• Title/Summary/Keyword: Co-alloy

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Effect of Carbon on the Coefficient of Thermal Expansion of As-Cast Fe-3 0 wt.%Ni-12.5wt.% Co-xC Invar Alloys

  • 김봉서;유경재;김병걸;이희웅
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.247-247
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    • 1999
  • The segregation (distribution) of nickel and the composition of its constituents influence the low thermal expansion characteristics (Invar effect) in Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy. The change of coefficient of the thermal expansion and magnetic properties were studied as an aspect of carbon addition causing the segregation of Ni in primary austenite of as-cast Fe-30 wt.% Ni-12.5 wt.% Co Invar alloy. The coefficient of thermal expansion of Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy showed its lowest value at 0.08 wt.% carbon, increased with increasing carbon content in the range of 0.08-1.0 wt.%C, kept constant at 1.0-2.0 wt.%C and decreased at carbon higher than 2.0 wt.%. The effective distribution of the coefficient of nickel in as-cast Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy increased with increasing carbon content. The volume fraction of they phase of Fe-30 wt.% Ni-12.5 wt.% Co-xC alloy increased with increasing carbon content. The microstructure of Fe-30 wt.% Ni-12.5 wt.% Co-xC alloy changed with the carbon content was independent of the coefficient of thermal expansion. The Curie temperature changed linearly with the carbon content and was similar to the change of the coefficient of thermal expansion. Moreover, the coefficient of thermal expansion decreased when the ratio of saturation magnetization to Curie temperature ($\sigma_s/T_c$) increased, decreasing the Curie temperature and showed a specific relationship with the magnetic properties of the Fe-30 wt.% Ni-12.5 wt.% Co-xCInvar alloy.

Study on Base metal Alloy (Base metal Alloy에 관한 고찰(考察))

  • Sung, Hwan-Kyung
    • Journal of Technologic Dentistry
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    • v.7 no.1
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    • pp.53-59
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    • 1985
  • This paper aims to examine baes metal alloy in all its aspects - the roles of elements, the content of every element according to uses, characters, laboratory technique methods and the kind of artificial base metal alloy registered in A.D.A. Specification. The results are as follows; 1. Base metal alloy is used widely bacaues it is rather cheap, but it should be handled appropriately in operating because its quality is bad. 2. Classifying base metal alloy, it is classified into Co-Cr alloy, Ni-Cr alloy, and Ni-Cr-Co alloy according to element, it is classified into partial denture alloy, surgical alloy and crown & bridge alloy according to use. 3. Among elements of base metal alloy, Bellium lowers the melting point of the alloy and increases the strength, but the amount should be limited when it is used because it destroys the organization of a living body. 4. The investments for base metal alloy are ethyl silcate bonded investment and phosphate bonded investment which endure well at high burn out temperature. 5. A.D.A specification No.14 in Kore contains Niranium, Nobilium, regalloy, Ticonium and Vitallium.

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Study on the Mechanical Properties of Laser Welded AZ31 Magnesium Alloy (AZ31 마그네슘 합금 레이저 용접부의 기계적 성질에 관한 연구)

  • Lee, M.Y.;Jeong, B.H.;Jeong, S.M.;Park, H.J.
    • Laser Solutions
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    • v.9 no.1
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    • pp.25-29
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    • 2006
  • This study aimed to investigate the change of mechanical properties with the rolling direction and shielding condition during laser welding of AZ31 magnesium alloy. AZ31 magnesium alloy sheets of 1mm thickness were welded using a continuous wave Nd:YAG laser with and without Ar shielding gas. The effect of Ar shielding gas and rolling direction on the mechanical properties were investigated using Vickers hardness, transverse-weld tensile. Porosity in the weld metals was investigated using an optical microscope. The experimental results showed that mechanical properties of AZ31 magnesium alloy laser welds were upgraded compared to those of base metal. Mechanical properties of AZ31 magnesium alloy laser welds were not substantially changed when Ar shielding gas was supplied.

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MAGNETIC PROPERTIES OF NANOCRYSTALLINE (Fe,Co)-B-Al-M (M=Nb/Mo/Ta) ALLOYS

  • Kang, D.B.;Cho, W.S.;Kim, T.K.;Cho, Y.S.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.483-486
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    • 1995
  • Soft magnetic properties of Fe-based (Fe,Co)-B-Al-M (M=Nb, Mo or Ta) nanocrystalline alloy have been investigated. The alloy obtained directly form the rapid solidification process. Microstructure of the alloy is a mixtu re of ultrafine bcc Fe(Co) nanocrystallines and a small amount of retained amorphous phase. Heat treatment of as-prepared alloys improves soft magnetic properties in high frequency range. ${(Fe_{.85}Co_{.15})}_{70}B_{18}Al_{10}Ta_{6}$ alloy alloy annealed at $500^{\circ}C$ for 1 h shows the most improved soth magnetic properties among the alloy examined. Average grain size of the nanocystalline is about 10 nm.

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A STUDY ON SURFACE ROUGHNESS OF METALS ACCORDING TO FINISHING AND POLISHING PROCEDURES - AN ATOMIC FORCE MICROSCOPE ANALYSIS - (연마방법에 따른 금속의 활택도에 관한 연구 - Atomic Force Microscope를 이용한 -)

  • Park Won-Kyu;Woo Yi-Hyung;Choi Boo-Byung;Lee Sung-Bok
    • The Journal of Korean Academy of Prosthodontics
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    • v.41 no.1
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    • pp.1-19
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    • 2003
  • The surface of metals should be as smooth as possible for optimum comfort, oral hygiene, low plaque retention, and resistance to corrosion. In this study five specimens of each precious metal(type III gold alloy, ceramic gold alloy, and Ag-Pd alloy) were divided into five groups according to finishing and polishing procedures : group 1(sandblaster), group 2(group 1+stone), group 3(group 2+brown rubber), group 4(group 3+green rubber), and group 5(group 4+rouge). Six specimens of each non-precious metal(Co-Cr alloy, Ni-Cr alloy, and Co-Cr-Ti alloy) were divided into six groups: group 1(sandblaster), group 2(group 1+hard stone), group 3(group 2+electrolytic polisher), group 4(group 3+brown hard rubber point), group 5(group 4+green hard rubber point), and group 6(group 5+rouge). Considering factors affecting the rate of abrasion, the same dentist applied each finishing and polishing procedure. In addition, the surface roughness of enamel, resin, and porcelain was evaluated. The effect of finishing and polishing procedures on surface roughness of precious and non-precious metals, enamel, resin, and porcelain was evaluated by means of Atomic Force Microscope(AutoProbe CP. Park Scientific Instruments, U.S.A.) that can image the three dimensional surface profile and measure average surface roughness values of each sample at the same time. The obtained results were as follows : 1. According to finishing and polishing procedures, the surface roughness of type III gold alloy, ceramic gold alloy, and Ag-Pd alloy was decreased in the order of group 1, 2, 3, 4, and 5 (P<0.01). 2. According to finishing and polishing procedures. the surface roughness of Co-Cr alloy, Ni-Cr alloy, and Co-Cr-Ti alloy was decreased in the order of group 1, 2, 3, 4, 5, and 6 (p<0.01). 3. There was not statistically significant difference in the surface roughness among three metals of precious metals in group 1 but was significant difference in group 2, 3, 4, and 5 (P<0.05). 4. There was not statistically significant difference in the surface roughness among three metals of non-precious metals in all groups. 5. When the surface roughness of the smoothest surface of each metal, enamel. porcelain, and resin was compared, porcelain was the smoothest and the surface roughness was decreased in the order of Ni-Cr alloy. Co-Cr alloy. Co-Cr-Ti alloy, resin. Ag-Pd alloy, ceramic gold alloy type III gold alloy, and enamel (P<0.01). The results of this study indicate that the finishing and polishing procedures should be carried out in a logical, systematic sequence of steps and the harder non-precious metals may be less resistance to abrasion than are the softer precious metals.

Machining of Wc-Co alloys with diamond tool (다이아몬드공구에 의한 초경합금의 절삭)

  • 김성청
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.6 no.2
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    • pp.102-111
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    • 1997
  • This paper deals with the machinability based on turning of WC-Co allows with the coated and the sintered diamond tools. The main conclusions obtained are as follows. (1) When machining WC-10%Co alloy, the flank wear of sintered diamond tool increases more largely with the increase of cutting speed in comparison with coated diamond tool. The tool wear decreases with the increase of the grain size and nose radius of sintered diamond tool. (2) When machining WC-20%Co alloy, the tool wear and cutting force decrease with the decrease of rake angle. Their exists a certain cutting speed range to exhibit the smallest tool wear in machining the WC-20%Co alloy, and this critical cutting speed becomes higher by 2 times in the case of coated diamond tool compared with sintered diamond tool. (3) The machinability becomes better with the increase of Co content. The effects of cutting speed and feed rate on the roughness of machined surface become smaller with the increase of Co content.

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Effect of B and W Contents on Hardness of Electroless Co Alloy Thin Films (B와 W의 함량이 무전해 Co 합금 박막의 경도에 미치는 영향 연구)

  • Lim, Taeho;Kim, Jae Jeong
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.895-900
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    • 2018
  • In this study, the electroless deposition of Co-B and Co-W-B alloy thin films was developed and the effect of B and W contents on the hardness of the alloy thin films were investigated. An amorphous Co alloy film was successfully formed by electroless deposition and the contents of B and W in the film were controlled by varying the concentrations of dimethylamine borane and sodium tungstate dihydrate, which were used as a reducing agent and W source, respectively. The hardness of the thin films increased as the contents of B and W were increased because B and W act as impurities suppressing the propagation of dislocation in a film. In addition, it was found that the content of B and W in the Co alloy films can be increased significantly when aeration is not performed. Finally, the hardness of Co-W-B alloy thin film was improved up to 8.9 (${\pm}0.3$) GPa.

The study on Comparison Evaluation of Shear Bond Strength of Co-Cr Based Alloy using for Porcelain Fused Metal (도재용착주조관용 Co-Cr계 비귀금속 합금의 전단결합강도 비교평가에 관한 연구)

  • Kim, Hee-Jin;Kim, Bu-Sob
    • Journal of Technologic Dentistry
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    • v.32 no.3
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    • pp.195-207
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    • 2010
  • Purpose: The purpose of this study was to observe the microstructural changes of surface in the specimens, performing the shear bond strength testing. The currently most used non-precious alloys are nickel-chromium based alloys with or without beryllium. However, their biocompatibility has been questioned concerning possible damages to the health of the patient and professionals involved in the fabrication of prosthesis caused by long exposure to Ni and Be. An option to nickel-chromium alloys is the cobalt-chromium alloy, an alternative that does not sacrifice the physical properties of the metal porcelain systems. Studies in the animals substantially show that the cobalt-chromium alloys are relatively well tolerated, being therefore more biocompatible than the nickel-chromium alloys. Methods: Non-addition Be to nickel-chromium based alloy(Bellabond plus) and cobalt-chromium alloy which has been widely used(Wirobond C) fused with ZEO light porcelain classified control group and cobalt-chromium alloy which is developing alloy of Alphadent company in Korea(Alphadent alloy) fused with ZEO light porcelain classified experimental group. The specimens of $4mm{\times}4mm{\times}0.5mm$ were prepared as-cast and as-opaque to cast body to analyze the mechanical characteristic change, the microstructure of alloy surface. The phase change was used to observe through XRD analysis and OM/SEM was used to observe the surface of specimens as-cast and as-opaque to cast body. Chemical formation of their elements was measured with EDS. Then hardness was measured with Micro Vicker's hardness tester. Shear bond strength test thirty specimens of $10mm{\times}10mm{\times}2mm$ was prepared, veneered, 3mm high and 3mm in diameter, over the alloy specimens. The shear bond strength test was performed in a universal testing machine(UTM) with a cross head speed of 0.5mm/min. Ultimate shear bond strength data were analyzed with one-way ANOVA and the Scheffe's test (P<0.05). Within the limits of this study, the following conclusions were drawn: The X-ray diffraction analysis results for the as-cast and as-opaque specimens showed that the major relative intensity of Bellabond plus alloy were changed smaller than Wirobond C and Alphadent Co-Cr based alloys. Results: Microstructural analysis results for the opaque specimens showed all the alloys increased carbides and precipitation(PPT). Alphadent Co-Cr based alloy showed the carbides of lamellar type. The Vickers hardness results for the opaque specimens showed Wirobond C and Alphadent Co-Cr based alloys were increaser than before ascast, but Bellabond plus alloy relatively decreased. The mean shear bond strengths (MPa) were: 33.11 for Wirobond C/ZEO light; 25.00 for Alphadent Co-Cr alloy/ZEO light; 18.02 for Bellabond plus/ZEO light. Conclusion: The mean shear bond strengths for Co-Cr and Ni-Cr based alloy were significantly different. But the all groups showed metal-metal oxide modes in shear bond strengths test at the interface.

Anodic Oxidation Behavior of AZ31 Magnesium Alloy in Aqueous Electrolyte Containing Various Na2CO3 Concentrations

  • Moon, Sungmo;Kim, Yeajin
    • Journal of the Korean institute of surface engineering
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    • v.49 no.4
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    • pp.331-338
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    • 2016
  • In this work, anodic oxidation behavior of AZ31 Mg alloy was studied as a function of $Na_2CO_3$ concentration in electrolyte by voltage-time curves and observation of surface appearances and morphologies after the anodic treatments, using optical microscopy and confocal scanning laser microscopy (CSLM). The voltage-time curves of AZ31 Mg alloy surface and surface appearances after the anodic treatments showed three different regions with $Na_2CO_3$ concentration : region I, below 0.2 M $Na_2CO_3$ where shiny surface with a number of small size pits; region II, between 0.4 M and 0.6 M $Na_2CO_3$ where dark surface with relatively low number of large size burned or dark spots; region III, more than 0.8 M $Na_2CO_3$ where bright surface with or without large size dark spots were obtained. The anodically treated AZ31 Mg alloy surface became significantly brightened with increasing $Na_2CO_3$ concentration from 0.5 M to 0.8 M which was attribute to the formation of denser and smoother surface films. Pits and porous protruding reaction products were found at relatively large size and small size spots, respectively, on the AZ31 Mg alloy surface in low concentration of $Na_2CO_3$ less than 0.2 M. The formation of pits is attributed to the result of repetition of the formation and detachment of porous anodic reaction products. Based on the experimental results obtained in this work, it is concluded that more uniform, denser and smoother surface of AZ31 Mg alloy could be obtained at more than 0.8 M $Na_2CO_3$ concentration if there is no other oxide forming agent.