_2$grown from Co/Ti bilayer as a diffusion source. The I-V characteristics of p+/n diodes were measured and compared with those of diode made from Co monolayer (monolayer diode). Monolayer diodes showed typical p+n junction characteristics with the leakage current of as low as 10$^{-12}$ A and forward current 6-orders higher than the leakage current, when drive-in annealed at 90$0^{\circ}C$ for 20 sec.. On the other hand, bilayer diodes showed the Schottky-like behaviors with forward currents rather higher than those of monolyer diodes, but with too high leakage currents, when drive-in annealed at $700^{\circ}C$ or higher. However, when the annealing temperature was lowered to $700^{\circ}C$ and annealing time was increased to 60 sec., the leakage current was reduced to 10$^{-11}$ A and thus sho3wed typical diode characteristics. The high leakage currents for diodes annealed at $700^{\circ}C$ or higher was attributed to Shannon contacts formed due to unremoved Co-Ti-Si precipitates. But when annealed at 50$0^{\circ}C$, B ions diffused in the direction of the surface layer, and thus the leakage currents were reduced by removing Shannon contacts.

• The Korean Journal of Ceramics
• /
• 제5권2호
• /
• pp.189-194
• /
• 1999

Crystallization of glasses in the system (Ca, Sr, Ba)$O-Al_2O_3-B_2O_3-SiO_2-TiO_2$ and dielectric properties of crystallized glasses were investigated. As increasing B2O3 content and decreasing SiO2 content in the glass, the major crystalline phase changed from $(Sr, Ba)_2TiSi_2O_8$ to (Ca, Sr, Ba)TiO3, the dielectric constant of crystallized glasses increased and the Temperature Coefficient of Capacitance (TCC) changed to negative. The dielectric constant and TCC was estimated for (Sr, Ba)2TiSi2O8 phase as 18 and -440 $ppm/^{\circ}C$, respectively and for (Ca, Sr, Ba)TiO3 phase as 307 and -1900 $ppm/^{\circ}C$, respectively. The dielectric properties of (Ca, Sr, Ba)TiO3 phase (in this study) were similar to those of (Ca, Ba) TiO_3 solid-solution^12)$, but $(Sr, Ba)_2TiSi_2O_8$ phase (in this study) and $Sr_2TiSi_2O_\;8^4$ showed the different properties.

• Journal of Magnetics
• /
• 제8권3호
• /
• pp.113-117
• /
• 2003

$Co_{78-x}Pt_xB_{10}Si_{12}$ alloys were produced using the melt-spin process in order to study the crystallization behavior and ensuing magnetic properties of the $Co_{78-x}Pt_xB_{10}Si_{12}$ (Co-Pt) amorphous alloys as a function of the Pt content. We showed that when $\chi$ $>$ 15 well below its stoichiometric composition, CoPt crystallized in the amorphous alloy, thus greatly altering the crystallized microstructure and magnetic properties during annealing. Below this composition, the main crystallization product was Co with Pt dissolved in its lattice. In spite of the nucleation of CoPt with high magnetic anisotropy, the highest coercivity was obtained when x was 15. It was also concluded that the Pt addition deteriorated the glass stability, triggering the devitrification at a progressively lower temperature.

• Journal of Magnetics
• /
• 제2권4호
• /
• pp.130-134
• /
• 1997

The amorphous Co-based alloy Co66Fe4Ni1B15Si14 (Metglas 2714A) is a suitable magnetic core material for high frequency operation. Appreciable reduction of the coercive force can be achieved by proper heat treatment. In this study, samples annealed at wide temperature range were analyzed using differential scanning calorimetry, high frequency B-H loop tester, X-ray diffractometer and resistivity meter. The results show that coercive force at 10 kHz decreases with in-creasing annealing temperature up to 773 K, but dramatically increases above this temperature. The squareness shows that the magnetic anisotropy on longitudinal direction of the as-cast state remains up to 773 K. Above this temperature, it decreases down to 0.5 that represents random distribution of magnetic domains. The crystallization abruptly occurs between 781 K and 783 K.

• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 2007년도 동계학술연구발표회 및 스핀트로닉스와 나노물리에관한 국제심포지움
• /
• pp.70-71
• /
• 2007

• 대한화학회지
• /
• 제53권3호
• /
• pp.233-243
• /
• 2009

실리카지지 니켈(Ni-Si$O_2$), 실리카지지 구리(Cu-Si$O_2$), 몇가지 조성의 실리카지지 니켈과 구리의 합금(Ni/Cu-Si$O_2$)을 실온에서 일산화탄소(CO)의 압력을 넓은 범위에서 변화시키면서(0.2 $torr{\sim}$50 torr) 흡착된 CO의 적외선 스펙트럼을 1500 $cm^{-1}{\sim}2500\;cm^{-1}$ 범위에서 관찰했고 실온에서 진공탈착시키면서 흡착된 CO의 적외선 스펙트럼을 관찰했다. Ni-Si$O_2$에 CO를 흡착시켰을 때 2059.6 $cm^{-1},\;{\sim}$2036.5 $cm^{-1},\;{\sim}$1868.7 $cm^{-1},\;{\sim}$1697.1 $cm^{-1}$의 네 흡수띠가 관찰되었고, Cu-Si$O_2$에 일산화탄소를 흡착시켰을 때 $\sim$2115.5 $cm^{-1},\;{\sim}$1743.0 $cm^{-1}$ 두 흡수띠가 관찰되었으며, Ni/Cu-Si$O_2$에서는 ${\sim}2123.2\;cm^{-1}$, 2059.6 $cm^{-1},\;{\sim}$2036.4 $cm^{-1},\;{\sim}$1899.5 $cm^{-1},\;{\sim}$1697.1 $cm^{-1}$에 다섯 흡수띠가 관찰되었다. Ni/Cu-Si$O_2$, Cu-Si$O_2$, Ni/Cu-Si$O_2$에서 CO를 흡착시켰을 때 관찰된 흡수스펙트럼은 이전의 보고와 근사적으로 일치한다. 1800 $cm^{-1}$ 이하의 흡수띠는 Ni이나 Ni/Cu 합금의 스텦이 있는 결정표면에서 관찰된 바 있는데 Ni-Si$O_2$, Ni/Cu-Si$O_2$를 실온에서 CO를 흡착시켰을 때 나타나는 ${\sim}1697.1\;cm^{-1}$ 흡수띠는 Ni이나 Ni/Cu 합금 표면에서 스텦에 인접한 흡착자리에 흡착한 CO에 기인한 흡수띠로 제시할 수 있다. Cu-Si$O_2$ 시료를 실온에서 CO를 흡착시켰을 때 Cu 결정표면에서 2000 $cm^{-1}$ 이하의 흡수띠가 관찰되는 경우는 드문데 1743.0 $cm^{-1}$ 흡수띠는 Cu 표면의 스텦에 인접한 흡착자리에 흡착한 CO에 기인한 흡수띠로 제시할 수 있다. Ni/Cu-Si$O_2$에서 Cu의 함량이 몰분율 0.5까지 변함에 따라 같은 CO 압력 또는 같은 진공탈착시간에서 흡수띠의 위치가 21 $cm^{-1}$ 이하로 다른 ⅠB 금속을 첨가했을 때보다 작게 변하는데 Cu d 전자의 리간드 효과가 작은 현상에 기인한 것으로 볼 수 있다.

• 한국분말재료학회지
• /
• 제24권5호
• /
• pp.370-376
• /
• 2017

In this study we manufacture a Ni-Cr-B-Si +WC/12Co composite coating layer on a Cu base material using a laser cladding (LC) process, and investigate the microstructural and mechanical properties of the LC coating and Ni electroplating layers (reference material). The initial powder used for the LC coating layer is a powder feedstock with an average particle size of $125{\mu}m$. To identify the microstructural and mechanical properties, OM, SEM, XRD, room and high temperature hardness, and wear tests are implemented. Microstructural observation of the initial powder and LC coating layer confirm the layer is composed mainly of ${\gamma}-Ni$ phases and WC and $Cr_{23}C_6$ carbides. The measured hardness of the LC coating and Ni electroplating layers are 653 and 154 Hv, respectively. The hardness measurement from room up to high temperatures of $700^{\circ}C$ result in a hardness decrease as the temperature increases, but the hardness of the LC coating layer is higher for all temperature conditions. Room temperature wear results show that the wear loss of the LC coating layer is 1/12 of the wear level of the Ni electroplating layer. The measured bond strength is also greater in the LC coating than the Ni electroplating.

• 한국분말재료학회지
• /
• 제21권5호
• /
• pp.377-381
• /
• 2014

This work describes the coloration, chemical stability of $SiO_2$ and $SnO_2$-coated blue $CoAl_2O_4$ pigment. The $CoAl_2O_4$, raw materials, were synthesized by a co-precipitation method and coated with silica ($SiO_2$) and tin oxide ($SnO_2$) using sol-gel method, respectively. To study phase and coloration of $CoAl_2O_4$, we prepared nano sized $CoAl_2O_4$ pigments which were coated $SiO_2$ and $SnO_2$ using tetraethylorthosilicate, $Na_2SiO_3$ and $Na_2SiO_3$ as a coating material. To determine the stability of the coated samples and their colloidal solutions under acidic and basic conditions, colloidal nanoparticle solutions with various pH values were prepared and monitored over time. Blue $CoAl_2O_4$ solutions were tuned yellow color under all acidic/basic conditions. On the other hand, the chemical stability of $SiO_2$ and $SnO_2$-coated $CoAl_2O_4$ solution were improved when all samples pH values, respectively. Phase stability under acidic/basic condition of the core-shell type $CoAl_2O_4$ powders were characterized by transmission electron microscope, X-ray diffraction, CIE $L^*a^*b^*$ color parameter measurements.