• Bulletin of the Korean Chemical Society
• /
• 제9권3호
• /
• pp.161-164
• /
• 1988

Infrared multiphoton decompositions (IRMPD) of $BrCH_2CH_2CH_2CH_2Cl$ were studied by using the pulsed $CO_2$laser. At 0.3 J laser energy the experimentally observed product ratios could be reasonably explained by the RRKM calculation with initial excitation energy of ca. 80 Kcal/mol. The pressure dependence of product yields led us to conclude that the collisional deactivation by the inert gas decreased the yield of low energy dissociation channel more significantly.

• Bulletin of the Korean Chemical Society
• /
• 제11권2호
• /
• pp.109-114
• /
• 1990

The anionic transition metal hydrides $(HW(CO)_4P(OMe)_3\;^-,\;HW(CO)_5\;^-,\;HCr(CO)_5\;^-,\;HFe(CO)_4\;^-)$ react with transition metal alkyl $(CpMo(CO)_3(CH_3)$ to yield $CH_4\;and\;CH_3CHO$ in addition to the inorganic products $(CpMo(Co)_3\;^-$, etc.). The reaction of these anionic metal hydrides with CpMo(CO)3{CH2CH(CH2)2} may lead to an elucidation of the reaction mechanisms involved; the organic product distributions are among $CH_4,\;CH_2\;=\;CHCH_2CH_3$, and $CH_3CH(CH_2)_2$, depending upon the anionic metal hydride used. These anionic metal hydrides also are reported to undergo a hydride-halide exchange reaction with organic halides; therefore, these similar reactions have been compared in terms of leaving group ability $(CpMo(CO)_3\;^-\;vs.\;Br^-)$ and the mechanistic pathways.

• 대한화학회지
• /
• 제50권5호
• /
• pp.369-373
• /
• 2006

Pd(CF3CO2)2-phosphine 및 Pd(CF3CO2)2-sulfide 계를 촉매로 사용하여 styrene의 아릴화반응을 연구하였다. 주 생성물인 trans-stilbene의 수율은 phosphine 치환체의 염기도가 증가할수록 높아졌고 입체장애가 클수록 낮아졌다. arylphosphine에서 styrene으로 aryl 기가 이동하는 현상은 동일한 arylphosphine에 대하여 Pd(CF3CO2)2의 경우가 더 높은 염기도를 가진 Pd(CH3CO2)2의 경우보다 더 많이 나타났으므로 이 반응은 Pd 이온이 먼저 aryl 기에 공격을 하는 친전자성 메커니즘에 의해 진행된다고 본다. 한편 Pd(CF3CO2)2-sulfide보다 Pd(CF3CO2)2-phosphine 계가 더 효과적인 촉매로 작용하였다.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• 제14권9호
• /
• pp.3680-3692
• /
• 2020

The purpose of this study is to orient users' touchpoints in co-design experience, to identify their need via visualized experience map, to recommend valid design information in online e-customization services. A user-centered co-design experience map (UCEM) is adopted to analyze the relation between users' desire and time spent, so as to evaluate the online co-design experiences. Based on evolutionary algorithm and fuzzy theory, data of this study is collected from 30 participants. The data was analyzed by descriptive analysis in SPSS, and frequency query and word cloud in NVivo. Employing design category and evaluating users' time spent, the findings are that (a) vamp color matching is consistent with interview data; (b) supported by qualitative feedback, the virtual experience map played an important role in the co-design process and the visualized interaction process; and (c) participants prefer to get more information and professional help on color matching and exterior design. Based on the findings in design category, future work should be focused on developing a better understanding of design resource recommendations and multi-stakeholder communication.

• KEPCO Journal on Electric Power and Energy
• /
• 제5권4호
• /
• pp.331-335
• /
• 2019

In this study we investigate catalytic activity and selectivity of mixture of Ag and ketjenblack according to their ratios by product analysis and electrochemical experiments, such as cyclic voltammetry, linear sweep voltammetry and chronoamperometry. We reveal that catalytic activity toward CO₂ reduction to CO is improved by simple mixing Ag nanoparticle and ketjenblack because addition of ketjenblack suppresses aggregation of Ag nanoparticles and brings increase in electrochemical active surface area. However, excess amount of ketjenblack rather inhibit the CO₂ reduction to CO. These observations provide clues to develop highly active Ag catalyst or electrode toward electrochemical reduction of CO₂.

• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2006년 추계학술발표대회 개요집
• /
• pp.120-122
• /
• 2006

This study deals with characterizations of microstructure and wear performance of a cladding layer, product on 1.9 mm-thick mild steel plate by the electric resistance welding, of composite metal powder of Coarse WC-6.5%Co and high carbon alloy(SHA). The cladding layer was examined and tested fur microstructural features, chemical composition, hardness, wear performance and wear mechanism. The cladding layer have two different matrix were observed by an optical microscope and EPMA. The one was the coarse WC-6.5Co structure. The other was the melted SHA with surrounding the WC-6.5Co structure. The hardness of WC-6.5Co was 1210HV. The hardness of SHA was 640HV. In comparison by wear rate, the cladding layer showed the remarkable wear performance that was 15 times of SM490 and about 62% of D2.

• 한국결정성장학회지
• /
• 제20권6호
• /
• pp.295-300
• /
• 2010

Metathetic route for the $MWO_4$ (M=Zn, Co) particles is a simple method of synthesis and a viable alternative method in a short time. $MWO_4$ (M=Zn, Co) particles were synthesized using solid-state metathetic (SSM) method with microwave irradiation. The $MWO_4$ (M=Zn, Co) particles were formed completely at $600^{\circ}C$ for 3 h. The crystallization process, thermal decomposition and morphology of the $MWO_4$(M= Zn, Co) particles were evaluated. The characteristics of the SSM reaction and the formation of a high lattice energy by-product NaCl were discussed.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1999년도 추계학술대회 논문집 학회본부 A
• /
• pp.40-42
• /
• 1999

In this paper, light-weight system of linear induction motor(LIM) for light railway train is presented, and is compared with former type of LIM. For the light-weight system without modification of motor size the material of primary core(silicon steel) is changed with iron-cobalt alloy and the material of primary winding(copper) is changed with aluminium. The characteristics of LIM are analyzed. Specially, the air gap magnetic flux density distribution due to end effect is showed with motor velocity, we will present papers continuously through designing and testing a trial product.

• Journal of Welding and Joining
• /
• 제25권3호
• /
• pp.72-77
• /
• 2007

This study deals with characterizations of microstructure and wear performance of a cladding layer, product on 1.9 mm-thick mild steel plate by the electric resistance welding, of composite metal powder of Coarse WC-6.5%Co and high carbon alloy (SHA). The cladding layer was examined and tested for microstructural features, chemical composition, hardness, and bondability. The cladding layer have two different matrix were observed by an optical microscope and EPMA. The one was the coarse WC-6.5Co structure. The other was the melted SHA with surrounding the WC-6.5Co structure. The hardness of WC-6.5Co was 1210HV. The hardness of SHA was 640HV.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
• /
• pp.1596-1599
• /
• 2009

Mobile ODF (one drop filling) portable display such as mobile phone and application product is needed high reliability than notebook, monitor and TV. Therefore, material development in order to optimize mobile & application ODF panel is needed. Through considering mobile ODF process and design, we have developed method of material matching test by several tests which is heat stress, UV stress and ODF process condition. So we have developed a material with characteristics of high reliability for mobile ODF panel.