• Title/Summary/Keyword: Co-alloy

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Development and Round Robin Test of Pt-Co Alloy Thin Film Standard Materials for the Quantification of Surface Compositional Analysis (표면 조성분석의 정량화를 위한 Pt-Co 합금박막 표준시료의 개발 및 공동분석)

  • 김경중
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.176-186
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    • 1998
  • Pure Pt, Co and their alloy thin films with three different compositions (Pt66-Co34, Pt40-Co60 and Pt18-Co82) were deposited on Si(100) wafers and proposed as a set of certified reference materials (CRM) for the quantification and standardization of surface compositional analysis. The compositions of the binary alloy thin films were controlled by in-situ XPS analyses and the certified compositions of the films have been determined by ICP-AES and RBS analyses after thin film growth. Through comparison of the compositions determined by in-situ XPS with those by ICP, relatively accurate compositions could be obtained with a matrix effect correction. Standard deviations of XPS and AES round robin tests with the Pt-Co alloy thin films were large up to about 4%. On the other hand, the average compositions of the Pt-Co alloy thin films by two methods were in a good agreement within 1%. The formation of a Pt rich surface layer by ion beam sputtering indicates that the surface modification by preferential sputtering must be understood for a better compositional analysis.

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Magnetic and magneto-optical properties of two metallic phase magnet Co/Co$_2$TiSn films

  • Kim, T. W.;Lee, J. W.;S. C. Shin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.375-377
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    • 1998
  • The magneto-optical properties of Co/Co$_2$TiSn two-phase magnet films were studied. These films show that relatively large Kerr rotations which are -0.4 deg. at the wavelength of 400 nm, compared to that of pure Co. It is conceivable that the magneto-optical effects may be due to both contributions of ferromagnetic Co matrix and ferromagnetic Co$_2$TiSn Heusler alloy precipitate. The perpendicular magnetization curve domonstrates a typical bubble domain hysteresis loop. the saturation magnetization change of the annealed film is less sensitive to temperature in the low temperature region and the Curie temperature of Co$_2$TiSn Heusler alloy precipitate is a little higher in the annealed film. These can be explained by the increase of the number of Co-Co exchange interaction in Heusler alloy structure resulting from the change of chemical ordering by annealing.

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Effects of Co Addition in High Strength and Low Thermal Expansion Invar Alloy (고강도 저열팽창 인바합금에 있어서 CO 첨가의 영향)

  • Kim, Bong-Seo;Jo, Yeong-Am;Yoo, Kyung-Jae;Kwon, Hae-Woong;Lee, Hui-Ung;Kim, Byung-Geol
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1901-1903
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    • 1999
  • To investigate invar alloy as a core material for increased capacity over-head transmission line which have high strength and low thermal expansion coefficient, hardness and thermal expansion coefficient of Fe-Ni-Co alloy have been studied. It is necessary that invar alloy have low thermal expansion coefficient and high strength for increased capacity over-head transmission line. In this paper. we tried to find out the effect of Ni and Co which has ferromagnetic properties and high saturation magnetization. It was found that Ni decrease thermal expansion coefficient and hardness, Co decrease thermal expansion coefficient but increase hardness in Fe-xNi-Co system. In Fe-(29-x)Ni-Co system, the material has no low thermal expansion properties substituting Co instead of Ni in concentration range of $1\sim7$%Co.

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Effects of process temperature on the microstructure and magnetic properties of electrodeposited Co-Pt alloy thin films (전해도금 공정온도가 Co-Pt 합금 박막의 미세구조 및 자기적 특성에 미치는 영향)

  • Lee, C.H.;Jeong, G.H.;Park, J.K.;Lee, K.K.;Suh, S.J.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.2
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    • pp.87-90
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    • 2008
  • Co-Pt alloy thin films were galvanostatically electrodeposited on Ru (30 nm)/Ta (5 nm)/Si (100) substrates from a amino-citrate based electrolyte. We used Ru(0002)-oriented buffer layers to control the crystallinity and orientation of the Co-Pt alloy thin films. The effect of solution temperature on the microstructure and magnetic properties of the Co-Pt alloy thin film was investigated. The samples were characterized by EDS, FESEM, XRD diffractometer using Cu $K{\alpha}$ radiation. The magnetic properties of these films were analyzed by a VSM and torque magnetometer. The Co-Pt alloy thin films were exhibited very high out-of-plane coercivity and squareness of the multilayer were 6527 Oe and 0.93, respectively, without heat treatment.

Solid State Interfacial Phenomena of High Performance Two Phase Polymer System(I) -Preparation and Characteristics of Liquid Crystalline Polyester and Poly(ε-caprolactam) Alloy- (고기능 고분자 복합재의 고상계면 현상에 대한 연구(I) -액정 Polyester와 Poly(ε-caprolactam) Alloy의 제조와 그 특성)

  • Kang, Doo Whan;Kang, Ho Jong;Jung, Hyo Sung;Lee, Yong Moo
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.49-58
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    • 1997
  • LCP/PA alloy was prepared by blending poly(${\varepsilon}-caprolactam$) (PA) with liquid crystal polyester, Vectra (LCP) having high elasticity and strength. The alloy prepared amorphous PA with more than 10 parts of thermotropic LCP had poor compatibility. To increase the compatibility of the alloy, compatibilizing agent, poly(glycinylmaleimide-co-methylmetacrylate)[poly(GMI-co-MMA)] copolymer was prepared by copolymerizing N-glycinylmaleimide(GMI) with methylmetacrylate(MMA). And then, it was blended with LCP and PA to produce LCP/PA alloy having an excellent compatibility. The compatibility characteristics of the alloy prepared from LCP and PA using the poly(GMI-co-MMA) was determined by measuring the thermal characteristics of glass transition temperature of nematic LCP, and rheological properties, and also high rate impact and flexual characteristics of the alloy were determined.

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A STUDY ON THE FLEXURAL BOND STRENGTH OF THE GOLD AND THE Co-Cr ALLOY TO THE DENTURE BASE RESINS (금 합금 및 비 귀금속 합금에 대한 의치상 레진의 결합강도에 관한 연구)

  • Park, Hyun-Joo;Kim, Chang-Whe;Kim, Yung-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.4
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    • pp.500-509
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    • 2000
  • In general, the three major oral functions of edentulous patients-mastication, phonation, esthetics-can be rehabilitated by the complete dentures, and both the resin based complete denture and the metal based complete denture are commonly used by many clinicians today. For the sake of many advantages such as the excellent thermal conductivity, low volumetric change, high strength, low risk of fracture and the better patient's adaptation, the metal based complete dentures are indicated to the several cases. But, there are common failures of these type of dentures mainly by the fracture or the debonding between the resin structures and the metal frameworks which is caused by the discrepancies of the flexural strength and the coefficient of thermal expansion. This is aggravated by the water contamination of the interface when exposed to the oral environment and results in the failure of complete denture treatment. So, the purpose of this study is to compare the bond strength and the fracture patterns of the gold alloy based and the Co-Cr alloy based complete dentures using the PMMA resins and the 4-META adhesive resins. The results of this study were as follows. 1. Both to the PMMA resin and the 4-META resin, the flexural bond strength of gold alloy is lower than that of Co-Cr alloy(P<0.05) 2. To the Co-Cr alloy, the bond strength of the 4-META resin is significantly higher than that of PMMA resin(P<0.05). 3. The flexural strength of the group with the mechanical retention form is significantly higher than that of the group without retention form(P<0.05). 4. Comparing with the other groups, the fracture patterns of the group 3 are quite different from the group 1,2,5.

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Comparative analysis on mechanical properties of gold and Co-Cr dental alloys due to joining methods (이종금속간의 결합방법에 따른 결합강도에 관한 비교 연구)

  • Park, Seong-Kyu;Choi, Boo-Byung;Kwon, Kung-Rock
    • Journal of Dental Rehabilitation and Applied Science
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    • v.19 no.2
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    • pp.75-86
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    • 2003
  • The purpose of this study was to evaluate their mechanical properties after laser-welding or soldering of precious and non-precious dental alloys. For this study, 30 Co-Cr alloy specimens, 15 gold alloy specimens, 15 palladium alloy specimens were casted and seperated on the middle area. 15 sperated Co-Cr specimens and 15 seperated gold alloy specimens were laser welded (GW Group). 15 sperated Co-Cr specimens and 15 sperated gold alloy specimens were soldered by coventional soldering method (GS Group). 15 sperated Co-Cr specimens and 15 seperated palladium alloy specimens were laser welded (PW Group). 15 sperated Co-Cr specimens and 15 sperated palladium alloy specimens were soldered by coventional soldering method (PS Group). Tensile strength, 0.2% yield strength, % elongation were recorded in nine specimens of each group. Bending strength were record in six specimens of each group. These data for four groups were subjected to a two-way analysis of variance(ANOVA). The fracture locations, fractured surfaces were examined by SEM(scanning electron microscope). The results were as following: 1) In the same alloy combination, the tensile strength and 0.2% yield strength and of the laser welded group with same metal combination were significantly less than soldered groups(p<0.05). 2) In the combination of Co-Cr/Palladium, the bending strength of laser welded group were significantly less than that of soldered groups(p<0.05). In the combination of Co-Cr/Gold, the bending strength of laser welded group were significantly higher than that of soldered groups(p<0.05). 3) In the same method of joint, the tensile strength and 0.2% yield strength and bending strength of the Co-Cr/gold were significantly higher than Co-Cr/palladium(p<0.05). 4) There was no significantly statistical difference between each group in the % elongation(p>0.05). 5) The fracture of the laser welded specimens occured in the welding area and a large void was observed at the center of the fracture surface. 6) The fracture of the soldered specimens occured also inthe soldered area and many porpsities were showed at the fracture sites.

Magnetic Properties of Anodic Oxidized Films Electrodeposited Cobalt-Iron (코발트-철(鐵)을 전해석출(電解析出)한 양극산화피막(陽極酸化皮膜)의 자기특성(磁氣特性))

  • Kang, Hee-Woo
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1143-1146
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    • 1993
  • The magnetic properties of aluminium anodized film in which Co-Fe alloy electrodeposited are investigated with regard to the alloy composition of magnetic films. The electrodeposited Co-Fe particles are confirmed to be single phase Co-Fe alloys by X-ray diffractions. The coercive force as well as the magnetic anisotropy energy can be controlled by changing the composition of the alloy. Magneticfilms having high saturation magnetization and high coercive force were obtained.

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Fabrication of Mg Alloy Foam via Melting Foaming Method Using $CaCO_3$ as Blowing Agent ($CaCO_3$를 이용한 발포 마그네슘 합금의 제조)

  • Yang, Dong-Hui;Seo, Chang-Hwan;Wang, Xiao-Song;Hur, Bo-Young
    • Journal of Korea Foundry Society
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    • v.26 no.6
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    • pp.272-276
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    • 2006
  • For the first time AZ91 (MgAl9Zn1) and AM60 (MgAl6) Mg alloy foams with homogeneous pore structures were prepared successfully via melting foaming method by using $CaCO_3$ powder as blowing agent. The possible foaming mechanisms and pore structures of these Mg alloy foams were discussed and investigated. The results show that Mg alloy melt can affect $CaCO_3$ decomposition behavior and AZ91 Mg alloy is relative easy to be foamed into metal foam with high porosity and big pore size.

Manufactures of dental casting Co-Cr-Mo based alloys in addition to Sn, Cu and analysis of infrared thermal image for melting process of its alloys (Sn 및 Cu를 첨가한 치과 주조용 Co-Cr-Mo계 합금제조 및 용해과정 분석)

  • Kang, Hoo-Won;Park, Young-Sik;Hwang, In;Lee, Chang-Ho;Heo, Yong;Won, Yong-Gwan
    • Journal of Technologic Dentistry
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    • v.36 no.3
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    • pp.141-147
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    • 2014
  • Purpose: Dental casting #Gr I (Co-25Cr-5Mo-3Sn-1Mn-1Si), #Gr II (Co-25Cr-5Mo-5Cu-1Mn -1Si) and #Gr III (Co-25Cr-5Mo-3Sn-5Cu-1Mn-1Si) master alloys of granule type were manufactured the same as manufacturing processes for dental casting Ni-Cr and Co-Cr-Mo based alloys of ingot type. These alloys were analyzed melting processes with heating time of high frequency induction centrifugal casting machine using infrared thermal image analyzer. Methods: These alloys were manufactured such as; alloy design, the first master alloy manufatured using vacuum arc casting machine, melting metal setting in crucible, melting in VIM, pouring in the mold of bar type, cutting the gate and runner bar and polishing. These alloys were put about 30g/charge in the ceramic crucible of high frequency induction centrifugal casting machine and heat, Infrared thermal image analyzer indicated alloys in the crucible were set and operated. Results: The melting temperatures of these alloys measuring infrared thermal image analyzer were decreased in comparison with remanium$^{(R)}$ GM 800+, vera PDI$^{TM}$, Biosil$^{(R)}$ f, WISIL$^{(R)}$ M type V, Ticonium 2000 alloys of ingot type and vera PDS$^{TM}$(Aabadent, USA), Regalloy alloys of shot type. Conclusion: Co-Cr-Mo based alloy in addition to Sn(#Gr I alloy) were decreased the melting temperature with heating time of high frequency induction centrifugal casting machine using infrared thermal image analyzer.