• Title/Summary/Keyword: CoPP

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Temperature Dependent Failure Machanisms of CaCO3 / PP Particulates ($CaCO_3$ / PP 입자 강화 복합재료의 온도변화에 따른 파괴기구)

  • Koh, Sung-Wi;Kim, Hyung-Jin
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.30 no.3
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    • pp.220-226
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    • 1994
  • In this paper the failure mechanisms of polypropylene resin composites filled with calcium carbonate particulates have been studied in the temperature range $-50^{\circ}C$ to $-50^{\circ}C$ The fillers used are both untreated and surface treated with stearic acid. The impact fracture toughness is evaluated from the impact energy absorbed divided by the uncut ligament area of the specimen. Impact fracture toughness increases as temperature is raised whether the fillers are coated or not. The static fracture toughness of these particular composites is evaluated based on the linear clastic fracture toughness of these particular composites is evaluated based on the linear clastic fracture mechanics. Static fracture toughess decreases with increasing temperature whether the fillers are coated or not. An extended stress whitened zone are observed through a large number of availabel sites for cavitation/debonding along particle matrix interface and matrix deformation.

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Ablation of Polypropylene for Breathable Packaging Films

  • Sohn, Ik-Bu;Noh, Young-Chul;Choi, Sung-Chul;Ko, Do-Kyeong;Lee, Jong-Min;Choi, Young-Jin
    • Laser Solutions
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    • v.9 no.3
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    • pp.15-21
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    • 2006
  • A Polypropylene (PP) film was ablated using a femtosecond laser with a center wavelength of 785 nm, a pulse width of 184 fs and a repetition rate of 1 kHz. Increments of both pulse energy and the shot number of pulses lead to co-occurrence of photochemical and thermal effect, demonstrated by the spatial expansion of rim on the surface of PP. The shapes of the laser-ablated PP films were imaged by a scanning electron microscope (SEM) and measured a 3D optical measurement system (NanoFocus). And, the oxygen transmission rate (ORT) of periodically laser-ablated PP film were characterized by oxygen permeability tester for modified atmosphere packaging (MAP) of fresh fruit and vegetable. Our results demonstrate that femtosecond pulsed laser is efficient tools for breathable packaging films in modifying the flow of air and gas into and out of a fresh produce container, where the micropatterns are specifically tailored in size, location and number which are easily controlled by laser pulse energy and pulse patterning system.

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Electrical Resistivity and Mechanical Properties of Polypropylene Composites Containing Carbon Nanotubes and Stainless Steel Short Fibers (탄소나노튜브와 스테인레스강 단섬유를 함유한 폴리프로필렌 복합체의 전기저항 및 기계적 특성)

  • Jung, Jong Ki;Park, Kihun;Bang, Daesuk;Oh, Myunghoon;Kim, Bongseok;Lee, Jong Keun
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.250-256
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    • 2014
  • Polypropylene (PP) composites containing conductive multi-walled carbon nanotube (MWNT) and stainless steel short fiber (SSF) were manufactured using a twin screw extruder and characterized their surface resistivity and mechanical properties in this work. Surface resistivity measurements showed that the percolation threshold appeared at a lower MWNT loading when a small amount of SSF was added to PP/MWNT composites. Tensile modulus and strength of the composites increased but elongation-at-break decreased greatly compared to pure PP. Also, the effects of MWNT and SSF on storage modulus and tan ${\delta}$ from dynamic mechanical analysis for the composites were examined, and the morphologies of fractured surface and the fillers were observed using a scanning electron microscope.

Characterization of Thermo-Plastic Vulcanized (TPV) Composite Prepared by the Waste Tire and Plastic Powder (폐타이어 분말과 재생PP로 제조한 열가소성 고무 플라스틱(TPV)의 물성평가)

  • An, Ju-Young;Park, Jong-Moon;Bang, DaeSuk;Kim, Bong-Suk;Oh, Myung-Hoon
    • Resources Recycling
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    • v.23 no.4
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    • pp.30-36
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    • 2014
  • 300,000 tons of waste tires are annually being produced with development of the automotive industry in Korea. Landfill and incineration treatment system are causing the economic problem through secondary environmental pollution and waste. Therefore, as one of the ways to take advantage of this, Thermo-Plastic Vulcanized (TPV) composite was prepared by the ground waste tire and plastic powders. The waste tire powder was gained by mechanical fracturing through crushers. The waste tire powder was ground by a shear crushing method and a 2-stage disk mill method instead of cutting crushing one. The waste tire powder of 50 mesh was mixed with Polypropylene(PP) in various proportions. TPVs were prepared by an extrusion, and tensile and impact tests were performed. In addition, the same experiments were repeated in 40, 80, 140 mesh conditions in order to observe size effect of waste tire powders.

Effects of Storage Temperature and Materials on Maintenance of Quality of Solidago virgaurea spp. gigantea in Modified Atmosphere Packaging (MAP 포장재의 종류와 온도가 울릉미역취의 품질에 미치는 영향)

  • Choi, Mal-Gum;Chung, Hun-Sik;Moon, Kwang-Deog
    • Food Science and Preservation
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    • v.15 no.6
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    • pp.804-809
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    • 2008
  • Modified atmosphere packaging (MAP) was assessed in terms of extending the shelf life of Solidago virgaurea spp. gigantea. In June 2005 Solidago virgaurea spp. gigantea were harvested from Ulleung Island, packaged in $30\;{\mu}m$ PP, $30\;{\mu}m$ Antifogging-OPP, $30\;{\mu}m$ LDPE, $18\;{\mu}m$ Macroperforated-HDPE, $60\;{\mu}m$ nylon/PE, or $85\;{\mu}m$ PVC/PE film, then stored at 4, 10 or $20^{\circ}C$ for up to 14 days. The $O_2$ concentration decreased to $9{\sim}10%$ in the PP and A-OPP packaging, to $12{\sim}16%$ in LDPE packaging, and to 2% in nylon/PE and PVC/PE packaging at $10^{\circ}C$. The $CO_2$ concentration increased to 5% at $10^{\circ}C$ in PP, A-OPP and LDPE packaging, but increased consistently in the nylon/PE and PVC/PE packaging. Weight loss was markedly reduced by all MAP films except M-HDPE, and which was enhanced with decreasing storage temperature. The soluble solids and pH were not affected by the packaging material at $4^{\circ}C$ and $10^{\circ}C$, but were affected at $20^{\circ}C$. The highest score for sensory qualities (appearance, color and overall acceptability) was obtained for vegetables stored at $4^{\circ}C$ in PP films. Our results show that MAP using PP films and $4^{\circ}C$ storage can effectively maintain the quality of Solidago virgaurea spp. gigantea.

Physiological activities of Pyrus pyrifolia Nakai, malt, Ziziphus jujuba Mill., Leonurus japonicus Houtt., Scutellaria baicalensis, and their mixtures (배, 맥아, 대추, 익모초, 황금 및 이들 혼합물의 생리활성)

  • SooJung Lee;HyunJun Kim;Mi Ja Chung
    • Food Science and Preservation
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    • v.30 no.6
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    • pp.999-1011
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    • 2023
  • This study investigated the anti-inflammatory, trypsin activity, and antioxidant effects of 11 kinds of plant extracts to discover materials for developing optimal mixtures that improve inflammation and help digestion. Ziziphus jujuba Mill. (ZJ), Leonurus japonicus Houtt. (LJ), Scutellaria baicalensis (SB), Platycodon grandiflorum, and Aster scaber extracts had excellent anti-inflammatory effects by reducing excessive nitric oxide (NO) and tumor necrosis factor-α content in lipopolysaccharide (LPS)-stimulated RAW264.7 macrophages. The malt (MA), Pyrus pyrifolia Nakai (PP), Raphanus sativus L., Platycodon grandiflorum extracts among the 11 kinds of plant extracts had high trypsin activity. The antioxidant activity of the plant extracts was examined by the DPPH radical scavenging activity, and the SB, PE, JU, and MA extracts had high antioxidant activity. Therefore, PP, MA, ZJ, LJ, and SB were selected to develop optimal mixtures that improve inflammation and help digestion. The extract of plant mixture containing PP, MA, ZJ, LJ, and SB in the ratio 1:1:2:1:2 (w/w) significantly inhibited NO production than the extract of PP, MA, ZJ, LJ, and SB, respectively, in LPS-stimulated RAW 264.7 macrophages. The DPPH radical scavenging activity of the mixture extract was significantly higher than the extract of PP, MA, ZJ, and LJ, respectively.

Analysis of Flavor Components of Coffee Beans in Polyethylene and Polypropylene Packaging Materials during Storage (원두커피 향미 성분의 폴리에틸렌과 폴리프로필렌 포장재에서의 저장 차이 분석)

  • Yu, Ha Kyoung;Lee, Seung Uk;Oh, Jae Young
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.23 no.2
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    • pp.89-95
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    • 2017
  • Although the global coffee market is growing every year and the demand for coffee wrapping paper is increasing accordingly, research on the effect of PE material and PP material on the coffee aroma used in the sealant layer, which will directly contact the product, is lacking. In this study, we studied the change of aroma patterns and flavor materials by adding coffee to PP and PE pouches. In addition, we observed changes in aroma patterns depending on the temperature and the presence of the deoxidizer. As a result, it was found that the PP type packaging material was slightly better than the PE type packaging material, but the performance was hardly changed by the material. Rather, the change in the aroma pattern due to temperature was dominant rather than the material. It is ideal that refrigerated distribution ($4^{\circ}C$) is the best storage temperature and sales are done within a short period of time. Among the indicators, pyridine was the most suitable material to study and there are many data about pyridine. Therefore, it is expected that the results can be derived by using pyridine.

Combustion Properties of Wood Treated by Combining Phosphorus-Nitrogen Compounds (인-질소 화합물 조합에 의해 처리된 목재의 연소성)

  • Jin, Eui;Chung, Yeong-Jin;Kim, Si-Kuk
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.39-44
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    • 2016
  • This study was to investigate the characteristics of combustion toxic gases of pinus rigida specimens treated with chemical additives such as pyrophosphoric acid (PP)/ammonuium ion ($NH_4{^+}$), methylenepiperazinomethyl-bis-phosphonic acid (PIPEABP) and $PIPEABP/NH_4{^+}$. Each pinus rigida plates was painted in three times with 15 wt% of each chemical additives in the aqueous solution. After drying these specimens at room temperature, the production of combustion gases and smoke was examined by the cone calorimeter (ISO 5660-1). As a result, the peak mass loss rate time (PMLR time) treated with chemicals was delayed upto 10.5~47.4% compared to that of using untreated specimen. In addition, the peak production of carbon monoxide ($CO\;_{peak}$) of 32.1~71.4% and total smoke release rate (TSRR) of 15.6~43.6% for test pieces treated with the chemical additive were higher than that of using the virgin plate. In particular, for the specimens treated with the chemical additive, the rate of smoke release (RSR) 29.4~41.5% was obtained higher than that of untreated plate except the specimen treated with $PP/4NH_4{^+}$. It can thus be concluded that the treatment using the chemical additive could partially increase the combustion-retardation properties of the species when compared to those of the virgin plate.

Internal Atmosphere of Individual Sweet Persimmon Package as Function of Fruit Size and Package Film Area (과일 크기와 포장 표면적에 따른 낱개 단감 포장의 기체조성)

  • Kim, Hae-Jin;Ahn, Gwang-Hwan;Jeong, Mi-Jin;An, Duck-Soon;Lee, Dong-Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.16 no.2_3
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    • pp.53-58
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    • 2010
  • Internal gas composition of single unit persimmon package was evaluated at $-1^{\circ}C$ as function of package film area and fruit weight in order to find packaging conditions to achieve the optimal modified atmosphere beneficial for keeping the freshness. With large fruit size(${\approx}230\;g$), low permeable films (LLDPE/PP in 35 or $40\;{\mu}m$ thickness and $30\;{\mu}m$ OPP) with an exact fitness to the fruit (surface area of $0.040\;m^2$) resulted in anaerobic atmosphere with occurrence of browning in long term storage. With medium (${\approx}210\;g$) and medium small (${\approx}190g$) sizes, larger surface area of low permeable $35\;{\mu}m$ LLDPE/PP film provided higher $O_2$ and lower $CO_2$ concentrations causing higher occurrence of softening and blackening discoloration. On the other hand, smaller surface area of lower $O_2$ and higher $CO_2$ concentrations had a high risk of browning. Wise combination of fruit size, packaging film and surface area is required for attaining the beneficial modified atmosphere to prevent the physiological injuries.

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Risk of Smoke Occurring in the Combustion of Plastics (플라스틱의 연소 시 발생하는 연기 위험성에 관한 연구)

  • You, Jisun;Chung, Yeong-jin
    • Fire Science and Engineering
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    • v.33 no.1
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    • pp.69-75
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    • 2019
  • In this study, the combustibility of five types of plastic plates, fiber reinforced plastic (FRP), polystyrene (PS), polycarbonate (PC), polypropylene (PP), and polyvinyl chloride (PVC), were tested using a cone calorimeter (ISO 5660). The PVC plate showed a $44.65kW/m^2$ lower peak heat release rate (HRR) and a $30.97kW/m^2$ lower maximum average rate of heat emission than the other four types of plastics, whereas the PS plate showed a $773.44kW/m^2$ higher peak HRR and $399.14kW/m^2$ higher maximum average rate of heat emission. The PC plate and PS plate showed the highest HRR by a maximum of 3.88 times in $CO_{mean}$ yields, while the PS pate and PP plate showed the highest HRR by a maximum 4.88 times in $CO_{2mean}$ yields. In addition, the smoke performance index (SPI) of the PS plate decreased by 74.81%~95.99%; the smoke growth index (SGI) increased to 76%~300%; the smoke intensity (SI) also increased to 917.73% ~ 9607.57%, and the danger of smoke increased. The PS plate was found to have the highest risk of life damage due to smoke on the thermal and smoke sides.